• Title/Summary/Keyword: $B_4C$ addition

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초고온용 ZrB2-계 세라믹스의 치밀화와 물성 (Densification and Properties of ZrB2-based Ceramics for Ultra-high Temperature Applications)

  • 김성원;김형태;김경자;서원선
    • 한국정밀공학회지
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    • 제29권3호
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    • pp.273-278
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    • 2012
  • $ZrB_2$ has a melting temperature of $3245^{\circ}C$ and a low density of $6.1\;g/cm^3$, which makes this a candidate for application to ultra-high temperature over $2000^{\circ}C$. Beside these properties, $ZrB_2$ has excellent resistance to thermal shock and oxidation compared with other non-oxide engineering ceramics. This paper reviewed briefly 2 research examples, which are related to densification and properties of $ZrB_2$-based ceramics for ultra-high temperature applications. In the first section, the effect of $B_4C$ addition on the densification and properties of $ZrB_2$-based ceramics is shown. $ZrB_2$-20 vol.% SiC system was selected as a basic composition and $B_4C$ or C was added to this system in some extents. With sintered bodies, densification behavior and hightemperature (up to $1400^{\circ}C$) properties such as bending strength and hardness are examined. In the second section, the effect of the SiC size on the microstructures and physical properties is shown. $ZrB_2$-SiC ceramics are fabricated by using various SiC sources in order to investigate the grain-growth inhibition and the mechanical/thermal properties of $ZrB_2$-SiC.

고강도 이온질화 기어의 개발 (Development of high-strength ion nitrided gear)

  • 김영훈;선철곤;김한군
    • 열처리공학회지
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    • 제7권3호
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    • pp.184-189
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    • 1994
  • The heat treatment charaterristic of SCM 440 and B 16 steels has been investigated in various condition(A, B and C) to the effect of heat treatment on mechanical properties, and the following results were obtained. 1. We are obtained a good nitriding characteristic in bainitic structure than other heat treatment cycle in our experiment. 2. Fatigue characteristic has shown in order of B)C)A condition as heat treatment cycle. 3. The effective hardening depth and fatigue characteristic has been excellented in B 16 than SCM 440 after the nitriding and Q. T for Band C condition. 4. Nitriding depth has been increased in addition of Cr, V and the nitriding efficiency is increased as easiness of banite formation to wide range of cooling rate by addition of Mo. 5. The depth of compound layer in parallel surface, notched slop plane and notched bottom has been varied to the nitriding depth of 5, 4 and 3 ${\mu}$ in relatively uniform pattern after 10h nitriding treatment for SCM 440 into A condition.

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New Transition Metal Mediated Alkylation Reaction of arachno-$S_{2}B_{7}H_{8}$, Insertion Reaction of arachno-$S_{2}B_{7}H_{8}^{-}$ with $(CO)_{5}M$ {${C(R_{1})(R_{2})}$} $(M=Cr,\;W;\;R_{1}=CH_{3},\;C_{6}H_{5};\;R_{2}=OCH_{3},\;SC_{6}H{5})$: Synthesis and Characterization of arachno-$4-RCH_{2}-6,8-S_{2}B_{7}H_{8}\;(R=CH_{3},\;IIa;\;C_{6}H_{5},\;IIb)$

  • Hee-Joo Jeon;Jae-Jung Ko;Kang-bong Lee;Sang Ook Kang
    • Bulletin of the Korean Chemical Society
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    • 제14권1호
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    • pp.113-117
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    • 1993
  • Good yield synthetic routes for the production of new B-alkyl-dithiaborane clusters are reported. The syntheses of the B-alkyl-dithiaboranes are based on the use of Fischer-type carbene reagents to activate the B-H bonds of dithiaborane for alkyl-addition reactions and are the first examples of transition-mediated reactions of dithiaborane to be reported. Thus, reactions employing arachno-$S_2B_7H_8$- and $(CO)_5M{C(R_1)R_2}$ (M = Cr, W; $R_1 = CH_3,\;C_6H_5;\; R_2 = OCH_3,\;SC_6H_5)$ were found to yield the intermidiate anions I, $[(CO)_5M{C(R_1)R_2S_2B_7H_8}]^-$, which upon protonation gave the corresponding neutral, air-sensitive cluster arachno-4-$RCH_2-6,8-S_2B_7H_8(R=CH_3,\;IIa;\;C_6H_5,\;IIb)$ range from 30 to 35% yield. Complexes IIa and IIb are isoelectronic with arachno-6,8-$S_2B_7H_9$ and, on the basis of the spectroscopic data, are proposed to adopt a similar arachno cage geometry in which an $RCH_2$ units are substituted to 4 position boron atom of the arachno-6,8-$S_2B_7H_9$.

B2C 전자상거래에서 고객신뢰의 영향요인과 구매의도에 대한 신뢰의 매개 역할 (Factors Influencing the Consumer Trust and Mediating Roles of Trust on Purchasing Intention in B2C Electronic Commerce)

  • 유일;최혁라
    • Asia pacific journal of information systems
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    • 제13권4호
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    • pp.49-72
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    • 2003
  • Despite the phenomenal growth of Internet users in recent years, the penetration rate of B2C electronic commerce(EC) is still low. According to previous studies, one of most often cited reasons is the lack of consumers' trust. Although trust is an important concept in B2C EC, there is a lack of theory-based empirical research in this area. In this paper, influencing factors are proposed for investigating the nature of trust in the specific context of B2C EC. Thirteen hypotheses are empirically tested. The results show that most of hypotheses are supported except for perceived size, perceived competence, perceived reputation, familiarity and third party recognition. In addition trust was found to have a strong positive effect on intention to purchase. Finally, trust was found to have a mediation effect between on influencing factors and intention to purchase. Implications of these findings are discussed for researchers and practitioners.

남성 성악가의 음도고정시 강도 변화와 강도고정시 음도 변화의 공기역학 및 성대접촉율의 변화 (Changes in Aerodynamic Function and Closed Quotient with the Variable Pitch and Loudness in Male Classic Singers)

  • 남도현;백재연;김재옥;박선영;최홍식
    • 음성과학
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    • 제14권2호
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    • pp.23-33
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    • 2007
  • This study examined the aerodynamic functions (mean airflow rate MFR, subglottal pressure Psub) and closed quotients (CQs) in the fixed pitch (C3, E3, G3, C4) with the variable loudness (70 and 80 dB) as well as in the fixed loudness at 70 dB and 80 dB with the variable pitch (C3, E3, G3, C4) in five classic male singers (Baritone). Results showed that MFR significantly increased at C3, E3, and G3 and Psub significantly increased at C4 when the loudness increased from 70 to 80 dB. At 70 dB, MFR and Psub significantly increased and CQ significantly decreased when the pitch increased from C3 to C4. At 80 dB, MFR significantly decreased when the pitch increased from C3 to G3. However, Psub showed the significant decrease with the pitch increased at 80 dB. In conclusion, as the loudness increases, the aerodynamic loss is getting higher and vocal efficiency becomes lower at low pitch than at higher pitch. At a low loudness level, the main mechanism to control loudness is the amount of medial compression of the vocal folds rather than the aerodynamic function. In addition, the aerodynamic function and medial compression of the vocal folds have a significant role in increasing the loudness level.

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CH$_{4}$-공기 분류 확산화염의 NOx 생성특성에 관한 수치해석 (Numerical analysis of NOx formation characteristics in CH$_{4}$-air jet diffusion flame)

  • 오창보;이창언
    • 대한기계학회논문집B
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    • 제22권2호
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    • pp.193-204
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    • 1998
  • Numerical analysis was performed with multicomponent transport properties and detailed reaction mechanisms for axisymmetric 2-D CH$_{4}$ jet diffusion flame. Calculations were carried out twice with the $C_{2}$-Thermal Mechanism including $C_{2}$ and thermal NO reactions and the $C_{2}$-Full Mechanism including prompt NO reactions in addition to the above $C_{2}$-Thermal NO mechanism. The results show that the flame structures such as flame temperature, major and minor species concentration are indifferent to respective mechanisms. The production path of Thermal NO is dominant comparing with that of Prompt NO in total NO production of pure CH$_{4}$ jet diffusion flame. This is because thermal NO mechanism mainly contributes to positive formation of NO in the whole flame region, but Prompt NO mechanism contributes to negative formation in the fuel rich region. In addition, 0$_{2}$ penetration near the nozzle outlet affects the flame structures, especially N0$_{2}$ formation characteristics.

급경사 복원 농경지 토양 유실 저감을 위한 개량제 효율 및 현장 적용성 평가 (Evaluation of Amending Materials to Reduce Soil Loss from Sloping Remediated Agricultural Land)

  • 황원재;박민석;현승훈;지원현;이상환
    • Ecology and Resilient Infrastructure
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    • 제4권3호
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    • pp.180-185
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    • 2017
  • 광산 활동에 의해 오염된 농경지의 복원은 개량제 처리와 복토를 기반의 미량원소 안정화 기법으로 진행되고 있다. 최근 복원된 부지 중 경사 농경지에서 토양 유실 문제가 대두되고 있다. 본 연구에서는 4종의 개량제 (벤토나이트, 석회, 유기물, 제강슬래그)를 다양한 비율로 단일 또는 복합처리 한 후 입단 형성의 효율을 평가했다. 복토재는 점토함량이 다른 3가지 토양 (A 토양=9.4%, B토양=14.7%, C 토양=21.2%)을 대상으로 했다. 단일처리 결과, A 토양은 유기물 5%, B와 C 토양은 석회 5%가 각 토양의 대조구에 비해 입단 형성이 가장 효과적이었다. 9가지 복합처리구 중에서 A 토양은 유기물 3% + 석회 1%, B와 C 토양은 유기물 1% + 석회 3% 처리구의 입단 형성이 가장 높았다 (A 토양=30.4%, B 토양=25.0%, C 토양=36.5%). 현장처리를 위해 각 복토재 (A 토양=0.045, B 토양=0.051, C 토양=0.054)와 국내 농경지의 평균 (0.032) 토양침식인자 차이만큼을 개량제에 의한 목표 입단 형성량으로 설정하였다(29.1% 입단형성). 비용편익을 고려한 최적 개량제 선정한 결과 A와 B 토양은 석회 3%, C 토양은 석회 5%가 가장 적합 했으며, 이를 통한 경사진 복원된 경사 농경지에서 토양 유실을 효과적이고 경제적으로 저감할 것으로 예측된다. 본 연구에서 석회 처리에 의한 토양 알칼리도 상승은 고려하지 않았다.

Synthesis and Structure of Benzotriazolyl Fluorenes

  • KohPark, Kwang-Hee;Jung, Hye-Mi;Lee, Tae-Woo;Kang, Sung-Kwon
    • Bulletin of the Korean Chemical Society
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    • 제31권4호
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    • pp.984-988
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    • 2010
  • 1-(Fluoren-2-yl)-benzo[d][1,2,3]triazoles 5a-b were synthesized starting from 2-nitrofluorene. 2-Nitrofluorenes 1a-b were reduced by catalytic hydrogenation, reacted with 2,4-dinitrofluorobenzene followed by catalytic hydrogenation to afford 2-(N-2,4-diaminophenyl)aminofluorenes 4a-b. Diazotization of 4a-b with $NaNO_2/H_2SO_4$ followed by treatment with $H_3PO_2$ gave 5a-b. Sulfonation of 5a-b yielded 7-benzotriazol-1-yl-fluorene-2-sulfonic acids 6a-b. The structures of 5b and 6b were firmly identified by X-ray crystal analysis in addition to $^1H$ NMR, $^{13}C$ NMR, and elemental analysis.

Efficacy of Brucella abortus strain RB51 vaccine in Korean mongrel dogs against virulent strains of B. abortus biotype 1 and B. canis

  • Hur, Jin;Baek, Byeong-Kirl
    • 한국동물위생학회지
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    • 제33권1호
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    • pp.29-35
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    • 2010
  • This study was performed to test the hypothesis that Brucella abortus strain RB51 (SRB51) might protect Korean indigenous mongrel dog against challenge with either virulent B. abortus biotype 1 or B. canis. A total of 12 Korean mongrel dogs were divided into four groups (Group A, B, C and D). Dogs belonging to Group A and C were inoculated subcutaneously with $1{\times}10^9$ CFU of SRB51 in 1ml of sterile phosphate buffered saline (PBS). Dogs of Group B and D were inoculated subcutaneously with 1ml of sterile PBS as control. At 12 weeks post vaccination, dogs of Group A and B were challenged by oral inoculation of virulent strain of B. canis ($5.0{\times}10^9$ CFU) and dogs of Group C and D were challenged by oral inoculation of virulent strain of B. abortus biotype 1 ($4.4{\times}10^{10}$ CFU). The serum antibodies titers in all dogs were monitored at regular interval for eight weeks after challenge (AC) by standard tube agglutination test, plate agglutination test, rose bengal test, 2-mercaptoethanol rapid slide agglutination test and 2-mercaptoethanol tube agglutination test. No antibody titers in Group A and C was detected. Also, the challenge strains were not found from blood of all dogs of Group A and C from 1 week AC till the end of the experiment by culture and modified AMOS-PCR, whereas B. canis and B. abortus challenge strains were detected from blood of Group B and D, respectively. In addition, neither of two challenge bacteria was recovered from liver, spleen, kidneys, lymph nodes and reproductive tracts of Group A and C dogs after postmortem. However, B. canis and B. abortus challenge strains were isolated from these tissues of Group B and D, respectively. These data suggest that SRB51 could be a promising vaccine candidate for immunizing dogs to control canine brucellosis caused by B. canis or B. abortus.

The Probiotic Lactobacillus Prevents Citrobacter rodentium-Induced Murine Colitis in a TLR2-Dependent Manner

  • Ryu, Seung-Hyun;Park, Jong-Hyung;Choi, Soo-Young;Jeon, Hee-Yeon;Park, Jin-Il;Kim, Jun-Young;Ham, Seung-Hoon;Choi, Yang-Kyu
    • Journal of Microbiology and Biotechnology
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    • 제26권7호
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    • pp.1333-1340
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    • 2016
  • The main objective of this study was to investigate whether Lactobacillus rhamnosus GG (LGG) ameliorated the effects of Citrobactor rodentium infection in Toll-like receptor 2 (TLR2) knockout (KO) and TLR4 KO mice, as well as in wild-type C57BL/6 (B6) mice. TLR2 KO, TLR4 KO, and B6 mice were divided into three groups per each strain. Each group had an uninfected control group (n = 5), C. rodentium-infected group (n = 8), and LGG-pretreated C. rodentium-infected group (n = 8). The survival rate of B6 mice infected with C. rodentium was higher when pretreated with LGG. Pretreatment with LGG ameliorated C. rodentium-induced mucosal hyperplasia in B6 and TLR4 KO mice. However, in C-rodentium-infected TLR2 KO mice, mucosal hyperplasia persisted, regardless of pretreatment with LGG. In addition, LGG-pretreated B6 and TLR4 KO mice showed a decrease in spleen weight and downregulation of tumor necrosis factor alpha, interferon gamma, and monocyte chemotactic protein 1 mRNA expression compared with the non-pretreated group. In contrast, such changes were not observed in TLR2 KO mice, regardless of pretreatment with LGG. From the above results, we conclude that pretreatment with LGG ameliorates C. rodentium-induced colitis in B6 and TLR4 KO mice, but not in TLR2 KO mice. Therefore, LGG protects mice from C. rodentium-induced colitis in a TLR2-dependent manner.