• Title/Summary/Keyword: $BF_3$

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Review on Facilitated Olefin Transport Membranes Utilizing Polymer Electrolytes and Polymer Nanocomposites (고분자 전해질과 고분자 나노복합체를 활용한 올레핀 촉진수송 분리막에 대한 총설)

  • Kang, Sang Wook
    • Membrane Journal
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    • v.26 no.3
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    • pp.173-178
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    • 2016
  • In this short review, the polymer electrolyte membranes consisting of polymer and Ag salts were introduced and various approaches to solve the long-term stability were summarized. In particular, utilizing $AgNO_3$ as carriers with ionic liquid, the replacement of polymer matrix as poly(ethylene phthalate) (PEP) for strong coordinative interactions with Ag ions and the introduction of $Al(NO_3)_3$ to $polymer/AgBF_4$ complexes were introduced for long-term stable facilitated olefin transport membranes. For the polymer nanocomposite membranes, the role of electron acceptors as polarizer on the surface of AgNPs and the approach to solve the low permeance were introduced.

CP-EAPap biomimetic actuator fabrication and performance (CP-EAPap 생체모방 작동기의 제조 및 성능)

  • Li, Qubo;Kim, Jae-Hwan;Deshpande, S.D.
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2005.05a
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    • pp.360-363
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    • 2005
  • Biomimetic actuators composed of cellophane with an electrically conducting polyaniline(PANI) film have been fabricated and tested in air ambience conditions doped with two different counter ions such as perchlorate (${ClO_4}^-$) and tetrafluoroborate (${BF_4}^-$). Fabrication of the trilayer CP//CELLOPHANE//CP substantially enhanced the tip displacement (13.2mm) compared to the small displacement (8.3mm) of the bilaye. CP//CELLOPHANE. The ion migration among layers is the main factor behind the expansion of cellophane, while the expansion/contraction of PANI are dependent on the redox reaction of the polymer. The displacement of the composite is dominated by the humidity content. This implies that the actuation principle is possibly due to the assistance of water existing.

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Comparison of Lower Limb Muscle Activity According to Different Gait Pattern and Speed on the Treadmill (트레드밀 전·후방 보행과 속도에 따른 다리근육의 근활성도 비교)

  • Choi, Seok-Hwa;Chun, Hye-Lim;Lee, Cu-Rie
    • Journal of Korean Physical Therapy Science
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    • v.25 no.2
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    • pp.55-61
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    • 2018
  • Purpose: This study is to compare muscle activation of leg muscles with forward and backward gait and treadmill speed. Method: The experimenter is a healthy ten male and female. They practice walking on the treadmill for 2 minutes and then walk 2km/h and 4km/h in front and back for 3 minutes. Muscle activities were recorded from the lower limb muscles (rectus femoris [RF], biceps femoris [BF], gastrucnemius [GCM]). Results: According to the study, lower extremity muscles have higher backward gait than forward gait. Conclusion: Muscle activity at the speed indicated that the muscular activity of the lower limbs was 4.0km/h, which is higher than 2.0km/h.

세계 주요고무제품제조업체의 영업실적

  • Kim, Min
    • The tire
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    • s.114
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    • pp.14-29
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    • 1984
  • 본자료는 세계 11개 주요 고무제품제조업체 (그 중 10개사는 82년도 매출액이 각각 10억 달러 이상임)의 재무상황과 최근의 영업실적을 분석한 것이다. 조사편의상 기업체들을 미국ㆍ유럽ㆍ일본의 3개 그룹으로 나누어 자료비교가 가능한 지난 82년도를 기준으로 분석했는데, 동년 총매출액 370억달러 중 미국이 53%, 유럽이 36%, 일본이 11%를 점하였다. 11개 업체는 Goodyear, Michelin,Pirelli, Firestone,Bridgestone, BF Goodrich, Dunlop, General Tire, Uniroyal, Continental, Yokohama 등인데, 이들이 모두 고무산업만을 하는 것은 아니다. 일본의 Sumitomo 사는 1983년에 Dunlop의 영국공장과 서독의 타이어공장을 사들이고, 84년에도 프랑스의 공장을 매입했지만 82년도 매출액이 7억 5,000만 달러에 불과하여 이번 분석대상에서 제외되었다. 각기업체 자료는 가급적 동일한 조건으로 취급하려 했지만, 각사의 정책상비밀로 하는 정보 때문에 제한을 받았다. 비교하기 쉽도록 하기 위하여 모든 금약은 미화 달러 기준으로 하였고, 자료는 대부분 각사의 결산보고서에 따른 것이다.

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Aromatic Fluorination by Decomposition of Triazenes in Ionic Liquids

  • Chu, Chan-Kook;Kim, Jong-Hwan;Kim, Dong-Wook;Chung, Kyoo-Hyun;Katzenellenbogen, John A.;Chi, Dae-Yoon
    • Bulletin of the Korean Chemical Society
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    • v.26 no.4
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    • pp.599-602
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    • 2005
  • The aromatic fluorination method involving the acid-catalyzed decomposition of a triazene in an ionic liquid is a very convenient and efficient way to prepare a variety of aromatic fluorides in a lab-scale. It should be particularly useful for the preparation aryl fluorides substituted with electron withdrawing substituents. Fluorination of triazene 1 (1.0 mmol) and p-toluenesulfonic acid (1.2 mmol) in an ionic liquid, 1-butyl-3-methylimidazolium tetrafluoroborate ([bmim][$BF_4$], 2.5 mL) proceeds very smoothly at 80 ${^{\circ}C}$ with or without an external source of fluoride, providing 73% yield in 30 min. Unlike diazonium salts, triazene precursors are stable enough to be stored for a long period of time without a noticeable decomposition.

The Change of the Digital Skin Temperature in Dental Outpatients by Biotrainer (Biotrainer를 이용한 치과외래환자의 수지피부온도변화에 관한 연구)

  • Gi-Hong Kwon;Myung-Yun Ko
    • Journal of Oral Medicine and Pain
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    • v.19 no.2
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    • pp.137-151
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    • 1994
  • In order to evaluate objectively the anxiety level in dental treatment, the author used Biotrainer(BF-120R), one of the skin temperature biofeedback apparatus, to examine 68 dental outpatients on their digital skin temperature change due to routine consecutive dental procedures(oral examination, anesthetic injection, cavity preparation, fissure sealing, polishing). The subjective anxiety level change was also evaluated by visual analog scale. The obtained results were as follows : 1. The skin temperature decreased through consecutive procedures and the temperature in each procedure decreased until 60sec, and then increased on 120sec. 2. The temperature changes in Preparation and Injection were greater than those in other procedures. 3. Generally, male exhibited more change of skin temperature in all procedures than female. 4. Type II, continuously decreasing after procedure, occupied the most in all patients and yhad the lowest beseline temperature. 5. The anxiety level of before-procedure was higher than that of after-procedure and the levels in Injection and Preparation were higher than in other procedures.

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Comparison of shallow junction properties depending on ion implantation and annealing conditions (이온주입 및 열처리 조건에 따른 박막접합의 특성 비교)

  • 홍신남;김재영
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.35D no.7
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    • pp.94-101
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    • 1998
  • To form 0.2 .mu.m p$^{+}$-n junctions, BF$_{2}$ ions with the energy of 20keV and the dose of 2*10$^{15}$ cm$^{-2}$ were implanted into the crystalline and preamorphized silicon substrates. Th epreamorphization was performed using 45keV, 3*10$^{14}$ cm$^{-2}$ As or Ge ions. Th efurnace annealing and rapid thermal annealing were empolyed to annihilate the implanted damage and to activate the implanted boron ions.The junction properties were analyzed with the measured values of the junction depth, sheet resistances, residual defects, and leakage currents. The thermal cycle of furnace annela followed by rapid thermal annela shows better characteristics than the annealing sequence of rapid thermal anneal and furnace annela.Among the premorphization species, Ge ion exhibited the better characteristics than the As ion.n.

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Acid and Base Catalyzed Intramolecular Cyclizations of N-Benzoylthiocarbamoyl-acetals

  • Lee, Bong-Yong;Kim, Choong-Sup;Lee, Jong-Wook
    • Archives of Pharmacal Research
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    • v.23 no.2
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    • pp.99-103
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    • 2000
  • Acid and base catalyzed intramolecular cyclizations of N-benzoylthioureidoacetal, contain-ing four functional groups adjacent to thiourea such as benzocarbamoyl, acetal, thioure and amide, were investigated. The condensation reaction of N-benzoyl thiocarbamoylgly-cine amide in the presence of 10% aqueous NaOH provided 1-(2,2-dimethoxy)ethyl-imi- dazolidine-2-thione exclusively. In the presence of pyridine, it was transformed to 2- thiohydantoin. N-Benzoyl thiocarbamoyl glycine amide was completely transformed to an iminothiazolidine exclusively in the presence of Lewis acid such as borontrifluoride ether-ate or trimethylsilyl iodide. 1-(2,2-Dimethoxy)ethyl-imidazolidine-2-thione was transformed to imidazole[2,1-b]thiazole and pyrazino[5,1-a]imidazole in the presence of $BF_3$.$ET_2$O and formic acid, respectively.

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하나로 1차 배관의 중성자 발생원 분석

  • 김명섭;홍광표;전병진
    • Proceedings of the Korean Nuclear Society Conference
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    • 1998.05a
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    • pp.227-232
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    • 1998
  • 하나로 1차 배관에서 중성자를 측정하고 발생 원인을 분석하였으며, 이를 통하여 중성자 계측 계통을 이용하여 핵연료 파손을 감시할 수 있는 가능성을 검토하였다. 중성자 측정에는 BF$_3$비례 계수관을 이용하였고, 1차 배관의 주 방사선원인 N-16에 의한 감마선 펄스의 영향은 무시 할 정도로 작았다. 중성자의 발생 원인을 규명하기 위해 원자로 정지 전후에 중성자 계수율의 변화를 측정하였다. 편자로의 정상 운전시 1차 배관에서 발생되는 중성자는 물속의 중수소가 고에너지 감마선을 흡수하여 방출하는 광중성자와 핵연료의 표면 오염에 의해 발생된 지발 중성자라고 가정하여 원자로 정지 전후의 발생량 변화를 계산하였다. 계산 결과와 측정값을 비교하여 1차 배관 주변에서 측정된 중성자 가운데 지발 중성자가 약 70 %, N-16에 의한 광중성자가 약 30%임을 확인하였다. 핵연료의 표면 오염 정도로 발생하는 지발 중성자도 민감하게 측정되므로, 이러한 지발 중성자 계측법이 핵연료의 손상 여부를 알아낼 수 있는 유용한 방법임을 확인할 수 있었다.

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포항방사광가속기 저장링시운전시의 방사선측정

  • 이희석;김제한;홍석모;박응수;정진화
    • Proceedings of the Korean Nuclear Society Conference
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    • 1995.05b
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    • pp.899-905
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    • 1995
  • 포항방사광가속기(Pohang Llght Sousrc)의 시운전기간동안 저장링건물에서의 방사선발생량을 측정하였다. Ionization Chamber와 Moderated BF$_3$ Counter로 구성된 지역방사선감시기시스템(RMS)외에 Pocket Inonization chamber, 연속기록이 가능한 Surveymeter를 고정 또는 이동시키면서 사용하였다. 시운전기간동안 선형가속기로부터의 입사시기와 저장시기에서의 방사선방출분포 및 선량의 정도가 명확히 구별되었으며 RF Cavity나 Bump Magnet등의 오동작에 의한 방사선 발생경로를 추정해 볼 수 있었다 여기서는 저장링실험지역 등에서의 공간선량분포와 부분차폐에 따른 변화를 측정하였으며 측정결과로부터 차폐계산시 사용된 방법을 통해 역으로 각 지역의 빔손실정도를 추정하고 계산식의 타당성을 검토해 보았다.

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