• Title/Summary/Keyword: $Al_3Sc$

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Relation between Metamorphic P-T Conditions and Boron Concentrations of Metasedimentary Rocks and Biotite Granitic Gneisses from NE Yeongnam Massif around Samcheok Area, South Korea (영남 육괴 북동부 변성퇴적암과 흑운모 화강편마암의 변성 온도-압력 조건과 전압 붕소 함량사이의 상관관계)

  • Cheong, Won-Seok;Sun, Gwang-Min;Na, Ki-Chang
    • Economic and Environmental Geology
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    • v.42 no.3
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    • pp.247-259
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    • 2009
  • This study is focused on the relationship between whole rock boron contents and metamorphic P-T conditions of metasedimentary rocks from northeastern Yeongnam massif around Samcheok area, Korea. Metamorphic P-T conditions of sillimanite and garnet zones based on the Ti-biotite geothermometer is 553-687$^{\circ}C$ and 582-722$^{\circ}C$ at 4-6 kbar, respectively. In the metasedimentary rocks, boron contents in whole rock decrease with increasing metamorphic grade, from sillimanite zone (9.60-189 ppm B) to garnet zone (2.63-15.97 ppm B), except one sample (90.9 ppm B) from garnet zone containing graphites. Boron depletion in garnet zone has relation with mode of tourmaline which are broken down with increasing metamorphic temperature. Boron contents are indirectly proportional to major and trace elements such as $Al_2O_3$, MgO, $Fe_2O_3$, $K_2O$, Li, Ba, Sc, Co, Cr, Rb and Cs that are abundant in tourmalines. In conclustion, tourmalines and graphite are modulator of boron contents in metasedimentary rocks. In the biotite granitic gneisses, boron contents (2.62-12.2 ppm B) are similar or lower than those of metasedimentary rocks and have no relation with metamorphic P-T conditions.

Geochemical Characteristics of Volcanics from Yangsan, Kyeongnam Province (경남(慶南) 양산지역(梁山地域)에 분포(分布)하는 화산암류(火山岩類)의 지구화학적(地球化學的) 특성연구(特性硏究))

  • Kim, M.Y.;Shin, H.J.;Lee, P.K.;Jang, Y.N.
    • Economic and Environmental Geology
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    • v.21 no.2
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    • pp.139-148
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    • 1988
  • The altered volcanic rocks, ranging from tuffaceous to andesitic rocks are widely distributed around the "caldera" area in the southeastern part of Kyeongsang province. The volcanic activity and tectonic movement are assumed to be followed by the hydrothermal activities in the area. From the mineral assemblage the type of alteration can be divided into two types; propylitic and argillic. The average concentration of gold in hydrothermally altered rocks is somewhat lower (about 20 ppb) than that of fresh rocks (45-25 ppb), but for Ag, vice versa. During the hydrothermal process, the concentration of the trace elements Ag, Hg, Co, As, Hf, Sc, Si, Al increased, and that of Na, Rb, K, Au, Mg, Ca etc. decreased. The high anomalous contents of silver for altered rocks range from 4-7 ppm and 1-3 ppm for relatively fresh rocks.

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한국에 분포하는 한약자원식물의 무기물 함량에 관한 연구 제 2 보 ( The Mineral Content of Medical Wild Plant Resources in Korea ( II ) )

  • 이상래
    • Korean Journal of Plant Resources
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    • v.3 no.2
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    • pp.115-121
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    • 1990
  • In view of the results to have measured metallic elements which is included in 40 sorts of herb medicines and surveyed their distribution, ninekinds of metals including Co, Ce, Ga, 71, Cd, As, Sbr Bu. Pb, are never orlittle included in almost herb medicines. Other twenty four sorts of ele-ments (Mo, Sc, Be, V, Ni, Su, Se, Ba, Cr, Su, Ti, B, Li, Mg, Ca, Sr, Mnl Fe,Cu, Zn. p, Al, Na, K) are metals that are included in large quentities incomparison with others. Selagirellae Radix contains is kinds of metallicelements more then other herb medicines does. The content of elements ofinorganic metal differs greatly according to the part of herb medicines .

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한국에 분포하는 한약자원식물의 무기물 함량에 관한 연구 제1 보 ( The Mineral Content of Medical Wild Plant Resources in Korea ( I ) )

  • 이상래
    • Korean Journal of Plant Resources
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    • v.3 no.2
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    • pp.107-114
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    • 1990
  • In view of the results to have measured metallic elements which is included in 45 sorts of herb medicines and surveyed their distribution, 8 kinds ofmetals including Co, Ge, Ga, TL, Cd, As, 8i, Pb, are never or little includedin almost herb medicines . Other twenty-five sorts of elements (Mo, Sc, Be, V,Ni, Sn, Se, Ba, Cr, Sb, Si, Ti, B, Li, Mg, Ca, Cr, Mn, Fe, Cu, Zn, p, Al, Na,K) are more or Less included in all herb Bedicines ana Na, Ca, p and K aremetals that are included in Large quentities in comrarison with others . Patri-uiae Radix Contains 7 kinds of metal lic elements more than other herb medicinesdoes .

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더덕 ( 사삼 )의 재배방법별 일반성분 및 무기성분에 관한 연구 ( Proximate and Mineral of Dried Wild and Cultivated Codonopsis lanceolata Benth , et Hook , Fil , of Different Cultivated Groups )

  • 신수철
    • Korean Journal of Plant Resources
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    • v.4 no.2
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    • pp.39-45
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    • 1991
  • Proximate compositions of the roots of cultured and wild Codonopsis lanceolata were examined as tile basic reasearch for the study of their source of processed foods.No significant difference in the contents was found between the wild root and thecultivated at 3$0^{\circ}C$ in biotronroom. In view of the results to have measured mineralswhich is included in 14 sorts of Codonopsis lanceolata and surveyed their distribution.12 kinds of minerals including T1, Co, Ge, Sm, Mo, Sc, Be, Cd, As, Ga, Bi, ph are ne-vel or little included in almost source. Other twenty-one sorts of minerals (Ni, Se,Ba, Sb, Si, Ti, B, Li, Ifs, Ca, Sr, Mn, Fe, Cu, Zn, p, Al, Na, V, Cr, K) are more or less in-cluded in all source and Ca, Mg, p, K, and Fe are metals that are included in large qu-entities in comparison with others. No minerals difference in the contents was foundbetween the cultivated temperature. The content of elements of inorganic metal differsaccording to the part of C. lanceolata.

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Geochemical Characteristics of A-type granite in Dongcheondong, Gyeongju (경주 동천동 일대에 분포하는 A-형 화강암의 지화학적 특성)

  • Myeong, Bora;Ju, Jiwon;Kim, Junghoon;Jang, Yundeuk
    • The Journal of the Petrological Society of Korea
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    • v.26 no.3
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    • pp.271-280
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    • 2017
  • The Dongcheondong granite is alkali feldspar granite in Dongcheondong, Gyeongju. The granite is coarse grained and consists of alkali feldspar, quartz, amphibole, and biotite. Alkali feldspar is perthitic orthoclase and quartz often shows undulatory extinction. Plagioclase often shows albite twins, and biotite and amphibole emplace as interstitial minerals. The Dongcheondong granite is plotted in A-type area having high ($Na_2O+K_2O)/Al_2O_3$ and low (MgO+CaO)/FeOT ratio. The Dongcheondong A-type granite has higher $SiO_2$, $Na_2O$, $K_2O$, Zr, Y, and REE contents (except for Eu) and lower $TiO_2$, $Al_2O_3$, CaO, MgO, Sr, Ba, and Eu contents than I-type granites in Gyeongsang Basin. These results show that the geochemical characteristics of the Dongcheondong A-type granite are distinguished from I-type granite in Gyeongsang Basin. A-type granite in the Dongcheondong is thought to has been generated by partial melting of I-type tonalite or granodiorite.

An SOFC Cathode Composed of LaNi0.6Fe0.4O3 and Ce(Ln)O2 (Ln=Sm, Gd, Pr)

  • Chiba, Reiichi;Komatsu, Takeshi;Orui, Himeko;Taguchi, Hiroaki;Nazawa, Kazuhiko;Arai, Hajime
    • Journal of the Korean Ceramic Society
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    • v.45 no.12
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    • pp.766-771
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    • 2008
  • We fabricated single cells with a cathode consisting of a $LaNi_{0.6}Fe_{0.4}O_3-Ce_{0.8}Sm_{0.2}O_{1.9}$ composite (LNF-S20DC composite) active layer and an LNF current collecting layer on a ${0.89ZrO_2}-{0.10Sc_2}{O_3}-0.01{Al_2}{O_3}$ electrolyte sheet. The cathode layers were prepared by the screen-printing method. The cathode properties of these cells were measured by the AC impedance method at $800^{\circ}C$. The cathodes with the ceria-LNF composite active layer exhibited high power performance prior to current loading. We investigated the influence of the mixture ratio of LNF and S20DC on the cathodes properties. The Sm in the ceria particles of the composite cathode was substituted with other rare-earth elements. Cathodes with Pr and Gd co-doped ceria in the active layer provided the better performance than those with Sm- or Gd-doped ceria.

Progress in Novel Oxides for Gate Dielectrics and Surface Passivation of GaN/AlGaN Heterostructure Field Effect Transistors

  • Abernathy, C.R.;Gila, B.P.;Onstine, A.H.;Pearton, S.J.;Kim, Ji-Hyun;Luo, B.;Mehandru, R.;Ren, F.;Gillespie, J.K.;Fitch, R.C.;Seweel, J.;Dettmer, R.;Via, G.D.;Crespo, A.;Jenkins, T.J.;Irokawa, Y.
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.3 no.1
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    • pp.13-20
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    • 2003
  • Both MgO and $Sc_2O_3$ are shown to provide low interface state densities (in the $10^{11}{\;}eV^{-1}{\;}cm{\;}^{-2}$ range)on n-and p-GaN, making them useful for gate dielectrics for metal-oxide semiconductor(MOS) devices and also as surface passivation layers to mitigate current collapse in GaN/AlGaN high electron mobility transistors(HEMTs).Clear evidence of inversion has been demonstrated in gate-controlled MOS p-GaN diodes using both types of oxide. Charge pumping measurements on diodes undergoing a high temperature implant activation anneal show a total surface state density of $~3{\;}{\times}{\;}10^{12}{\;}cm^{-2}$. On HEMT structures, both oxides provide effective passivation of surface states and these devices show improved output power. The MgO/GaN structures are also found to be quite radiation-resistant, making them attractive for satellite and terrestrial communication systems requiring a high tolerance to high energy(40MeV) protons.

Block Shear Behavior of Cold-Formed Duplex Stainless Steel (STS329FLD) Welded Connection with Base Metal Fracture (냉간성형 듀플렉스계 스테인리스강(STS329FLD) 용접접합부 모재 블록전단파단 거동)

  • Hwang, BoKyung;Kim, TaeSoo
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.35 no.4
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    • pp.157-165
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    • 2019
  • Recently, lean duplex stainless steel, STS329FLD with less nickel (reduced to 0.5~1.5%) has been developed as a substitute of austenitic stainless steel (8%~10.5% nickel in STS304) and included in Korean standards (KS). This paper investigates the block shear behavior of cold-formed duplex stainless steel (STS329FLD, nominal plate thickness of 1.5mm) fillet-welded connection with base metal fracture. Main variables are weld lengths in the longitudinal and the transverse directions of applied force ranged from 20mm to 50mm. As a result, specimens failed by typical block shear facture (the combination of gross section tensile fracture and shear fracture or shear yielding) and ultimate strength of the specimens got higher with the increase of weld length. Block shear fracture strengths predicted by current design specifications (KBC2016/AISC2016 and EC3) and existing proposed equations for welded connections by Topkaya, Oosterhof & Driver and Lee et al. were compared with test strengths. KBC2016/AISC2016 and EC3 design specifications underestimated block shear strength of STS329FLD welded connections by on average 24%, 29%, respectively and Oosterhof & Driver, Topkaya and Lee et al's equations overestimated the ultimate strength of the welded connection by the range of 3% to 44%.

Fundamental Study on Recycling as Construction Material of Dredged Harbor Soil Mixed with Clay and Glass Frit (점토와 유리프리트를 혼합한 항만준설토의 건축자재 재활용에 관한 기초연구)

  • Im, Dong-Su;Kim, Kyung-Nam;Cho, Yeon-Bae;Park, Joon-Seok
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.4
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    • pp.575-585
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    • 2013
  • This research was performed to evaluate the recycling feasibility as a construction material of dredged harbor soil mixed with clay and glass frit. Concentration of heavy metals of the dredged soil from D harbor was severly high, showing Zn of 526.0~13,150.1 mg/kg. The dredged soil was maily composed of 48.30 wt% $SiO_2$, 16.60 wt% $Al_2O_3$, 10.10 wt% CaO, 7.75 wt% $Fe_2O_3$. The clay and the glass frit contained 70.82 wt% $SiO_2$ and $Al_2O_3$ 18.78 wt%, and 71.75 wt% $SiO_2$, 13.99 wt% CaO, 8.51 wt% $Na_2O$, respectively. After adding 10~40 wt% to the clay and sintering them at $1,000^{\circ}C$ or $1,100^{\circ}C$, the compressive strength of the sintered specimens showed $132.6{\sim}178.5kgf/cm^2$ or $581.2{\sim}793.7kgf/cm^2$, respectively. In case of SC46 with the addition 40 wt% of the dredged soil to the clay, the compressive strength ($793.7kgf/cm^2$) of specimen sintered at $1,100^{\circ}C$ was over 5 times higher than that at $1,000^{\circ}C$. The specimen mixed with 40 wt% of dredged soil, 60 wt% of clay and 1 wt% of glass frit satisfied the 1st grade standard for clay brick by KS L 4201. The results of all specimens by Korean Standard Leaching Test also satisfied the standard criteria.