• 한국세라믹학회지
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• 제37권4호
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• pp.354-358
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• 2000

Tetragonal (t)-ZrO2/Al2O3 composites doped with Y2O3, Nb2O5, and Fe2O3 ((Y, Nb, Fe)-TZP/Al2O3) were prepared over the range containing Fe2O3 from 0.1 to 0.5 mol% with 0.1 mol% intervals to evaluate the effect of Fe2O3 addition on chromaticity, hydrothermal stability, and mechanical property of the composites. After autoclaving for 20 h at 18$0^{\circ}C$ under 3.5 MPa water vapor pressure, no tlongrightarrowm phase transformation was observed probably due to the preferential solid solubility of Fe2O3 in Al2O3, the presence of the rigid Al2O3 particles, and the inherent phase stability of (Y, Nb)-TZP. The optimized strength and the fracture toughness of the composite were 700 MPa and 8.5 MPa.m1/2, respectively, when 0.1 mol% Fe2O3 was added. The composites have shown a gradual color change from a slightly white ivory to a pale yellowish brown with increasing the Fe2O3 concentration.

• 한국전기전자재료학회논문지
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• 제30권1호
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• pp.7-12
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• 2017

3YSZ + (x) $Al_2O_3$ composites (x = 20, 40, 60, 80 wt%) were fabricated and the influences of particle sizes of $Al_2O_3$ on their microstructures and mechanical properties were investigated with XRD, SEM, vickers hardness and fracture toughness. $Al_2O_3$-3YSZ composites containing $Al_2O_3$ powder of a $0.3{\mu}m$ and an $1.0{\mu}m$, which are here in after named as $Al_2O_3$($0.3{\mu}m$)-3YSZ and $Al_2O_3$($1.0{\mu}m$)-3YSZ, respectively, were made by mixing raw materials, uni-axial pressing and sintering at $1,400^{\circ}C$, $1,500^{\circ}C$, and $1,600^{\circ}C$. $Al_2O_3$($0.3{\mu}m$)-3YSZ composites show the higher density and the better mechanical properties than $Al_2O_3$($1.0{\mu}m$)-3YSZ composites. The Vickers hardness of the $Al_2O_3$($0.3{\mu}m$)-3YSZ composites show a peak value of 1,997 Hv at the content of 60 wt% $Al_2O_3$, which is a slightly higher value in comparison with 1,938 Hv of the $Al_2O_3$($1.0{\mu}m$)-3YSZ composite. However, the fracture toughness of $Al_2O_3$-3YSZ composites monotonically increases with decreasing the content of $Al_2O_3$ without any peak values. $Al_2O_3$($0.3{\mu}m$)-3YSZ and $Al_2O_3$($1.0{\mu}m$)-3YSZ composites sintered at $1,600^{\circ}C$ have a maximum value of a $6.9MPa{\cdot}m^{1/2}$ and a $6.2MPa{\cdot}m^{1/2}$, respectively at the composition of containing 20 wt% $Al_2O_3$. It should be noticed that the mechanical properties and the sintering density of the $Al_2O_3$-3YSZ composites can be enhanced by using more fine $Al_2O_3$ powder due to their denser microstructure and smaller grain size.

• The Korean Journal of Ceramics
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• 제5권4호
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• pp.371-374
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• 1999

Y2O3 and Nb2O5 co-doped tetragonal zirconia polycrystals((Y, Nb)-TZP) containing 10 to 30 vol% $Al_2O_3$ were prepared and hydrothermal stability of the composites was evaluated after aging for 5 h at the temperature range of $150^{\circ}C$ $250^{\circ}C$ under 4 MPa $H_2O$ vapor pressure in an autoclave. The (Y, Nb)-TZP/Al2O3 composites showed excellent phase stability under the hydrothermal conditions, as compared with the 3Y-TZP/$Al_2O_3$ composites, due to the combined effects of the Y-Nb ordering in the $t-ZrO_2$ lattice, the reduction of oxygen vacancy concentration, and the $Al_2O_3$ addition. The strength and fracture toughness of the (Y, Nb)-TZP/$Al_2O_3$ composite, containing 20 vol% of 2.8 $Al_2O_3$ particles, were 700 MPa and 8.1 MP.$am^{1/2}$, respectively.

• 한국주조공학회지
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• 제24권2호
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• pp.108-114
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• 2004

$Al_2O_3$, SiC reinforced Al matrix composites were fabricated by centrifugal spray casting method and their wear resistance characteristics have been studied. Particles are generally uniformly distributed in the microstructure of as-cast specimens. In order to investigate the effect of secondary deformation, hot rolling was performed for each specimen of pure Al matrix composites with a reduction of 10, 20, 30, 40 and 50% at $400{\sim}500^{\circ}C$, respectively. Microstructure of specimen showed that particle distribution density and hardness increased because of increasing of reduction ratio. Wear test with a various sliding velocity of 1.98, 2.38, 2.88 and 3.53m/sec showed that the wear resistance characterization of composite improved remarkably compared to the normal alloy and performs without reinforced particles. Microstructural observation for the worn surface of pure Al specimens without particles showed that a change in wear mechanism seemed to separate layer by surface fatigue. In other case of Al composite reinforced with $Al_2O_3$ and SiC, the grinder type of wear mechanism was shown.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제49권9호
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• pp.516-522
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• 2000

The mechanical and electrical properties of the hot-pressed and annealed $\beta-SiC-ZrB_2$ electroconductive ceramic composites were investigated as a function of the liquid forming additives of$Al_2O_3+Y_2O_3$ Phase analysis of composites by XRD revealed $\alpha-SiC(6H) ZrB_2\; and YAG(Al_5Y_3O_{12})$ The relative density of composites were increased with increased Al2O3+Y2O3 contents. The Flexural strength showed the highest value of 390.6MPa for composites added with 20wt% Al2O3+Y2O3 additives at room temperature. Owing to crack deflection crack bridging phase transition and YAG of fracture toughness mechanism the fracture toughness showed the highest value of 6.3MPa.m1/2 for composites added with 24wt% Al2O3+Y2O3 additives at room temperature. The resistance temperature coefficient showed the value of$ 2.46\times10^{-3}\;, 2.47\times10^{-3},\; 2.52\times10^{-3}/^{\circ}C$ for composite added with 16, 20, 24wt% Al2O3+Y2O3 additives respectively. The electrical resistivity of the composites was all positive temperature coefficient resistance(PTCR) in the temperature range of $256{\circ}C\; to\; 900^{\circ}C$.

• 한국분말재료학회지
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• 제10권4호
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• pp.235-240
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• 2003

The $Al/Al_2O_3$ composites fabricated by powder in sheath rolling method were cold-rolled by 50% reduction and annealed for 1.8 ks at various temperatures ranging from 200 to 50$0^{\circ}C$, for improvement of the mechanical properties. The mechanical properties and texture of the composites after rolling and annealing were investigated. The tensile strength of the composites increased significantly due to work hardening after cold rolling, however it decreased due to restoration after annealing. The strength of the composites was improved by thermo mechanical treatment. On the other hand, the texture evolution with annealing temperatures wa,i different between the unreinforced material and the composites. The unreinforced material showed a deformation (rolling) texture of which main component is ｛112｝<111> at annealing temperatures up to 30$0^{\circ}C$. However, the composites have already exhibited a recrystallization texture of which main component is ｛001｝<100> after annealing at 20$0^{\circ}C$. This proves that the critical temperature for recrystailization is lower in the composites than in the unreinforced ones.

• 한국세라믹학회지
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• 제28권1호
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• pp.11-18
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• 1991

A precipitation method, one of the most effective liquid phase reaction methods, was adopted in order to prepare high-tech Al2O3/ZrO2 composite ceramics, and the effects of stress-induced phase transformation of ZrO2 on thermal shock behavior of Al2O3-ZrO2 ceramics were investigated. Al2(SO4)3.18H2O, ZrOCl2.8H2O and YCl3.6H2O were used as starting materials and NH4OH as a precipitation agent. Metal hydroxides were obtained by single precipitation(process A) and co-precipitation(process B) method at the condition of pH=7, and the composition of Al2O3-ZrO2 composites was fixed as Al2O3-15v/o ZrO2(+3m/o Y2O3). Critical temperature difference showing rapid strength degradation by thermal shock showed higher value in Al2O3/ZrO2 composites(process A : 20$0^{\circ}C$, process B : 215$^{\circ}C$) than in Al2O3(175$^{\circ}C$). The improvement of thermal shock property for Al2O3/ZrO2 composites was mainly due to the increase of strength at room temperature by adding ZrO2. The strength degradation was more severe for the sample with higher strength at room temperature. Crack initiation energies by thermal shock showed higher values in Al2O3/ZrO2 composites than in Al2O3 ceramics due to increase of fracture toughness by ZrO2.

• 대한기계학회논문집A
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• 제20권3호
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• pp.753-764
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• 1996

The metal matrix composites(MMC) are currently receiving a great deal of attention. These composites possess exellent mechanical and physical properties such as modulus, strength, wear resistance and thermal stability, which make them very attractive for use in automotive piston. In this study, $Al/{Al_2}{O_3}$(15%) composites are fabricated by the squeeze casting method. Mechanical properties such as tensile strength and ductility are performed at room and elevated temperature($250^{\circ}C$ and $350^{\circ}C$), respectively. Through thermomechanical analyser, thermal expansion coefficient of $Al/{Al_2}{O_3}$ composites are conducted for ranging from room temperature to ($400^{\circ}C$.And bending fatigue tests are also performed by the rotary bending machine at room temperature.The tensile strength and elastic modulus have been improved up to 38% and 35% by the addition of the reinforcements, respectively. Thermal expansion coefficients of MMCs which is located normal and parralel to the applied pressure are showed slightly different less than 10%. Fatigue strengh of the composite was improved by about 20% compared with that of unreinforced Al alloy. The results of this study will be used to understand the basic fracture behavior of MMCs and eventually to expand the applocation of MMCs as a machine parts undertaken various loadings.

• Journal of Welding and Joining
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• 제20권2호
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• pp.109-115
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• 2002

In the case of using high temperature by coating ceramic/metal, large stress was produced due to difference of thermal expansion coefficient between those. And then lead to delamination. In order to relaxation of the stress A1$_2$O$_3$/SS316 composite powders with $10wt.%Al_2O_3$ compositional gradient and $10wt.%Al_2O_3$ agglomerated powder were made by spray drying method. These powders were sintered to improve the strength and to be plasma sprayed in order to fabricate the FGC(functionally graded coating). The influence of gun power, working distance and Ar pressure on the microstructure of the coating layer was studied in order to optimize the plasma spray conditions. It was proven that the optimum conditions were 40kw gun power, 5cm working distance and $100ft^3/h$ Ar flow for both powders. FGC with 10 compositional steps was fabricated and the total thickness was 1.3mm. FGC was heat treated at $1100^{\circ}C$for 10hours to evaluate the heat resisting characteristics.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1999년도 추계학술대회 논문집
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• pp.335-338
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• 1999

The effect of monoclinic $ZrO_2$(pure) and tetragonal $ZrO_2$ containing 5.35wt% $Y_2$$O_3$(Y-TZP) addition on the mechanical properties and thermal shock resistance of $Al_2$$O_3$ ceramic were investigated. The addition of $ZrO_2$(m) and Y-TZP increased sintering density of $Al_2$$O_3$. The vickers hardness increased with increasing the volume fraction of Y-TZP going through a maximum at 20wt%. The hardness of the specimens was found to be depend on the sintering density. With increasing the volume fraction of $ZrO_2$(m) and Y-TZP, the fracture toughness of the composite is increased. This result may be taken as evidence that toughening of ${Al_2}{O_3}$ can also be achieved by the transformation toughening and microcrack toughening of $ZrO_2$. The property of the& shock for ${Al_2}{O_3}$-$ZrO_2$ composites was improved by increasing the volume fraction of monoclinic $ZrO_2$(pure).Grain size increased with increasing the volume fraction of $ZrO_2$.