• Title/Summary/Keyword: $Al_2O_3

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Study on the Oxidation Process of Potential Acid Sulfate Soil (잠재 산성황산염토양의 산화과정에 대한 연구)

  • Han, Kang-Wan;Chun, Jae-Chul;Cho, Jae-Young;Kim, Geum-Hee;Ann, Yeoul
    • Korean Journal of Soil Science and Fertilizer
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    • v.29 no.3
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    • pp.243-248
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    • 1996
  • To find out the oxidation process of potential acid sulfate soil(PASS) along with time. the PASS were treated with lime and ammonia water to adjust soil pH in laboratory column condition. pH range of PASS showed 6.5 to 7.5. however, complete oxidized PASS by $H_2O_2$ showed 2.1 to 2.5. After pilling the PASS under the natural condition. oxidation occured slowly from surface of the pilled soil. The oxidation of PASS proceeded slowly when the soil was in submerged condition. but quickly in dried condition. The content of sulfide-sulfur in PASS sharply decreased after exposing to the air and the decreasing rate was greater in dried than in submerged condition. The content of sulfate-sulfur continuously decreased in submerged condition. but increased in dried condition. Contents of $Fe^{+{+}}$ and $Al^{+{+}}$ in PASS were generally increased with time and the increasing rate was greater in submerged than in dried condition. Liming to PASS was slowly acting to pH change and ammonia water caused fast pH change within a short period of time. The contents of sulfate-sulfur and exchangeable aluminum in drainage water decreased with time and the contents of sulfide-sulfur and ferrous iron were increased.

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Estimation of Refractive Index in MIR range from the Reflectance Measurements for IR Optics Materials (반사율 측정에 의한 적외선 광학재료의 중적외선 굴절률 추정)

  • Jin, Doo-han;Jeong, Kyung-Seok
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.6
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    • pp.411-416
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    • 2020
  • An optical arrangement has been set inside a photo-spectrometer to measure the reflectance of IR optics materials in mid IR range. The optical arrangement consists of equally spaced 4 gold coated full reflecting mirrors with the incidence angle of 45°. Baseline beam intensity IB has been measured while the beam proceeds through the 4 mirrors. Reflectance of a mirror has been estimated from the IB. And the beam intensity IS with the specimen in the optical path has been measured with the 4th mirror replaced with the specimen. Reflectance of the specimen has been estimated from the value of IS/IB. Then the estimated reflectance has been put in Fresnel equation relating reflectance and refractive index(RI) to estimate the RI of the material. Measurement has been made for sapphire, germanium, magnesium fluoride, and zinc sulfide. The estimated RI of the materials are closely matching with reference data and the maximum difference less than 2% over the wavelength range 3-5㎛ for all materials tested. As an FT-IR photo-spectrometer with a broadband wavelength infrared light source is used, this method has the advantage of measuring the refractive index at multiple wavelengths in a single measurement.

A Study on the Phase Change and Microstructure Change According to the Sintering Temperature of Cement Clinker Applied with Coal Ash (석탄재를 적용한 시멘트 클링커의 소성온도에 따른 상변화 및 미세구조 변화 고찰)

  • Yoo, Dong-Woo;Im, Young-Jin;Choi, Sang-Min;Lee, Chang-Hyun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.4
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    • pp.553-560
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    • 2021
  • In this study, cement clinker using a pure sample and clinker using 7% coal ash were sintered at a temperature of 1050~1500℃. Changes in the content of cement minerals and changes in microstructure by sintering temperature were reviewed. The application of coal ash as a raw material for cement clinker was applicable as a source of Al2O3 and SiO2. At a sintering temperature of 1350℃ or higher, the cement clinker applied with coal ash showed the same level of mineral content as compared to the cement clinker applied with pure raw material. The microstructure also showed a similar state, confirming that coal ash can be used as a raw material for cement. In XRD-Reitveld analysis, a maximum amount of Belite was produced at 1250℃. The conversion from Belite to Alite was observed from 1350℃. From 1350℃, the interstitial phase and the mineral phase presumed to be alite were distinguished. It was clearly distinguished from 1400℃. As the sintering temperature increased, the shape and boundary of the crystal phase became clear, and the size of the crystal phase was also increased.

Effects of Chemical Composition and Particle Size of Starting Aluminum Source on the Spheroidization in the Flame Fusion Process (화염용융법에 의한 구상 알루미나 제조에 미치는 초기 알루미나 원료의 화학조성과 입도의 영향)

  • Eom, Sun-Hui;Pee, Jae-Hwan;Lee, Jong-Keun;Hwang, Kwang-Taek;Cho, Woo-Seok;Kim, Kyeong-Ja
    • Journal of Powder Materials
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    • v.16 no.6
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    • pp.431-437
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    • 2009
  • Various inorganic fillers improve the thermal conductivity and physical properties of organic products. Alumina has been used a representative filler in the heat radiation sheet for the heat radiation of electric device. The high filling rate of alumina increases the thermal conductivity and properties of products. We successfully developed the spherical alumina by flame fusion process using the oxygen burner with LPG fuel. In the high temperature flame (2500$\sim$3000$^{\circ}C$) of oxygen burner, sprayed powders were melting and then rotated by carrier gas. This surface melting and rotation process made spherical alumina. Especially effects of chemical composition and particle size of stating materials on the melting behavior of starting materials in the flame and spheroidization ratio were investigated. As a result, spheroidization ratio of boehmite and aluminum hydroxide with endothermic reaction of dehydration process was lower than that of the sintered alumina without dehydration reaction.

Trends of Breast Cancer and its Management in the Last Twenty Years in Aden and Adjacent Governorates, Yemen

  • Harhra, Nasser Aa;Basaleem, Huda O.
    • Asian Pacific Journal of Cancer Prevention
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    • v.13 no.9
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    • pp.4347-4351
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    • 2012
  • Background: Breast cancer is the most common cancer of women and the principal cause of death in middle aged women. The objective of this study was to describe the trend of breast cancer and its management in Aden and adjacent south-eastern governorates of Yemen during the last 20 years. Patients and Methods: This is a retrospective analysis of previous studies on patients with breast cancer in Aden and adjacent south-eastern governorates, Yemen (January 1989 through December 2007). The studied variables were: sex, age, time and type of presentation, disease stage, pathological types and the performed surgical treatment. The sources of information were the treatment registry of Aden health office, archives of Al-Gamhouria teaching hospital; major referral and other public and private hospitals in Aden and Aden Cancer Registry. Results: The total number of patients was 476, 99% being females. The age range was 19-88 years. The most affected age was 30-50 years (60.5%), 95% presenting after one month of having breast symptoms. Forty-five percent presented with signs of advanced local disease, while 59.2% had palpable axillary lymph nodes on presentation. Early breast cancer (stages I-II) occurred in 47%, and late breast cancer (stages III-IV) in 51.5%. Invasive ductal carcinoma was the commonest pathology (89.3%). The main surgical treatment was mastectomy (modified radical mastectomy (50%). Conclusion: Breast cancer is predominantly a disease of young with late presentation and advanced disease. Improving health awareness and earlier diagnosis of the disease by health education, encouraging breast self-examination, and providing the mammography equipment and mammary clinics in hospitals are recommended. Establishment of oncology and radiotherapy centers in Aden is a necessity.

UY Ursae Majoris: An A-Subtype W UMa System with a Very Large Fill-Out Factor and an Extreme Mass Ratio

  • Kim, Chun-Hwey;Song, Mi-Hwa;Park, Jang-Ho;Jeong, Min-Ji;Kim, Hye-Young;Han, Cheongho
    • Journal of Astronomy and Space Sciences
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    • v.36 no.4
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    • pp.265-281
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    • 2019
  • We present new BVRI light curves of UY UMa with no O'Connell effect and a flat bottom secondary eclipse. Light curve synthesis with the Wilson-Devinney code gives a new solution, which is quite different from the previous study: UY UMa is an A-subtype over-contact binary with a small mass ratio of q = 0.21, a high inclination of 81°.4, a small temperature difference of ΔT=18°, a large fill-out factor of f = 0.61, and a third light of approximately 10% of the total systemic light. The absolute dimensions were newly determined. Seventeen new times of minimum light have been calculated from our observations. The period study indicates that the orbital period has intricately varied in a secular period increase in which two cyclical terms with periods of 12y.0 and 46y.3 are superposed. The secular period increase was interpreted to be due to a conservative mass transfer of 2.68 × 10-8 M/yr from the less massive to the more massive star. The cyclical components are discussed in terms of double-light time contributions from two additional bound stars. The statistical relations of Yang & Qian (2015) among the physical parameters of 45 deep, low mass ratio contact binaries were revisited by using the physical parameters of UY UMa and 25 Kepler contact binaries provided by Şenavci et al. (2016).

Influence of Subsurface Layer on the Indentation Damage Behavior of YSZ Thermal Barrier Coating Layers Deposited by Electron Beam Physical Vapor Deposition (전자 빔 물리적 증착(EB-PVD)법으로 코팅된 YSZ 열차폐층의 압흔손상 거동에 대한 하부층의 영향)

  • Heo, Yong-Suk;Park, Sang-Hyun;Han, In-Sub;Woo, Sang-Kuk;Jung, Yeon-Gil;Paik, Un-Gyu;Lee, Kee-Sung
    • Journal of the Korean Ceramic Society
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    • v.45 no.9
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    • pp.549-555
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    • 2008
  • The thermal barrier coating must withstand erosion when subjected to flowing gas and should also maintain good stability and mechanical properties while it must also protect the turbine component from high temperature, hot corrosion, creep, and oxidation during operation. In this study we investigated the influence of subsurface layer, $Al_2O_3$ or NiCrCoAIY bond coat layer, on the indentation damage behavior of YSZ thermal barrier coating layers deposited by electron beam physical vapor deposition (EB-PVD). The bond coat is deposited using different process such as air plasma spray (APS) or spray of high velocity oxygen fuel (HVOF) and the thickness is varied. Hertzian indentation technique is used to induce micro damages on the coated layer. The stress-strain behaviors are characterized by results of the indentation tests.

Effect of Electrolyte on Preperation of Porous Alumina Membrane by Anodic Oxidation (양극산화에 의한 다공성 알루미나 막의 제조시 전해질의 영향)

  • Lee, Chang-Woo;Hahm, Yeong-Min;Kang, Hyun-Seop;Chang, Yoon-Ho
    • Applied Chemistry for Engineering
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    • v.9 no.7
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    • pp.1047-1052
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    • 1998
  • The porous alumina membrane was prepared from aluminum metal(99.8%) by anodic oxidation using DC power supply of constant current mode in aqueous solution of sulfuric, oxalic, phosphoric and chromic acid. Pore size and distribution, membrane thickness, morphology and crystal structure were examined with several anodizing conditions : reaction temperature, electrolyte concentration, current density and electrolyte type. It was found that ultrafiltration membrane was fabricated in electrolyte of sulfuric, and oxalic acid. On the other hand, microfiltration membrane was fabricated in electrolyte of phosphoric, and chromic acid. Also, it was shown that crystal structure of porous alumina membrane prepared in sulfuric, oxalic, and phosphoric acid was amorphous, whereas porous alumina membrane prepared in chromic acid had ${\gamma}$ type of crystal structure.

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Superoxide Dismutase Isoenzyme Activities in Plasma and Tissues of Iraqi Patients with Breast Cancer

  • Hasan, Hathama Razooki;Mathkor, Thikra Hasan;Al-Habal, Mohammed Hasan
    • Asian Pacific Journal of Cancer Prevention
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    • v.13 no.6
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    • pp.2571-2576
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    • 2012
  • Breast cancer is the first of the most common ten cancers in Iraq. Its etiology is multifactorial, oxidative stress and lipid peroxidation being suggested to play important roles in carcinogenesis. The purpose of this study was to investigate the oxidant-antioxidant status in breast cancer patients, by measuring SOD isoenzyme activities (total SOD, CuZn-SOD, Mn-SOD and EC-SOD) in plasma and breast tumors, and by estimating thiobarbituric reactive substances (TBRS) in tissue homogenates. General increase in total SOD activity was observed in plasma and tissue samples of breast tumors, greater in the malignant when compared to benign group (p<0.05). Mn-SOD showed a significant decrease in tissue malignant samples (p<0.05), and insignificant decrease in plasma malignant samples compared with control and benign samples. Plasma EC-SOD activity in both patient benign and malignant breast tumors demonstrated 3.5% and 22.8% increase, respectively. However, there was a decrease in tissue EC-SOD activity in malignant breast tumors when compared with benign. A similar tendency was noted for TBRS. We suggest that elevated total SOD might reflect a response to oxidative stress, and then may predict a state of excess reactive oxygen species in the carcinogenesis process. If there is proteolytic removal of the heparin binding domain, EC-SOD will lose its affinity for the extracellular matrix and diffuse out of the tissue. This will result in a decreased EC-SOD activity, thus leading to an increase in the steady-state concentration of $O^{2-}$ in this domain, and increase in EC-SOD activity in the extracellular fluid. This might explain the results recorded here concerning the decrease in tissue EC-SOD activity and increase in plasma of breast cancer patients.

An Antibiotic against Bacillus amyloliquefaciens from Streptomyces sp. KM-48 (Streptomyces 속 KM-48 균주가 생성하는 Bacillus amyloliquefaciens 에 대한 항생물질)

  • Lee, Sang-Man;Song, Bang-Ho
    • Microbiology and Biotechnology Letters
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    • v.11 no.1
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    • pp.39-45
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    • 1983
  • One of Streptomyces sp. was screened as an antibiotic producing strain against Gram positive bacteria specifically from about one hundred Actinomycetes collections. The isolated KM-48 strain, indexed in our collection, was secreted an anbitiotic in nutrient broth culture. The active principle was extracted with acetone from the lyophilized solid of cultured filtrate. The nonadsorbed elute in aluminium oxide was isolated as a purified homogeneity which revealed a sing1e spot under ultra-violet beam on avicel thin layer chromatography. The isolated antibiotic was sensitive specifically against the Gram positive bacteria and fungi. About fifty percent inhibition of the control growth on Bacillus amyloliquefaciens was 18$\mu\textrm{g}$/$m\ell$. The antibiotic was lavile against thermotreatment and stabled in acidic condition remarkably. The KM-48 was identified as a similar strain to Streptomyces tsusimaensis on its morphological and cultural characteristics.

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