• Korean Journal of Materials Research
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• v.11 no.10
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• pp.869-878
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• 2001

Alumina $(Al_2O_3)$ green bodies were fabricated by gel-casting using three kinds of alumina with different particle size (mean particle size: 4.6 $\mu\textrm{m}$, 0.32 $\mu\textrm{m}$, 10nm). The effects of particle size on gel-casting process and green microstructure were investigated. The optimum dispersion conditions using ammonium salt (D-3019) as dispersant were 0.2 wt% (4.63 $\mu\textrm{m}$), 0.5 wt% (0.32 $\mu\textrm{m}$), and 5.0 wt% (10 nm), in high solid loading. The optimum solid loading of each starting material for gel-casting was obtained as 59 vol% (4.63 $\mu\textrm{m}$), 57 vol% (0.32 $\mu\textrm{m}$), 15 vol% (10 nm), depending on particle size, indicating that nano-size particle (10 nm) represent lower solid loading as high specific surface area than those of other two starting materials. The drying at ambient conditions (humidity; $\thickapprox$90%) was performed more than 48hrs to enable ejection of the part from the mold and then at $120^{\circ}C$ for 2hrs in an air oven, showing no crack and flaw in the dried green bodies. The pore size and distribution of the gelcast green bodies showed the significant decrease with decreasing particle size. Green microstructure was dependent on the pore size and distribution due to the particle size, and on the deairing step. The green density maximum obtained was 58.9% (4.63 $\mu\textrm{m}$), 60% (0.32 $\mu\textrm{m}$), 47% (10 nm) theoretical density (TD), and the deairing step applied before gel-casting did not affect green density.

• Progress in Superconductivity
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• v.8 no.1
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• pp.71-74
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• 2006

High $J_c$ over 1 $MA/cm^2$ YBCO film has been successfully prepared using nitrate precursors by spray pyrolysis method. Aerosol drolpets generated using a concentric spray nozzle were directly sprayed on a $LaAlO_3$(100) single crystal substrate. The cation ratio of precursor solution was Y:Ba:Cu=1:2.65:1.35. The distance between nozzle and substrate was 15 cm. Deposition temperature was ranging from $750^{\circ}C\;to\;800^{\circ}C$. Deposition pressure was 100 Torr, and oxygen partial pressure was varied from 10 Torr to 50 Torr. The microstructure, phase formation, texture development and superconducting properties of deposited films were largely changed with oxygen partial pressure. Deposited films showed a texture with(001) planes parallel to substrate plane. High quality film was obtained when film was deposited at $760^{\circ}C$ with an oxygen partial pressure of 30 Torr. The critical current density($J_c$) of the YBCO film was 1.75 $MA/cm^2$ at 77 K and self-field.

• Textile Coloration and Finishing
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• v.35 no.2
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• pp.128-136
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• 2023

Recently, the automobile industry is developing as the demand for automo- biles increases due to industrial development and population growth. In addition, many studies are being conducted to reduce heat loss inside the automobiles in order to save energy inside the automobiles due to environmental regulations. In this study, alumina, nanosilicon, and aerogel, which are adiabatic materials, were filled in PET to manufacture yarn, identify physical and mechanical properties, and weave into fabric to confirm adiabatic performance. As the content of the adiabatic material increased, the tensile strength of the fibers filled with alumina and nanosilicon decreased greatly, and the adiabatic property slightly increased. The tensile strength of fibers filled with the aerogel decreased slightly, but the adiabatic properties were greatly increased. Therefore, it is considered to be due to the large volume fraction in the PET yarn due to the low density of the aerogel.

• Restorative Dentistry and Endodontics
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• v.8 no.1
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• pp.89-96
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• 1982

The purpose of this study is to identify the phases of four different types, low-copper lathe cut (Type II, class 1) and spherical (Type II, class 2) amalgam alloys which are made by Caulk company and high copper Dispersalloy (Type II, class 3) made by Johnson & Johnson and Tytin (Type I, class 2) made by S.S. White and to determine the Vickers hardness number on the individual phase and four different types of dental amalgam. After each amalgam alloy and Hg measured exactly by the balance was triturated by the mechanical amalgamator (De Trey), the triturated mass was inserted into the cylindrical metal mold which was 4 mm in diameter and 12mm in height and was pressed by the Instron Universal Testing machine (Model 1125) at the speed of 1mm/minute with 143$kg/cm^2$ according to the A.D.A. Specification No. 1. The Specimen removed from the mold, mounted and stored in the room temperature for 7 days. The speciman was polished with the emery paper from #220 to #1200 and finally on the polishing cloth with 0.3 and 0.05 um $Al_2O_3$ powder suspended in water. And then each specimen was etched by Allan's method and washed with Sodium Bisulfinite for 30 seconds. Finally differentiation and metallography on each phase were obtained by using metallographical microscope (Versamet, Union) and microhardness was obtained by using microhardness tester (MVH-2, Torsee). The results were as follows: 1. In the low-copper amalgam, the ${\gamma}$, ${\gamma}_1$ and ${\gamma}_2$ phase were observed and in the high-copper amalgam, the ${\gamma}$, ${\gamma}_1$. ${\epsilon}$ and ${\eta}$ phases were observed but ${\gamma}_2$ phase was not observed. 2. Among the microhardness of each amalgam phase measured under pressing a vickers diamond indenter with 2.0gm load for 30 seconds, e phase has the highest V.H.N (314 ${\pm}$ 20), and in low-copper amalgam 12 phase has the lowest V.H.N. (29${\pm}$1) and ${\eta}$ phase which was observed in high-copper amalgam has 230${\pm}$13 V.H.N and this phase is considerd to contribute to strengthen the handness in amalgam. 3. The V.H.N. measured under pressing a Vickers diamond indenter with 300.0gm load for 30 seconds in low-copper amalgam was lower than that of high-copper amalgam.

• The Journal of Korean Academy of Prosthodontics
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• v.45 no.2
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• pp.203-215
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• 2007

Statement of problem: Titanium and its alloy, with their excellent bio-compatibility and above average resistance to corrosion, have been widely used in the field of dentistry. However, the excessive oxidization of titanium which occurs during the process of firing on porcelain makes the bonding of titanium and porcelain more difficult than that of the conventional metal-porcelain bonding. To solve this problem related to titanium-porcelain bonding, several methods which modify the surfaces, coat the surfaces of titanium with various pure metals and ceramics, to enable the porcelain adhesive by limiting the diffusion of oxygen and forming the adhesive oxides surfaces, have been investigated. Purpose: The purpose of this study was to know whether the titanium-porcelain bonding strength could be enhanced by treating the titanium surface with gold and TiN followed by fabrication of clinically applicable porcelain-fused-to-titanium crown Material and method: The porcelain-fused-to-titanium crown was fabricated after sandblasting the surface of the casting titanium coping with $Al_2O_3$ and treating the surface with gold and TiN coating followed by condensation and firing of ultra-low fusing porcelain. To compare with porcelain-fused-to-titanium crowns, porcelain-fused-to-gold crowns were fabricated and used as control groups. The bonding strengths of porcelain-fused-to-gold crowns and porcelain-fused-totitanium crowns were set for comparison when the porcelain was fractured on purpose to get the experimental value of fracture strength. Then, the surface were examined by SEM and each fracturing pattern were compared with each other Result:Those results are as follows. 1. The highest value of fracture strength of porcelain-fused-to-titanium crowns was in the order of group with gold coating, group with TiN coating, group with $Al_2O_3$ sandblasting. No statistically significant difference was found among the three (P>.05). 2. The porcelain-fused-to-gold crowns showed the highest value in bonding strength. The bonding strength of crowns porcelain-fused-to-titanium crowns of rest groups showed bonding strength reaching only 85%-94% of that of PFG, though simple comparision seemed unacceptable due to the difference in materials used. 3. The fracturing patterns between metal and porcelain showed mixed type of failure behavior including cohesive failure and adhesive failure as a similar patterns by examination with the naked eye and SEM. But porcelain-fused-to-gold crowns showed high incidence of adhesive failure and porcelain-fused-to-titanium crowns showed high incidence of cohesive failure. Conclusion: Above results proved that when fabricating porcelain-fused-to-titanium crowns, treating casting titanium surface with gold or TiN was able to enhance the bonding strength between titanium and porcelain. Mean value of masticatory force was found to showed clinically acceptable values in porcelain bonding strength in all three groups. However, more experimental studies and evaluations should be done in order to get better porcelain bonding strength and various surface coating methods that can be applied on titanium surface with ease.

• The Journal of the Petrological Society of Korea
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• v.9 no.2
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• pp.99-118
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• 2000

The variation of Na(A), K, Na(M4), A l O and Al(VI)+Fe3++Ti+Cr in the zonal amphiboles from the amphibolites of the Hwanggangri area indicates that the tschermakite-, edenite- and glaucophane substitutions are higher in the rim than in the core, in which actinolite changes to hornblende with going outward from core to rim. The contents of substitutional elements of hornblende~ of three samples@l29-2, M76-2, M78), which include diopside and greenish brown hornblende and are thought to represent the highest metamorphic grade, are lower than those of rim homblendes of the lower metamorphic grade and are higher than those of core actinolite that they conform to the middle domain in those of the whole amphiboles. Considerations about the origin of zonal amphiboles are as follows. Firstly, two samples(R102-1, R210-9) have the same amphibole composition like core is actinolitic hornblende, and rim is magnesian hastingsite although plagioclases such as albite(R102-1) and labradorite (R210-9) show the wide compositional difference. It is impossible to produce both albite and labradorite by one metamorphic event. Judging from this wide compositional difference, the existence of zonal amphiboles does not indicate the miscibility gap but is thought to be the result of the polymetamorphism. Secondly, the crystallographically sharp and gradational interfaces between actinolite and hornblende fonned in the amphibolites rgardless of the distance from the granite. In case of the samples(R210-9, M128, M130) having the sharp interface between two amphiboles, the plagioclase show the compositions produced at the low grade and the medium grade. Because such variable compositions of plagioclase indicates the overprinting of metamorphism of higher metamorphic grade than that of the formation of miscibility gap, it implies that zonal amphiboles were formed by polymetarnorphism. In case of the gradational interface between two amphiboles, this texture is also thought to be the effect of polymetamorphism from the fact that this texture mainly occur near the granite and from the consideration of the metamporphic grade. The relationship between the compositional variations of the amphiboles and the pressure types of metamorphism suggests that actinolitic core is considered to be grown by the metamorphism of medium pressure, while hornblende rim is shown to have genetic relations with the metamorphism of low pressure type.

• Economic and Environmental Geology
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• v.32 no.6
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• pp.611-631
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• 1999

Enviromental geochemisty and heary metal contamination at the Kongjueil mine creek were underaken on the basis of physicohemical properties and mineralogy for various kinds of water (surface, mine and ground water),soil, precipitate and sediment collected of April and December in 1998. Hydrgeochemical composition of the water samples are characterized by relatively significant enricant of Ca+Na, alkiali ions $NO_3$ and Cl inground and surfore water, wheras the mine waters are relatively eneripheral water of the mining creek have the characteristics of the (Ca+Mg)-$(HCO_3+SO_4)$type. The pH of the mine water is high acidity (3.24)and high EC (613$\mu$S/cm)compared with those of surface and ground water. The range of $\delta$D and $\delta^{18}O$ values (relative to SMOW) in the waters are shpwn in -50.2 to -61.6% and -7.0 to -8.6$\textperthousand$(d value=5.8 to 8.7). Using computer program, saturation index of albite, calcite, dolomite in mine water are nearly saturated. The gibbiste, kaolinite and smectite are superaturated in the surface and ground water, respectively. Calculated water-mineral reaction and stabilities suggest that weathing of silicate minerals may be stable kaolinite owing to the continuous water-rock reaction. Geochemical modeling showed that mostly toxic heavy metals may exist larfely in the from of metal-sulfate $(MSO_4\;^2)$and free metal $(M^{2+})$ in nmine water. These metals in the ground and surface water could be formed of $CO_3$ and OH complex ions. The average enrichment indices of water samples are 2.72 of the groundwater, 2.26 of the surface water and 14.15 of the acid mine water, normalizing by surface water composition at the non-mining creek, repectively. Characteristics of some major, minor and rate earth elements (Al/Na, K/Na, V/Ni, Cr/V, Ni/Co, La/Ce, Th/Yb, $La_N/Yb_N$, Co/Th, La/Sc and Sc/Th) in soil and sediment are revealed a narrow range and homogeneous compositions may be explained by acidic to intermediate igneous rocks. And these suggested that sediment source of host granitic gneiss colud be due to rocks of high grade metamorphism originated by sedimentary rocks. Maximum concentrations of environmentally toxic elements in sediment and soil are Fe=53.80 wt.% As=660, Cd=4, Cr=175, Cu=158, Mn=1010, Pb=2933, Sb=4 and Zn=3740 ppm, and extremely high concentrations are found are found in the subsurface soil near the ore dump and precipitates. Normalizing by composition of host granitic gneiss, the average enerichment indices are 3.72 of the sediments, 3.48 of the soils, 10.40 of the precipitates of acid mine drainage and 6.25 of the soils near the main adit. The level of enerichment was very severe in mining drainage sediments, while it was not so great in the soils. mineral composition of soil and sediment near the mining area were partly variable being composed of quartz, mica, feldspar, chlorite, vermiculite, bethierin and clay minerals. reddish variable being composed of quartz, mica, feldspar, chlorite, vermiculite, bethierin and clay minerals. Reddish brown precipitation mineral in the acid mine drainage identifies by schwertmanite. From the separated mineralgy, soil and sediment are composed of some pyrite, arsenopyite, chalcopyrite, sphalerite, galena, malachite, goethite and various kinds of hydroxied minerals.

• Restorative Dentistry and Endodontics
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• v.23 no.1
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• pp.183-196
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• 1998

The purpose of this study was to determine the effect of bleaching technique on the shear bond strength of esthetic restorative materials to bovine enamel. The bleaching agent was used 35% $H_2O_2$(Hi-Lite, Shofu, U.S.A.). Experimental groups were divided into two divisions as group A and B. Experimental A groups for the effect of number of bleaching were as follows ; Group Al : no bleaching Group A2 : bleaching 1 time ( for 5 minutes ) Group A3 : bleaching 3 times ( each for 5 minutes ) Group A4 : bleaching 6 times ( each for 5 minutes ) Group A5 : bleaching 9 times ( each for 5 minutes ) Experimental B groups for the effect of storage period in artificial saliva were as follows ; Group B1 : not stored in artificial saliva after bleaching Group B2 : stored in artificial saliva for 1 day after bleaching Group B3 : stored in artificial saliva for 1 week after bleaching Group B4 : stored in artificial saliva for 2 weeks after bleaching Group B5 : stored in artificial saliva for 4 weeks after bleaching Composite resin and glass ionomer cement were bonded to all specimens, and the shear bond strength between enamel and r~storative material were measured in Instron Universal Testing Machine(Instron, 4467, U.S.A,), Additionally, the bleached enamel specimens were examed after etching with 37.4% $H_3PO_4$ for 1 min under SEM(S-2300, Hitachi Co., Japan) to observe the effect of bleaching procedure on enamel surface morphology. The result were as follows ; 1. In SEM findings, bleached bovine enamel was found to be superficially rough. 2. In bleached bovine enamel, the effect of acid etching was reduced with the increase of number of bleaching. 3. The mean shear bond strength of composite resin and glass ionomer cement to bleached enamel surface tended to be lower than those to non-bleached enamel surface. 4. With the increase of number of bleaching, the shear bond strength of composite resin and glass ionomer cement to bleached enamel were progressively decreased. 5. Increasing the, storage period in artificial saliva after bleaching, the shear bond strength of composite resin and glass ionomer cement to bleached enamel were progressively increased. 6. The mean shear bond strength of glass ionomer cement to bleached bovine enamel tended to be clearly lower than that of composite resin.

• Membrane Journal
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• v.32 no.2
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• pp.150-162
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• 2022

In the field of water treatment and pharmaceutical bio an alumina hollow fiber membrane used for mixture separation. However, due to the lack of strengths it is very brittle to handle and apply. Therefore, it is necessary to study and improve the bending strength of the membrane to 100 MPa or more. In this study, as the mixing ratio of the nano-particles increased to 0, 1, 3, and 5 wt%, the viscosity of the fluid mixture increased. The pore structure of the hollow membrane produced by interrupting the diffusion exchange rate of the solvent and non-solvent during the spinning process suppresses the formation of the finger-like structure and gradually increases the ratio of the sponge-like structure to improve the membrane mechanical strength to more than 100 MPa. As a result, an interparticle space was ensured to improve the porosity of the sponge-like structure with high permeability, and it showed excellent N2 permeability of about 100000 GPU and high water permeability of 3000 L/m² h. Therefore, it can be concluded, that the addition of γ-Al₂O₃ nanoparticles as sintering aid is an important method to enhance the mechanical strength of the α-alumina hollow fiber membrane to maintain high permeability.

• Korean Journal of Environmental Agriculture
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• v.2 no.1
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• pp.35-44
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• 1983

In order to elucidate the change of plant community of natural forests caused by air pollution in the area of Mt. Dosjil of Ulsan city, 25 study subplots, 5 subplots from each 5 plots were set up. These plots lay along gradients of chronic exposure to airborne sulfur dioxide ($SO_2$), fluorides(F) and possibly other pollutants. Total nitrogen, organic matter, available $P_2O_5$, and CEC were generally depressed near industrial sourecs of air pollutants. The author found a total 7 species near sources of air pollutants and 13 species at the utmost plot from air pollutants. Number of individuals, species diversity, evenness, similarity index and biomass were generally depressed near the industrial source of air pollutants. Tolerant plants to air pollution is Cyperus amuricus, Calamagrostis arundinacea, Bidens bipinnata, Cocculus trilobus, Digtaria sanguinalis, Persicaria hydropiper, Pinus thunbergii, Ambrosia artemisiifolia var. elatior, Rhododendron schlippenbachii and Robinia pseudoacacia. It contains 4.41ton/ha of aboveground biomass of Robinia pseudoacacia in damaged forest by air pollution and 39.47ton/ha of it in the non-attacked forest. The annual net production is 0.67ton/ha. yr in damaged forest and $7.73ton/ha{\cdot}yr$ in the non-attacked forest.