• Composites Research
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• 제15권1호
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• pp.32-40
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• 2002

가압주조법을 이용하여 전자 패키징용 고부피분율 $SiC_p/Al$ 금속복합재료를 제조하였다. $SiC_p$ 예비성형체를 제조하기 위하여 예비성형체 금형을 고안하였으며, $Al_2O_{3f}$섬유 보강재를 $SiC_p$ 입자 보강재의 1/10비율로 첨가하고, 무기 성형제($SiO_2$)를 0.8% 이하로 사용하여 49~70 vol.% 의 예비성형체 제작에 성공하였다. 제조된 고부피분율 예비성형체로 금속용탕을 원활히 침투시키기 위해 온도, 가압력 등의 제조조건을 정하였으며, 이러한 새로이 고안된 금형조건을 FEM 열전도 해석에 도입하여 금속복합재료 제조시 몰드 내부에서 발생하는 온도변화를 분석하였다. 제조된 금속복합재료에 대해서는 충격특성 및 열팽창계수 특성평가를 실시하였다. 본 연구를 통해 제조된 금속복합재료의 충격흡수 에너지는 0.2~0.3J, 열팽창계수는 $8~10ppm/^{\circ}C$, 밀도는 $2.9~3.0g/cm^3$로 나타나 패기징 재료로서 적합한 특징을 가진 복합재료가 성공적으로 개발되었음을 확인하였다.

• 한국세라믹학회지
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• 제48권5호
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• pp.335-341
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• 2011

Continuous SiC fiber-reinforced SiC-matrix composites ($SiC_f$/SiC) had been fabricated by electrophoretic infiltration combined with ultrasonication. Nano-sized ${\beta}$-SiC added with 12 wt% of $Al_2O_3-Y_2O_3$ additive and Tyranno$^{TM}$-SA3 fabric were used as a matrix phase and fiber reinforcement, respectively. After hot pressing at 5 different conditions, the density, microstructure and mechanical properties of $SiC_f$/SiC were characterized. Hot pressing at relatively severe conditions, such as $1750^{\circ}C$ for 1 and 2 h, resulted in a brittle fracture behavior due to the strong fiber-matrix interface in spite of their high flexural strength. On the other hand, toughened $SiC_f$/SiC composite could be achieved by hot pressing at milder condition because of the formation of weak interface in spite of the decreased flexural strength. These results proposed the importance of weak fiber-matrix interface in the fabrication of ductile $SiC_f$/SiC composite.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2001년도 춘계학술발표대회 논문집
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• pp.29-33
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• 2001

In the present study, AZ91Mg/$\textrm{Al}_2\textrm{O}_3$ short fiber+SiC particulates hybrid metal matrix composites(MMCs) were fabricated by squeeze casting method. Different particulate sizes of 45, 29 and $9\mu\textrm{m}$ were hybridized with 5% volume fraction to investigate the effect of SiC particulates size on microstructure, mechanical and thermal properties such as hardness, flexural strength, wear resistance and thermal expansion. Results show that the microstructure of the hybrid composites were quite satisfactory, namely revealing relatively uniform distribution of reinforcements. Some aggregation of SiC particulates caused by particle pushing was observed especially in the hybrid composites containing in fine particulates($9\mu\textrm{m}$). The hardness and flexural strength were improved by decreasing particulates size, whereas wear resistance improved by increasing particulates size because of large particulates restricting matrix wear from contacted stress. Regardless of particulates size, thermal expansion of composites was the same. This may be because the content of particulates was in all cases 5 volume fraction.1

• 한국주조공학회지
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• 제15권4호
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• pp.388-396
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• 1995

This study has been conducted with the purpose of examining the fatigue crack growth characteristics of $Al_2O_3$ short fiber reinforced aluminum matrix composites made by squeeze casting process with different applied pressure and binder amount. Fatigue crack growth experiments have been performed under constant load amplitude method with a fixed load ratio. The rate of crack propagation was decreased with binder amount as well as applied pressure. Also fatigue crack growth path in matrix was changed from flat to rough mode with an increase of applied pressure. In the composites, fatigue crack was propagated to interface between matrix and reinforcement at 10MPa, but it was propagated to reinforcement at 20MPa. The major reason of thee result was considered that interfacial bonding force and microstructure of matrix were improved due to an increase of applied pressure. Localized ductile striation in the composites was observed at low growth rate region and such a phenominon was remarkable with an increase of applied pressure. At high growth rate region, the propensity of fracture appearance was changed from interfacial debonding to reinforcement fracture with an increase of applied pressure.

• 한국해양공학회:학술대회논문집
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• 한국해양공학회 2004년도 학술대회지
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• pp.347-351
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• 2004

[ $Si_3N_4$ ] composites have been extensively studied for engineering ceramics, because it has excellent room and high temperature strength, wear resistance properties, good resistance to oxidation, and good thermal and chemical stability. In the present work, carbon short fiber reinforced $Si_3N_4$ ceramics were fabricated by hot press method in $N_2$ atmosphere at $1800^{\circ}C$ using $Al_2O_3\;and\;Y_2O_3$ as sintering additives. Content of carbon short fiber was $0\%,\;0.1\%\;and\;0.3\%$. The composites were evaluated in terms of density, flexural strength and elastic modulus through the 3-point bending test at room temperature. Also, The wear behavior was determined by the pin on disk wear tester using silicon nitride ball. Experimental density and flexural strength decreased with increasing content of carbon fiber. But specific modulus increased with increasing content of carbon fiber. In addition, friction coefficient and specific wear loss decreased with increasing content of carbon short fiber by reason of interfacial defects between matrix and fiber.

• 복식문화연구
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• 제11권1호
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• pp.66-74
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• 2003

This study is to improve the worst lightfastness of a natural dye. To modify the fiber surface, low temperature oxygen plasma was carried out on silk fabric. The result is followed below after the examination of surface shape, dyeability, color change, UV absorbent influence and lightfastness. 1. When electric discharge outputs are 60W, 80W and 100w, and processing times are 10minutes, 20minutes and 40minutes, the etching effect of surface increased as electric discharge outputs and processing times increased. 2. When examined UV absorbent for 5hours, 10hours, 20hours, 40hours and 80hours, the value changes of E are 1.47, 2.51, 2.91, 3.71, 4.51 and 5.31 in case of Al pre-mordanting/ prasma 80W, 20min./ UVabsorbent 5% (100:1), 2.31, 2.47, 3.84, 3.90, 3.61 and 4.42 in case of Al pre-mordanting/prasma 80W, 20min.1 UV absorbent 5% (o.w.f.). The lightfastness decreased when UV absorbent increased. 3. Dyeability of the samples pre-treated with five different methods was in the following order: plasma processing for 20minutes at 60W/Al pre-mordanting > Al pre-mordanting > plasma processing for 20minutes at 60W > Al after-mordanting. non mordanting Plasma treatment had superior effect on dyeability. 4. When UV absorbent was applied in fabric, the sample under higher electric discharge out puts showed more effective in improving lightfastness.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2003년도 춘계학술발표강연 및 논문개요집
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• pp.240-240
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• 2003

SiC 섬유의 고온강도를 향상시키기 위한 소결조제로 boron, aluminum 등을 사용할 수 있다. 본 연구에서는 폴리카보실란에 aluminum precursor를 첨가한 후 중합반응을 거쳐 Al-contained polycarbosilane을 합성하였다. 합성된 Al-contained polycarbosilane을 용융방사하여 섬유화 하고 열분해 공정을 통해 Si-Al-C-O 나노복합 섬유를 제조하였다. 먼저 aluminum butoxide와 polycarbosilane(commercial)을 200m1 xylene에 용해시켜 14$0^{\circ}C$에서 1시간 동안 reflux하였다. evaporator를 이용하여 xylene를 제거한 후 autoclave에서 25$0^{\circ}C$/30$0^{\circ}C$ 중합과정을 통해 가교결합 시켰다 이와 같이 합성된 시료는 ICP분석을 통해 aluminum 함량을 확인하였고 FT-IR(Fig.1) 및 GPC분석(Fig.2)으로부터 화학구조 및 분자량변화를 확인하였다. aluminum 첨가량이 증가함에 따라 Si-H/Si-$CH_3$의 결합크기의 비가 감소하였으며 이로부터 aluminum butoxide와 polycarbosilane의 가교결합이 이루어진 것으로 보이며 중합 후 분자량의 증가 또한 가교결합에 의한 결과로 사료된다 열무게감량(TGA) 측정 결과는 40$0^{\circ}C$부터 유기리간드의 분해가 일어나며 80$0^{\circ}C$이상에서 세라믹화 과정이 완료되었음을 알 수 있었다 또한 aluminum 첨가량이 증가함에 따라 세라믹 수율도 증가하였음을 확인하였다. 합성된 aluminum-contained polycarbosilane은 20$0^{\circ}C$에서 1시간 동안 불융화과정을 거쳐 환원 및 진공 분위기에서 고온 열처리하였으며 이로부터 얻어진 시료에 대해 XRD분석을 수행하였다. SEM과 TEM을 이용하여 미세구조를 관찰하였다.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2002년도 추계학술발표대회 논문집
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• pp.139-142
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• 2002

This study presents a mathematical model predicting the stress-strain behavior of fiber reinforced (FMMCs) and fiber/particle reinforced metal matrix composites (F/P MMCs). MMCs were fabricated by squeeze casting method using Al2O3 short fiber and particle as reinforcement, and A356 aluminum alloy as matrix. The fiber/particle ratios of F/P MMCs were 2:1, 1:1, 1:2 with the total reinforcement volume fraction of 20 vol.%, and the FMMCs were reinforced with 10 vol,%, 15 vol. %, 20 vol. % of fibers. Tensile tests were conducted and compared with predictions which were derived using laminate analogy theory and multi-failure model of reinforcements. Results show that the tensile strength of FMMCs with 10 vol.% of fiber was well matched with prediction, and as the fiber volume increases, predictions become larger than experimental results. The difference between the prediction and experiment is considered to be a result of matrix allowance of fiber damage in tensile loading. As the fiber volume fraction in FMMCs increases, the fiber damage increases and so that the tensile strength is reduced. The strength of F/P MMCs approaches more closely to the prediction than FMMCs reinforced with 20 vol.% of fibers because F/P MMCs contains small quantity of fibers and thus has a positive effect in fiber strengthening.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2001년도 추계학술발표대회 논문집
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• pp.79-82
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• 2001

In this research, tile effects of reinforcements type on mechanical properties of MMCs were studied. Six kinds preform were fabricated by using Saffil short fiber, HTZ short fiber, $Al_2O_3$ particle, and SiC particle. MMCs were fabricated by using squeeze casting methods. Various tests were conducted to show the effects of reinforcements type on mechanical properties of MMCs. Tensile and compressive properties of MMCs depend on short fiber, however wear properties depend on particle reinforcement. Generally, properties of fiber/particle hybrid MMCs were excellent than those of MMCs with short fiber.

• 한국산업보건학회지
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• 제26권2호
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• pp.225-236
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• 2016

Objectives: Nanomaterials have been used in various fields. As use of nanoproducts is increasing, workers dealing with nanomaterials are also gradually increasing. Exposure assessments for nanomaterials have been carried out for protection of worker's health in workplace. Exposure studies were mainly focused on manufacturing processes, but these studies on after-treatment processes such as refinement, weighing, and packing were insufficient. So, we investigated exposure characteristics of particles during after-treatment processes of $Al_2O_3$ fibers and Ni powders. Methods: Mass-production of Ni powder process was carried out in enclosed capture-type canopy hood. In a developing stage, $Al_2O_3$ was handled with a local ventilation unit. Exposure characteristics of particles were investigated for $Al_2O_3$ fiber and Ni powder processes during the periods of 10:00 to 16:00, 20 May 2014 and 13:00 to 16:00, 21 May 2014, respectively. Three real-time aerosol instruments were utilized in exposure assessment. A scanning mobility particle sizer(SMPS, nanoscan, model 3910, TSI) and an optical particle counter(OPC, portable aerosol spectrometer, model 1.109, Grimm) were used to determine the particle size distribution in the size range of 10-420 nm and $0.25-32{\mu}m$, respectively. In addition, a nanoparticle aerosol monitor(NAM, model 9000, TSI) was used to measure lung-deposited nanoparticle surface area. Membrane filters(isopore membrane filter, pore size of 100 nm) were also used for air sampling for the FE-SEM(model S-5000H, Hitachi) analysis using a personal sampling pump(model GilAir Plus by 2.5 L/min, Gilian). Conclusions: For Ni powder after-treatment process, only 27% increase in particle concentration was found during the process. However, for $Al_2O_3$ fiber after-treatment process, significant exposure(1.56-3.34 times) was observed during the process.