• 한국전기전자재료학회논문지
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• 제19권3호
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• pp.228-232
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• 2006

In this paper, in order to develop low temperature sintering $PbTiO_3$-system piezoelectric ceramics for thickness-vibration-mode piezoelectric transformer, $Pb_{0.76}Ca_{0.24}[(Mn_{1/3}Sb_{2/3})_{0.04}Ti_{0.96}]O_3$ ceramics using $0.25\;wt\%\;CaCO_3$ and $0.2\;wt\%\;Li_{2}CO_3$ as sintering aids were manufactured according to the variation of poling field. The specimens could be sintered at $930\;^{\circ}C$. The piezoelectric properties were investigated according to the poling field. The maximum properties showed at the field of 6.5 kV/mm, which had kt of 0.49, Qmt of 1816, and $d_{33}$ of 81.4 pC/N.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2010년도 제39회 하계학술대회 초록집
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• pp.162-162
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• 2010

InSb has received great attentions as a promising candidate for the active layer of infrared photodetectors due to the well matched band gap for the detection of $3{\sim}5\;{\mu}m$ infrared (IR) wavelength and high electron mobility (106 cm2/Vs at 77 K). In the fabrication of InSb photodetectors, passivation step to suppress dark currents is the key process and intensive studies were conducted to deposit the high quality passivation layers on InSb. Silicon dioxide (SiO2), silicon nitride (Si3N4) and anodic oxide have been investigated as passivation layers and SiO2 is generally used in recent InSb detector fabrication technology due to its better interface properties than other candidates. However, even in SiO2, indium oxide and antimony oxide formation at SiO2/InSb interface has been a critical problem and these oxides prevent the further improvement of interface properties. Also, the mechanisms for the formation of interface phases are still not fully understood. In this study, we report the quantitative analysis of indium and antimony oxide formation at SiO2/InSb interface during plasma enhanced chemical vapor deposition at various growth temperatures and subsequent heat treatments. 30 nm-thick SiO2 layers were deposited on InSb at 120, 160, 200, 240 and $300^{\circ}C$, and analyzed by X-ray photoelectron spectroscopy (XPS). With increasing deposition temperature, contents of indium and antimony oxides were also increased due to the enhanced diffusion. In addition, the sample deposited at $120^{\circ}C$ was annealed at $300^{\circ}C$ for 10 and 30 min and the contents of interfacial oxides were analyzed. Compared to as-grown samples, annealed sample showed lower contents of antimony oxide. This result implies that reduction process of antimony oxide to elemental antimony occurred at the interface more actively than as-grown samples.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2005년도 추계학술대회 논문집 Vol.18
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• pp.176-177
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• 2005

In this paper, in order to develop low temperature sintering $PbTiO_3$-system piezoelectric ceramics for thickness-vibration-mode piezoelectric transformer, $Pb_{0.76}Ca_{0.24}[(Mn_{1/3}Sb_{2/3})_{0.04}Ti_{0.96}]O_3$ ceramics using $0.25wt%CaCO_3$ and 0.2wt%$Li_2CO_3$ as sintering aids were manufactured according to the variation of poling field. Specimens could be sintered at the sintering temperature of $930^{\circ}C$. The piezoelectric properties increased according to the increase of poling field and showed the maximum values (kt=0.49, Qmt=1816, and $d_{33}$=81.4pC/N) under 6.5kV/mm.

• 한국세라믹학회지
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• 제39권4호
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• pp.386-393
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• 2002

본 연구는 티탄산칼륨 섬유(K2O·$nTiO_2$)를 제조한 후, 도전율이 우수한 Sb-doped $SnO_2$(ATO: Antimony Tin Oxide)를 티탄산 칼륨 섬유에 코팅하는 기술을 개발하는데 목적이 있다. 티탄산칼륨 섬유는 서냉 소성법으로 제조하였으며 섬유의 평균 길이는 $15{\mu}m$, 평균 직경은 $0.5{\mu}m$이었다. ATO를 졸-겔법, 공침법, 균일침전법등 세가지 방법으로 티탄산칼륨 섬유에 코팅 하였으며 ATO 코팅된 티탄산칼륨 섬유는 ATO 함량(5∼70 wt%), Sb 함량(0∼20 wt%), 온도($450∼800^{\circ}C$), 수세 여부 및 회수(3∼4회) 등을 변화 시키며 비저항 변화를 관찰하였다. 공침법의 경우 ATO 함량이 30wt%에서 103${\Omega}$·cm 낮은 비저항을 나타내었으며, 그 이상의 함량에서는 거의 일정한 값($60{\Omega}{\cdot}cm∼90{\Omega}{\cdot}$cm)을 보였다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1983년도 하계학술회의강연.논문초록집
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• pp.225-226
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• 1983

• 한국전기전자재료학회논문지
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• 제22권6호
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• pp.489-494
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• 2009

In this study, In order to improve dielectric and piezoelectric properties of Lead-free piezoelectric ceramics, $0.95(K_{0.5}Na_{0.5})NbO_3-0.05Li(Sb_{0.8}Nb_{0.2})O_3+0.2\;wt%Ag_2O+0.4\;wt%MnO_2+Xwt%CuO$ were investigated as a function of the amount of CuO addition. With increasing the amount of CuO addition, density was increased up to 0.4 wt.% CuO and then decreased above. And also, electro mechanical coupling factor ($k_p$) was decreased. At the 0.4 wt% CuO added specimen sintered at $1020^{\circ}C$, $k_p$, Qm, density, dielectric constant (${\varepsilon}_r$) and $d_{33}$[pC/N] showed the optimal value of $4.37\;g/cm^3$, 0.354, 305, 645, and 144 pC/N respectively.

• 한국산학기술학회논문지
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• 제12권1호
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• pp.390-395
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• 2011

본 연구에서는 고출력 압전 변압기에 적합한 압전 세라믹을 찾고자 그 조성으로 PZT계에 $Pb(Mn_{1/3}Nb_{2/3})O_3$와 $Pb(Sb_{1/2}Nb_{1/2})O_3$이 첨가된 3성분계 조성인 0.95Pb($Zr_xTi_{1-x}$)$O_3$+yPMN+(0.05-y)PSN으로 하였는데, 기계적 품질계수를 향상시킬 목적으로 PMN을 선정하였고, PSN은 유전율 및 전기기계 결합계수가 PMN으로 인해 저하되는 것을 방지 하고자 선정하였다. 이 3성분계 조성에서 최적의 성능을 가질 수 있는 MPB(Morphotropic Phase Boundary) 영역에서 유전 압전 및 전기적 특성을 정량적 정성적으로 검토하였다.

• 한국재료학회지
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• 제29권3호
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• pp.150-154
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• 2019

This study investigates the effect of MnO2 and CuO as acceptor additives on the microstructure and piezoelectric properties of $0.96(K_{0.5}Na_{0.5})_{0.95}Li_{0.05}Nb_{0.93}Sb_{0.07}O_3-0.04BaZrO_3$, which has a rhombohedral-tetragonal phase boundary composition. $MnO_2$ and CuO-added $0.96(K_{0.5}Na_{0.5})_{0.95}Li_{0.05}Nb_{0.93}Sb_{0.07}O_3-0.04BaZrO_3$ ceramics sintered at a relatively low temperature of $1020^{\circ}C$ show a pure perovskite phase with no secondary phase. As the addition of $MnO_2$ and CuO increases, the sintered density and grain size of the resulting ceramics increases. Due to the difference in the amount of oxygen vacancies produced by B-site substitution, Cu ion doping is more effective for uniform grain growth than Mn ion doping. The formation of oxygen vacancies due to B-site substitution of Cu or Mn ions results in a hardening effect via ferroelectric domain pinning, leading to a reduction in the piezoelectric charge coefficient and improvement of the mechanical quality factor. For the same amount of additive, the addition of CuO is more advantageous for obtaining a high mechanical quality factor than the addition of $MnO_2$.

• 분석과학
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• 제34권1호
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• pp.17-22
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• 2021

In this study, flame retardant mixtures of decabromodiphenylethane (DBDPE) and Sb2O3 were analyzed using Fourier transform infrared (FT-IR) spectroscopy. The experimentally obtained wavenumbers of DBDPE and Sb2O3 were 1321 and 949 cm-1, respectively, whereas those obtained by theoretical calculation were 1370 and 818 cm-1, respectively. Strong correlation was observed between the mixing molar ratios and observed peak area ratios, suggesting that FT-IR analysis can be used to obtain relative amounts of the individual components of flame retardant mixture.

• Journal of Electrochemical Science and Technology
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• 제11권2호
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• pp.165-171
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• 2020

The electrochemical preparation and spectroscopic characterisation of iridium-antimony (Ir-Sb) species is important owing to their potential applications as nanostructure materials. Nanostructures, i.e. nanoflower and nanodisk, of Ir-Sb were electrodeposited on conductive substrates using a practical electrochemical method based on the simultaneous underpotential deposition (UPD) of Ir and Sb from the IrCl₃ and Sb₂O₃ at a constant potential. Electrochemical UPD mechanism of Ir-Sb was studied using cyclic voltammetry and potential-controlled electrochemical deposition techniques. Herein, X-ray diffraction, scanning electron microscopy, energy dispersive spectroscopy, X-ray photoelectron and Raman spectroscopy were used to determine the morphological and structural properties of the electrochemically-synthesised Ir-Sb nanostructures.