• 한국자기학회지
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• 제8권4호
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• pp.179-184
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• 1998

일반적으로 페로브로스카이트 구조의 망간 산화물에서 많이 관찰되어온 초거대 자기 저항 현상은 임계점 (큐리온도) 부근에서 온도 변화에 의한 상자성-강자성 상전이와 동반한 전기 전도 기수 변화에 따른 급격한 저항 변화와 매우 밀접한 광계가 있다. 본 논문에서는 이러한 전기 저항-온도 거동을 모사하기 위해, 온도에 따른 상분율 변화 함수를 유효매질 이론(effective media theory)을 이용하여 모형식을 마련하엿다. 미 모형식은 실제 La0.7Ca0.3MnO3의 저항-온도 거동을 매우 정확하게 모사하였다.

• 한국결정학회:학술대회논문집
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• 한국결정학회 2002년도 정기총회 및 추계학술연구발표회
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• pp.12-12
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• 2002

Lanthanum manganites have been extensively studied for the application to magnetic devices since the colossal magnetoresistance of these compounds has been observed [1]. The critical temperatures, Tc, of manganites La/sub 0.7/Ca/sub 0.3-x/Ba/sub x/MnO₃ increased as the content of Ba increased except the abrupt jump near the critical concentration. The step like behavior of the critical temperature for a similar compound has been known to be related to the structural phase transition [2]. To understand the step like behavior of Tc, the EXAFS technique is applied to the La/sub 0.7/Ca/sub 0.3-x/Ba/sub x/MnO₃ compound system. The ordering between the manganese and oxygen was examined by this method. The EXAFS analysis shows that the coordination numbers were not changed before and after the phase transition, the bonding distance between manganese and oxygen is about 1.94 ± 0.02 Å, which is consistent with other work [3] and the Debye waller parameters were about σ²= 0.0037 ± 0.0005 Ų for x=0.0 and x=3.0, respectively. The value of Debye-Waller parameter for x=0.09 is about σ² = 0.0050 ± 0.0005 Ų in about phase transition concentration. Based on the Debye-Waller parameters, it is shown that the ordering between manganese and oxygen is significantly reduced near the phase transition concentration.

• Journal of Korean Vacuum Science & Technology
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• 제7권1호
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• pp.8-12
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• 2003

The effects of lattice strain on the magnetic and the transport properties of La$_{0.8}$Sr$_{0.2}$MnO$_3$films grown on a LaAlO$_3$ (001) substrate and on a La$_{0.8}$Sr$_{0.2}$MnO$_3$ layer have been studied. It was observed that the metal-insulator and the ferromagnetic transitions turn out to be at higher temperatures for the film deposited on La$_{0.8}$Sr$_{0.2}$MnO$_3$ layer with respect to that on LaAlO$_3$. The dependence of Curie temperature on the bulk and the Jahn-Teller strains has also been determined. determined.

• Journal of Magnetics
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• 제18권1호
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• pp.34-38
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• 2013

This paper studies the effects of the Mn-site substitution by nickel on the magnetic properties and the magnetocaloric properties of $La_{0.7}Ca_{0.3}Mn_{1-x}Ni_xO_3$ (x = 0, 0.05 and 0.1). The orthorhombic crystal structures of the samples are confirmed by the room temperature X-ray diffraction. The dependence of the Curie temperature ($T_C$) and the magnetic entropy change (${\Delta}S_M$) on the Ni doping content was investigated. The samples with x = 0 had the first order phase transition, while the samples with x = 0.05 and 0.1 had the second order phase transition. As the concentration of Ni increased, the maximum entropy change (${\mid}{\Delta}S_M{\mid}_{max}$) decreased gradually, from 2.78 $J{\cdot}kg^{-1}{\cdot}K^{-1}$ (x = 0) to 1.02 $J{\cdot}kg^{-1}{\cdot}K^{-1}$ (x = 0.1), in a magnetic field change of 15 kOe. The measured value of $T_C$ was 185 K, 150 K and 145 K for x = 0, 0.05 and 0.1, respectively. The phase transition temperatures became wider as x increased. It indicates that the Mn-site substitution by Ni may be used to tailor the Curie temperature in $La_{0.7}Ca_{0.3}Mn_{1-x}Ni_xO_3$.

• 한국자기학회:학술대회 개요집
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• 한국자기학회 2000년도 International Symposium on Magnetics The 2000 Fall Conference
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• pp.429-430
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• 2000

• 한국진공학회:학술대회논문집
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• 한국진공학회 2003년도 제25회 학술발표회 초록집
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• pp.79-79
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• 2003

• 한국진공학회:학술대회논문집
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• 한국진공학회 2003년도 제25회 학술발표회 초록집
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• pp.181-181
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• 2003

• 한국자기학회:학술대회 개요집
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• 한국자기학회 2005년도 하계학술연구발표회 논문개요집
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• pp.199-199
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• 2005

• 한국재료학회지
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• 제21권4호
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• pp.216-219
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• 2011

Perovskite manganites such as $RE_{1-x}A_xMnO_3$ (RE = rare earth, A = Ca, Sr, Ba) have been the subject of intense research in the last few years, ever since the discovery that these systems demonstrate colossal magnetoresistance (CMR). The CMR is usually explained with the double-exchange (DE) mechanism, and CMR materials have potential applications for magnetic switching, recording devices, and more. However, the intrinsic CMR effect is usually found under the conditions of a magnetic field of several Teslas and a narrow temperature range near the Curie temperature ($T_c$). This magnetic field and temperature range make practical applications impossible. Recently, another type of MR, called the low-field magnetoresistance(LFMR), has also been a research focus. This MR is typically found in polycrystalline half-metallic ferromagnets, and is associated with the spin-dependent charge transport across grain boundaries. Composites with compositions $La_{0.7}(Ca_{1-x}Sr_x)_{0.3}MnO_3)]_{0.99}/(BaTiO_3)_{0.01}$ $[(LCSMO)_{0.99}/(BTO)_{0.01}]$were prepared with different Sr doping levels x by a standard ceramic technique, and their electrical transport and magnetoresistance (MR) properties were investigated. The structure and morphology of the composites were studied by X-ray diffraction (XRD) and scanning electronic microscopy (SEM). BTO peaks could not be found in the XRD pattern because the amount of BTO in the composites was too small. As the content of x decreased, the crystal structure changed from orthorhombic to rhombohedral. This change can be explained by the fact that the crystal structure of pure LCMO is orthorhombic and the crystal structure of pure LSMO is rhombohedral. The SEM results indicate that LCSMO and BTO coexist in the composites and BTO mostly segregates at the grain boundaries of LCSMO, which are in accordance with the results of the magnetic measurements. The resistivity of all the composites was measured in the range of 90-400K at 0T, 0.5T magnetic field. The result indicates that the MR of the composites increases systematically as the Ca concentration increases, although the transition temperature $T_c$ shifts to a lower range.

• 한국자기학회:학술대회 개요집
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• 한국자기학회 2003년도 하계학술연구발표회 및 한.일 공동심포지엄
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• pp.62-63
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• 2003

Electron-phonon interaction plays a significant role in forming of colossal magnetoresistance effect (CMR). Polaron formation was observed by neutron diffraction and by extended X-ray absorption fine structure (EXAFS) analysis. Local probe as given by the EXAFS is a useful method to study the polaronic charge and its dependence on temperature and ions size. Here we present the EXAFS study of polaronic charge in $La_{0.7}Ca_{0.3-x}Ba_{x}MnO_3$ compositions.