• Title/Summary/Keyword: ${\gamma}'$ phase

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High Temperature Deformation Behavior of Beta-gamma TiAl Alloy (Beta-gamma TiAl 합금의 고온변형거동)

  • Kim, J.S.;Kim, Y.W.;Lee, C.S.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2006.05a
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    • pp.429-433
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    • 2006
  • High Temperature deformation behavior of newly developed beta-gamma TiAl alloy was investigated in this study. The optimum processing condition was investigated with the aid of Dynamic Materials Model (DMM). Processing maps representing the efficiency of power dissipation for microstructural evolution and instability were constructed utilizing the results of hot compression test at temperatures ranging from $1000^{\circ}C$ to $1200^{\circ}C$ and strain rate ranging from $10^{-4}/s$ to $10^2/s$. The Artificial Neural Network (ANN) simulation was adopted to consider the deformation heating. With the help of processing map and microstructural analysis, the optimum processing condition was presented and the role of $\beta$ phase was also discussed in this study.

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Effect of W Substitution on the Precipitation Behavior of χ and σ Phase in Super Duplex Stainless Steels (슈퍼 2상 스테인리스강에서 χ와 σ상의 석출거동에 미치는 W치환의 영향)

  • Han, Huyn-Sung;Kim, Seong-Hwi;Kang, Chang-Yong
    • Korean Journal of Materials Research
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    • v.26 no.4
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    • pp.200-206
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    • 2016
  • This study was carried out to investigate the effect of W substitution on the precipitation behavior of ${\chi}$ and ${\sigma}$ phases in super duplex stainless steel. The ${\chi}$ phase was precipitated at the interface of ferrite / austenite phases and inside the ferrite phase at the initial stage of aging. With an increase in the aging time, the volume fraction of the ${\chi}$ phase increased, and then decreased with the transformation from the ${\chi}$ phase to the ${\sigma}$ phase. The ${\sigma}$ phase was precipitated later than the ${\chi}$ phase, and the volume fraction of x phase increased with the increase in the aging time. The ferrite phase was decomposed into the new austenite (${\gamma}2$) and ${\sigma}$ phases by aging treatment. The decomposition of the ferrite phase into the ${\gamma}2$ and ${\sigma}$ phases was retarded by W substitution for Mo. The volume fraction of the ${\chi}$ phase increased and that of the ${\sigma}$ phase decreased due to W substitution. The ${\chi}$ and ${\sigma}$ phases were intermetallic compounds, which had lower nickel concentration, and higher chromium, molybdenum, and tungsten concentrations. The ${\chi}$ phase has higher molybdenum and tungsten concentrations than those of the ${\sigma}$ phase. The amounts of chromium and nickel in the ${\chi}$ and ${\sigma}$ phases did not change, but these phases have higher concentrations of molybdenum and tungsten due to W substitution for Mo.

The Effect of Post Oxidation on Corrosion Characteristics of Gas Nitrocarburised Carbon Steels (Nitrocarburising 처리된 탄소강의 내식특성에 미치는 Post Oxidation 효과)

  • Kim, Y.H.;Jung, K.H.
    • Journal of the Korean Society for Heat Treatment
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    • v.12 no.1
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    • pp.9-20
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    • 1999
  • The effect of post oxidation, water-quenched after holding in air for 5~420 seconds or cooling or furnace cooling, on corrosion resistance and phase formation characteristics of the surface layer of SM20C and SM45C carbon steels after gas nirtrocarbursing in the $NH_3-5%CO_2-N_2$ gas atmosphere at $580^{\circ}C$ for 3hours is studied. The compound layers of two steels consist of ${\varepsilon}-Fe_{2-3}N$, ${\gamma}^{\prime}-Fe_4N$ and $Fe_3O_4$, phases, however, the quantity of ${\gamma}^{\prime}-Fe_4N$ phase increases for the furnace cooled specimen compared to that of air cooling specimen. With increasing $NH_3$ content in the gas mixture and also increasing the keeping time in the air after gas nitrocarburising, the ${\varepsilon}-Fe_{2-3}N$ phase of compound layer increases, while the decreased current density recognizing the improvement of corrosion resistance are shown. the passive current density of SM45C steel is lower than that of SM20C steel at the same nitrocarburising conditions.

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High Nitrogen Steel for Core of Over-head Transmission Line (가공송전선 코아용 고질소강 연구)

  • Kim, Bong-Seo;Yoo, Kyung-Jae;Kwon, Hae-Woong;Lee, Hee-Woong;Kim, Byung-Geol
    • Proceedings of the KIEE Conference
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    • 1998.07d
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    • pp.1555-1557
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    • 1998
  • In order to investigate the core material for over-head transmission line with non-magnetic and high strength nitrogen steel, microstructure and several basic properties of Fe-Mn-Cr-Ni-N steel have been studied. It is necessary that core material have a $\gamma$ phase to have a non-magnetic characteristics. To acquire a $\gamma$ phase, Mn, Ni and C are added as a alloying element. It was found that Fe-25Mn-16Cr-1Ni-N alloy have a stable $\gamma$ phase. The precipitate from this alloy system was $(Cr, Fe)_7C_3$. High Mn and N steel satisfies Sievert's relation that solubility of nitrogen increases with the square root of partial pressure of gas in metal-gas system and the hardness have proportional relation with nitrogen concentration.

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Determination of ${\gamma}-Aminobutyric$ Acid and Glutamic Acid in Rat Brain by High Performance Liquid Chromatography with Electrochemical Detection (HPLC-ECD를 이용한 흰쥐의 뇌 중 감마 아미노부티르산 및 글루탐산의 정량)

  • 강종성;이순철
    • YAKHAK HOEJI
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    • v.43 no.3
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    • pp.300-305
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    • 1999
  • A sensitive and efficient assay method was applied to determine the level of glutamic acid (GA) and ${\gamma}-aminobutyric$ acid (GABA) in frontal cortex and hippocampus of rat administrated with ethanol and drugs. The compounds were derivatized with ο-phthalaldehyde (OPA) and 2-mercaptoethanof for precolunm analysis. The condition for the simultaneous determination of GA, GABA and $\beta-aminobutyric$ acid (BABA) by high performance liquid chromatography with electrochemical detection was reverse phase $C_{18}$ column as stationary phase, 0.1 M phosphate buffer containing 0.1 mM $Na_4EDTA$ : methanol = 55:45 (v+v) pH 3.8 as mobile phase and 0.7V electrode voltage. The stability of reaction product of GA, GABA and BABA with OPA could be increased by adding the same volume of polyethylene glycol 400 to reaction mixture. The GABA level in frotal cortex of rat was significantly decreased by the administration of picrotoxin and diazepam, but it was significantly increased by the administration of red ginseng total saponin, N-methyl-D-glucamine and (-)-deprenyl.

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A Study of Structures and Magnetic Properties of Electrodeposited Fe-45 wt%Ni-P Alloys (전착법에 의한 Fe-45 wt%Ni-P 합금의 조직과 자기적 성질에 관한 연구)

  • 구승현;이흥렬;김동환;황태진;임태홍
    • Journal of Surface Science and Engineering
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    • v.36 no.6
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    • pp.461-465
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    • 2003
  • The microstructures and magnetic properties of electrodeposited Fe-45 wt%Ni-P alloys have been investigated. The structures of electrodeposited Fe-45 wt%Ni alloy was FCC i.e. ${\gamma}$ phase and the size of crystallite was 10 nm. The structure of electrodeposited Fe-45 wt%Ni-1 wt%P alloy showed ${\gamma}$ phase and 7 nm sized nanocrystalline. The electrodeposited Fe-45 wt%Ni-P alloys containing 2∼3 wt% of P exhibited ${\gamma}$$\alpha$ dual phases. The electrodeposited Fe-45 wt%Ni-P alloys above 3.5 wt% showed an amorphous structure. P in the alloys acted grain refining and phase changing element. The resistivity of the electrodeposited alloys increased with P contents. Effective permeability at high frequency (above 1 MHz) increased with P contents up to 2 wt% and this was ascribed to the easier magnetization rotation owing to the reduction of eddy current. Effective permeability decreased with P contents above 3 wt% and this was ascribed to the transformation of the ferromagnetism of Fe-45 wt%Ni alloy gradually into paramagnetism with the introduction of P into the electrodeposited alloy matrix.

The Characteristics of Compound Layers Formed during Plasma Nitrocarburising in Pure Iron (플라즈마 침질탄화처리된 순철의 화합물층 특성)

  • Cho, H.S.;Lee, S.Y.;Bell, T.
    • Journal of the Korean Society for Heat Treatment
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    • v.13 no.3
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    • pp.143-150
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    • 2000
  • Ferritic plasma nitrocarburising was performed on pure iron using a modified DC plasma unit. This investigation was carried out with various gas compositions which consisted of nitrogen, hydrogen and carbon monoxide gases, and various gas pressures for 3 hours at $570^{\circ}C$. After treatment, the different cooling rates(slow cooling and fast cooling) were used to investigate its effect on the structure of the compound layer. The ${\varepsilon}$ phase occupied the outer part of the compound layer and ${\gamma}^{\prime}$ phase existed between the ${\varepsilon}$ phase and the diffusion zone. The gas composition of the atmosphere influenced the constitution of the compound layer produced, i.e. high nitrogen contents were essential for the production of ${\varepsilon}$ phase compound layer. It was found that with increasing carbon content in the gas mixture the compound layer thickness increased up to 10%. In the gas pressure around 3 mbar, the compound layer characteristics were slightly effected by gas pressure. However, in the low gas pressure and high gas pressure, the compound layer characteristics were significantly changed. The constitution of the compound layer was altered by varying the cooling rate. A large amount of ${\gamma}^{\prime}$ phase was transformed from the ${\varepsilon}$ phase during slow cooling.

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Pulsar Polar Cap and Slot Gap Models: Confronting Fermi Data

  • Harding, Alice K.
    • Journal of Astronomy and Space Sciences
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    • v.30 no.3
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    • pp.145-152
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    • 2013
  • Rotation-powered pulsars are excellent laboratories for studying particle acceleration as well as fundamental physics of strong gravity, strong magnetic fields and relativity. Particle acceleration and high-energy emission from the polar caps is expected to occur in connection with electron-positron pair cascades. I will review acceleration and gamma-ray emission from the pulsar polar cap and associated slot gap. Predictions of these models can be tested with the data set on pulsars collected by the Large Area Telescope on the Fermi Gamma-Ray Telescope over the last four years, using both detailed light curve fitting, population synthesis and phase-resolved spectroscopy.

Repression of γ-Glutamylcysteine Synthetase and Glutathione S-Transferases by Metformin, an Anti-diabetic Agent, in H4IIE Rat Hepatocytes

  • Bae, Eun-Ju;Cho, Min-Joo;Kim, Sang-Geon
    • Toxicological Research
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    • v.23 no.2
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    • pp.127-133
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    • 2007
  • Metformin is a drug used to lower blood sugar levels in patients with type 2 diabetes via activation of adenosine monophosphate (AMP)-activated protein kinase (AMPK). The primary objective of this study was to investigate whether metformin at the pharmacologically effective concentrations affects the expressions of ${\gamma}$-glutamylcysteine synthetase and phase II antioxidant genes in the H4IIE cell. Treatment of the cells with either metformin or 5-aminoimidazole-4-carboxamide riboside (AICAR) abrogated tert-butylhydroxyquinone (t-BHQ) induction of ${\gamma}$-glutamylcysteine synthetase, a rate limiting enzyme of GSH synthesis. The ability of t-BHQ to induce glutathione S-transferases (GSTs), a major class of phase II detoxifying enzymes that playa critical role in protecting cells from oxidative stress or electrophiles, was also inhibited by the agents. Transcriptional gene repression by metformin was verified by the GSTA2 promoter luciferase assay. Moreover, either metformin or AICAR treatment significantly decreased t-BHQ-dependent induction of other GSTs (i.e., $GST{\mu}$ and $GST{\pi}$ forms). Taken together, our data indicate that metformin treatment may result in the repression of ${\gamma}$-glutamylcysteine synthetase and glutathione S-transferase genes possibly via AMPK activation.

Evolution of Microstructure and Mechanical Properties of a Ni Base Superalloy during Thermal Exposure (니켈기 초내열합금의 열간노출에 따른 미세조직 및 기계적 특성 변화)

  • Kim, In-Soo;Choi, Baig-Gyu;Jung, Joong-Eun;Do, Jeong-Hyeon;Jung, In-Yong;Jo, Chang-Yong
    • Journal of Korea Foundry Society
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    • v.36 no.5
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    • pp.159-166
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    • 2016
  • The microstructural evolution of a cast Ni base superalloy, IN738LC, has been investigated after long term exposure at several temperatures. Most of the fine secondary ${\gamma}^{\prime}$ particles resolved after 2000 hour exposure at $816^{\circ}C$. At higher temperatures of $871^{\circ}C$ and $927^{\circ}C$, secondary ${\gamma}^{\prime}$ resolved after 1000 hours of exposure, and cuboidal primary ${\gamma}^{\prime}$ grew with exposure time. During the thermal exposure, ${\sigma}$ phase formed at all tested temperatures, and ${\eta}$ phase was observed around interdendritic regions due to carbide degeneration. The influence of microstructural evolution during thermal exposure on the mechanical properties has been analyzed. The effects of ${\gamma}^{\prime}$ particle growth are more pronounced on the high temperature creep properties than on the room temperature tensile properties.