• 제목/요약/키워드: ${\eta} _{c*}$

검색결과 360건 처리시간 0.022초

근사직교 경계고정 곡선좌표계를 사용한 수치적 격자생성 (The numerical grid generation using the nearly orthogonal boundary-fitted curvilinear coordinate systems)

  • 맹주성;신종균
    • 대한기계학회논문집
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    • 제12권3호
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    • pp.561-565
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    • 1988
  • 본 연구에서는 제어함수를 수식으로부터 유도하여 자동적인 격자간격제어가 가능한 "근사직교 경계고정곡선좌표계"를 생성하는 새로운 방법을 제시하여 2차원영역 에 대한 그 적용을 논의하고자 한다. 논의하고자 한다.

GENERALIZED BI-QUASI-VARIATIONAL-LIKE INEQUALITIES ON NON-COMPACT SETS

  • Cho, Yeol Je;Chowdhury, Mohammad S.R.;Ha, Je Ai
    • 대한수학회논문집
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    • 제32권4호
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    • pp.933-957
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    • 2017
  • In this paper, we prove some existence results of solutions for a new class of generalized bi-quasi-variational-like inequalities (GBQVLI) for (${\eta}-h$)-quasi-pseudo-monotone type I and strongly (${\eta}-h$)-quasi-pseudo-monotone type I operators defined on non-compact sets in locally convex Hausdorff topological vector spaces. To obtain our results on GBQVLI for (${\eta}-h$)-quasi-pseudo-monotone type I and strongly (${\eta}-h$)-quasi-pseudo-monotone type I operators, we use Chowdhury and Tan's generalized version of Ky Fan's minimax inequality as the main tool.

Ni기 초내열 합금 LESS 1의 합금설계 및 평가: I. 합금 설계 및 고온 상 안정성 평가 (Alloy Design and Properties of Ni based Superalloy LESS 1: I. Alloy Design and Phase Stability at High Temperature)

  • 윤정일;강병일;최봉재;김영직
    • 한국주조공학회지
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    • 제33권5호
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    • pp.215-225
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    • 2013
  • The alloys required for fossil power plants are altered from stainless steel that has been used below $600^{\circ}C$ to Ni-based alloys that can operate at $700^{\circ}C$ for Hyper Super Critical (HSC) steam turbine. The IN740 alloy (Special Metals Co. USA) is proposed for improved rupture strength and corrosion resistance at high temperature. However, previous studies with experiments and simulations on stable phases at about $700^{\circ}C$ indicated the formation of the eta phase with the wasting of a gamma prime phase, which is the most important reinforced phase in precipitation hardened Ni alloys, and this resulted in the formation of precipitation free zones to decrease the strength. On the basis of thermodynamic calculation, the new Ni-based superalloy named LESS 1 (Low Eta Sigma Superalloy) was designed in this study to improve the strengthening effect and structure stability by depressing the formation of topologically close packed phases, especially sigma and eta phases at high temperature. A thermal exposure test was carried out to determine the microstructure stability of LESS 1 in comparison with IN740 at $800^{\circ}C$ for 300 hrs. The experimental results show that a needle-shaped eta phase was formed in the grin boundary and it grew to intragrain, and a precipitation free zone was also observed in IN740, but these defects were entirely controlled in LESS 1.

3D 복극충진전기분해를 이용한 원전 ETA에 의해 유발된 폐수 내 COD 및 T-N 제거 (Removal of COD and T-N caused by ETA from Nuclear Power Plant Wastewater using 3D Packed Bed Bipolar Electrode System)

  • 김한기;정주영;신자원;박주양
    • 상하수도학회지
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    • 제26권3호
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    • pp.409-421
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    • 2012
  • Ethanolamine (ETA) is mainly used to prevent corrosion of pipe in secondary cooling system of nuclear power plant. Condensed ETA in wastewater could increase COD and T-N when it was emitted to natural water system. Compared to conventional treatments, electrochemical oxidation process using packed bed bipolar electrodes was adopted to treat COD and T-N. According to arrangement of feeder electrode, single packed bed bipolar electrode reactor and multi-paired packed bed bipolar reactor were developed and conventional zero-valent iron (ZVI) was selected as conducting bipolar electrode. Bipolar electrodes were coordinated three-dimensionally in the reactor. The experimental results showed that COD and T-N was little removed in unit system at different pH condition (pH 8 and 11) on 100V. However, in multi-paired system that applied 600V, COD was eliminated 80.85% (anode-cathode-anode, A-C-A) and 85.11% (cathode-anode-cathode, C-A-C), respectively. T-N was also removed 96.88% (A-C-A) and 90.63% (C-A-C), simultaneously. Current efficiency was estimated both single and multi-paired system. At unit bipolar packed bed reactor, current efficiency was almost zero, however in multi-paired system, current efficiency was 300~500% at A-C-A and 250~350% at C-A-C. Current efficiency was over 100% hence it was confirmed that this system is more effective than conventional electrochemical oxidation system.

High-Performance Flexible Organic Light-Emitting Devices using Amorphous Indium Zinc Oxide Anode

  • Kang, Jae-Wook;Jeong, Won-Ik;Kim, Han-Ki;Kim, Do-Geun;Lee, Gun-Hwan;Kim, Jang-Joo
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권2호
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    • pp.1425-1428
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    • 2007
  • The amorphous IZO on flexible substrate (PC) shows similar electrical conductivity and optical transmittance with commercial ITO glass even though it was prepared at $<50\;^{\circ}C$. Moreover, it exhibits little resistance change during 5000 bending cycles, demonstrating good mechanical robustness. A green phosphorescent OLED fabricated on amorphous IZO on flexible PC shows maximum external quantum efficiency of ${\eta}_{ext}=13.7\;%$ and power efficiency of ${\eta}_p=32.7\;lm/W$, which are higher than a device fabricated on a commercial ITO on glass (${\eta}_{ext}=12.4%$ and ${\eta}_p=30.1\;lm/W$) and ITO on flexible PC (${\eta}_{ext}=8.5%$ and ${\eta}_p=14.1\;lm/W$).

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Viscosity and Diffusion Constants Calculation of n-Alkanes by Molecular Dynamics Simulations

  • Lee, Song-Hi;Chang, Tai-Hyun
    • Bulletin of the Korean Chemical Society
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    • 제24권11호
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    • pp.1590-1598
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    • 2003
  • In this paper we have presented the results for viscosity and self-diffusion constants of model systems for four liquid n-alkanes ($C_{12}, C_{20}, C_{32}, and C_{44}$) in a canonical ensemble at several temperatures using molecular dynamics (MD) simulations. The small chains of these n-alkanes are clearly $<{R_{ee}}^2>/6<{R_g}^2>>1$, which leads to the conclusion that the liquid n-alkanes over the whole temperatures considered are far away from the Rouse regime. Calculated viscosity ${\eta}$ and self-diffusion constants D are comparable with experimental results and the temperature dependence of both ${\eta}$ and D is suitably described by the Arrhenius plot. The behavior of both activation energies, $E_{\eta}$ and $E_D$, with increasing chain length indicates that the activation energies approach asymptotic values as n increases to the higher value, which is experimentally observed. Two calculated monomeric friction constants ${\zeta}$ and ${\zeta}_D$ give a correct qualitative trend: decrease with increasing temperature and increase with increasing chain length n. Comparison of the time auto-correlation functions of the end-to-end vector calculated from the Rouse model for n-dodecane ($C_{12}$) at 273 K and for n-tetratetracontane ($C_{44}$) at 473 K with those extracted directly from our MD simulations confirms that the short chain n-alkanes considered in this study are far away from the Rouse regime.

Kinetics and Stereochemistry of CO Substitution Reactions of Half-Open Chromocene Carbonyls(Ⅱ) : Reactions of Cp$(\eta^{5}-2,4-Me_{2}C_{5}H_{5})$CrCO and Phosphines

  • Chung, Jong-Jae;Roh, Byung-Gill
    • Bulletin of the Korean Chemical Society
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    • 제14권6호
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    • pp.669-673
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    • 1993
  • The CO substitution reactions of the complex, $Cp(S-2,4-Me_2C_5H_5)CrCo$ with $PR_3(PR_3=PMePh_2,\;P(OCH_3)_3,\;PMe_2Ph)$ were investigated spectrophotometrically at various temperatures. From the reaction rates, it was suggested that the CO substitution reaction took place by first-order (dissociative) pathway. Activation parameters in decaline were ${\Delta}H^{\neq}\;=\;22.0\;kcal{\cdot}mol^{-1}$, ${\Delta}S^{\neq}=\;-3.8cal{\cdot}mol^{-1}{\cdot}K^{-1}$. Unusually low value of ${\Delta}S{\neq}$ suggests an ${\eta}^5-S{\to}{\eta}^5-U$ conversion of the pentadienyl ligand. This suggestion was confirmed by the Extended-Huckel molecular orbital (EHMO) calculations, which revealed that the total energy of $Cp(S-2,4-Me_2C_5H_5$)CrCO is about 0.42 kcal/mol more lower than that of $Cp(U-2,4-Me_2C_5H_5)CrCO$ and the energy of $[Cp(U-2,4-Me_2C_5H_5)Cr{\cdots}CO]^{\neq} $ transition state is about 2.43 kcal/mol lower than that of $[Cp(S-2,4-Me_2C_5H_5)Cr{\cdots}CO]^{\neq}$ transition state.

실내시험을 통한 광양만 점토의 압밀 및 전단특성분석 (Analysis of Consolidation and Shear Characteristics for the Kwangyang Bay Clay)

  • 이영휘;김용준;김대길
    • 한국지반공학회논문집
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    • 제15권1호
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    • pp.151-160
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    • 1999
  • 광양만의 해저에서 채취한 점성토시료의 물리적 성질과 역학적 특성을 규명하기 위한 일련의 실내시험을 수행하였다. 주요 시험내용은 제반 물리적 성질시험, 표준압밀시험, 비배수 및 배수 삼축시험(CIU, CID) 등이다. 통일분류에 의하면 CL, CH로 구분되는 광양만 점토는 자연함수비, 38.3~84.6%, 액성지수, 0.71~0.98 이고 과압밀비가 1.06~l.60인 실질적인 정규압밀상태라고 볼 수 있다. 비배수 삼축시험에서의 유효응력경로는 (q, p)공간에서 등방압밀응력($p_0$) 으로 규준화되고, 등 전단변형률선은 원점을 통과하며 선형적이다. 비배수 전단변형률($\varepsilon$)은 응력비($\eta$) 만의 함수이고, ($\varepsilon/\eta, \eta$) 공간에서 절편값을 갖는 직선으로 나타났다. 또한, 등방압밀응력으로 규준화된 간극수압도 응력비에 대하여 직선이고, 그 구배, C는 간극수압 매개변수로 정의될 수 있다. 이상에서 기술된 경향을 근거로 하여 비배수 응력경로 및 전단변형률을 예측할 수 있는 계산식을 제안하였고, 제안식에 의하여 계산된 응력경로와 전단변형률은 기존의 Cam-clay이론 보다 실측치에 더 가까운 값을 주는 것으로 나타났다. 배수시험 결과에서 얻어진 응력경로 상의 파괴점은 비배수 응력경로의 한계상태선과 동일 선상에 위치하며, 이 사실은 한계상태이론의 기본 개념과 일치한다.

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반응표면분석법에 의한 전곡립의 압출성형공정 분석 (Analysis of Whole Grains Extrusion by Response Surface Methodology)

  • 신해헌;박보선;이혜림;최문정;황재관
    • 한국식품과학회지
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    • 제33권6호
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    • pp.686-692
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    • 2001
  • 전곡립을 이용한 기능성 식품개발을 위하여 현미, 현미찹쌀, 보리, 현미율무를 온도 $110{\sim}130^{\circ}C$, 수분함량 $15{\sim}25%$, 스크류속도 $200{\sim}300rpm$의 조건에서 압출성형하고, 반응표면분석법(RSM)을 이용하여 최적조건을 분석하였다. 압출공정에 의한 전곡립의 수용화 효과는 수분용해지수(WSI), 농도(수율), 고유점도를 측정하였으며, 수율과 고유점도를 동시에 고려하여 새로운 무차원군의 최적인자인 $([\eta])$를 적용하여 최적조건을 찾고자 하였다. 각 조건별 실험결과를 반응표면분석을 실시하여 본 결과, 종속변수들에 대한 결정계수$(R^2)$$0.936{\sim}0.984$ 범위로 나타났다. 현미의 경우에는 수용화 수율, 현미찹쌀은 고유점도, 보리와 현미율무는 수용화 수율과 고유점도에 대해서 모델식이 유의성을 나타내었다. 특히 독립변수 중에서는 수분함량이 가장 큰 영향을 보였다. 최적인자인 $([\eta])$에는 고유점도가 더 큰 영향을 미치므로, 현미의 경우에서는 유의성을 보이지 않았다. 현미의 경우를 제외하고 최적화 인자로 설정한 $([\eta])$의 최적값을 찾기 위하여 회귀분석을 한 결과 임계점은 스크류 속도는 약 300rpm, 수분함량은 20%, 온도는 $120^{\circ}C$인 지점에서 나타났다.

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두께에 따른 비정질 칼코게나이드 $Ag/As_{40}Ge_{10}Se_{15}S_{35}$ 박막의 홀로그래피 데이터 격자형성 (The Formation of Holographic Data Grating on Amorphous Chalcogenide $Ag/As_{40}Ge_{10}Se_{15}S_{35}$ Thin Films with Various Thickness)

  • 여철호;정홍배
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제55권8호
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    • pp.387-391
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    • 2006
  • The Ag photodoping effect in amorphous $As_{40}Ge_{10}Se_{15}S_{35}$ chalcogenide thin films for holographic recording has been investigated using a He-Ne laser (${\lambda}$=632.8 nm). The chalcogenide films thickness prepared in the present work were thinner in comparison with the penetration depth of recording light ($d_p=1.66{\mu}m$). It exhibits a tendency of the variation of the diffraction efficiency (${\eta}$) in amorphous chalcogende films, independently of the Ag photodoping. That is, ${\eta}$ increases rapidly at the beginning of the recording process and reaches the maximum (${\eta}_{max}$) and slowly decreases slowly with the exposed time. In addition, the value of ${\eta}_{max}$ depends strongly on chalcogenide film thickness(d) and its maximum peak among the films with d = 40, 80, 150, 300, and 633 nm is observed 0.083% at d = 150 nm (approximately 1/2 ${\Delta}n$), where ${\Delta}$n is the refractive index of chalcogenide thin film (${\Delta}n=2.0$). The ${\eta}$ is largely enhanced by Ag photodoping into the chakogenides. In particular, the value of ${\eta}_{max}$ in a bilayer of 10-nm-thick Ag/150-nm-thick $As_{40}Ge_{10}Se_{15}S_{35}$ film is about 1.6%, which corresponds to ${\sim}20$ times larger than that of the single-layer $As_{40}Ge_{10}Se_{15}S_{35}$ thin film (without Ag). And we obtained the diffraction pattern according to the formation of (P:P) polarization holographic grating using Mask pattern and SLM.