• Title/Summary/Keyword: ${\delta}^{13}C$ and C/N

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Fracture Mechanic's Approach on Retardation Behaviors under Overloading (과대 하중작용 시 균열성장 지연 거동에 대한 파괴역학적 정리)

  • Kang, Yong-Goo;Park, Jun-Young
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.11 no.5
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    • pp.13-20
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    • 2012
  • In order to clarify the effect of overload on crack growth behaviors, fatigue tests for overload were carried out for round plain specimens of SM45C steel. In the experiment, typical semi-elliptical crack shape was found and further crack growth behaviors were tested. Using three types of single overload fatigue tests, Crack growth retardation phenomenon were examined. The growth rate of surface crack(da/dN) during retardation period was analyzed in terms of ${\Delta}K$ and ${\Delta}K_{eff}$. On the growth rate of surface crack analyzed by ${\Delta}K$, the dependence of overload stress levels appears. However, on the growth rate by ${\Delta}K_{eff}$ obtained by Willenborg analysis, there is a non-liner relationship between da/dN and ${\Delta}K_{eff}$ with narrow scatter band.

Separation of $H_2$/$N_2$ Gas Mixture by PTMSP-PEI and PDMS-PEI Composite Membranes (PTMSP-PEI와 PDMS-PEI 복합막에 의한 수소/질소 혼합기체 분리)

  • 강태범;조성혜;이현경
    • Membrane Journal
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    • v.13 no.4
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    • pp.291-299
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    • 2003
  • Polymer membranes such as poly(1-trimethylsilyl-1-propyne)-polyetherimide (PTMSP-PEI) and poly(dimethylsiloxane)- polyetherimide (PDMS-PEI) composite membrane were prepared by solution casting method. To investigate the characteristics of these membranes, the analytical methods such as FT-IR, $^1H-NMR,$ DSC, TGA, GPC, and SEM have been utilized. The number-average (equation omitted) and weight-average (equation omitted) molecular weight of PTMSP were 477,920 and 673,329 respectively. The glass transition temperature ($T_g$) of PTMSP was $224^{\circ}C.$ The separation of the gas mixture ($H_2/N_2$) through the composite membranes were studied as a function of pressure. The separation factor (${\alpha}, {\beta},$ quation omitted) of the composite membranes used in this work increased as the pressure of permeation cell increased. The real separation factor (${\alpha}$), head separation factor (${\beta}$), and tail separation factor (equation omitted) of PTMSP-PEI composite membrane were 2.28, 1.17, and 1.96 respectively at ${\Delta}P$ 30psi and $25^{\circ}C.$ (${\alpha}, {\beta}$ and equation omitted of PDMS-PEI composite membrane were 3.70, 1.53, and 2.42 respectively at ${\Delta}P$ 30psi and $25^{\circ}C$.

Determination of the Origin in both Dissolved Inorganic Nitrogen and Phytoplankton at the Lake Paldang using Stable Isotope Ratios (δ13C, δ15N, δ15N-NO3 and δ15N-NH4) (질산염 및 식물플랑크톤의 안정동위원소비를 이용한 팔당호 수계내의 질소원 기원 연구)

  • Kim, Min-Seob;Lee, Eun-Jeong;Yoon, Suk-Hee;Lim, Bo-La;Park, Jaeseon;Park, Hyunwoo;Chung, Hyen-Mi;Choi, Jong-Woo
    • Korean Journal of Ecology and Environment
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    • v.50 no.4
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    • pp.452-458
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    • 2017
  • The nitrogen isotope value in both ammonium and nitrate ion were determined at 9 stations during both June and August 2016, in order to understand the origin of DIN at the Han river. ${\delta}^{15}N-NO_3$ and ${\delta}^{15}N-NH_4$ values in 8 stations (CP, SB, MHC, P4, SJ, SBC, P2, SC) were no significant variation. However ${\delta}^{15}N-NO_3$ and ${\delta}^{15}N-NH_4$ values in KK (Kyeongan stream) showed significant different in comparison with 8 stations, with an apparent increase of nitrogen isotope values. These results indicate that antropogenic nitrogen source influence on KK station. Also the ${\delta}^{13}C$ and ${\delta}^{15}N$ isotope ratio of phytoplankton (Diatom and Cyanobacteria) in KK (Kyeongan stream) showed heavier values, compared to other study stations. These results indicate that nitrogen isotope value in phytoplankton effects by different nitrogen source in study sites. These results suggest that the analysis of stable isotope ratios is a simple but useful tool for the identification of dissolved inorganic nitrogen origin in aquatic environments.

Implications on Sedimentological and Geochemical Changes in Late Quaternary Sediments and Pore Water of the Southwestern East Sea (동해 남서부 해역의 제4기 후기 퇴적물과 공극수에서의 퇴적학적 및 지화학적 변화의 의미)

  • Park, Myong-Ho;Kim, Ji-Hoon;Ryu, Byong-Jae;Lee, Song-Suk;Han, Sang-Geun;Kil, Young-Woo
    • The Korean Journal of Petroleum Geology
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    • v.12 no.1
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    • pp.20-26
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    • 2006
  • Late Quaternary stratigraphy and sedimentary environmental changes were studied based on four core sediments and their pore water taken from the southwestern part of the East Sea. The results of tephrostratigraphy and radiocarbon dates indicate that the cores cover the time interval from the middle stage of Marine Isotope Stage (MIS) 3 to MIS 1 (Holocene). The average of sedimentation rate in core sediments varies from 10 cm/kyr to 20 cm/kyr, but it fluctuates generally in particular time intervals such as MIS 2, which would be related with the sea-level changes at that time. On the other hand, the relations between ${\delta}^{13}C_{org}$ and C/N ratios suggest that the organic matter in the cores was originated mainly from marine algae. In addition, the value of ${\delta}^{13}C_{CH4}$ indicates bacterial origin rather than thermogenic one.

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Thermodynamic Characteris tics of Surface Activities of N-Alkyl Pyridinium Bromide (N-Alkyl Pyridinium Bromide류의 계면활성에 대한 열역학적 특성)

  • Kim, Yeoung-Chan;Kim, Dong-Sik;Jeong, Soon-Wook;Shon, Byoung-Chung
    • Journal of the Korean Applied Science and Technology
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    • v.8 no.2
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    • pp.105-114
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    • 1991
  • In relation to the preparation of Langmuir-Blodgett thin film, four kinds of N-alkylpyridiniurn bromide were synthesized. The values of surface tensions of these materials, measured with a Traube stalagmometer, gave the relationship between the critical micells hydrophobic radical and between CMC and temperature. Values of thermodynamic properties(${\Delta}H^0_m,\;{\Delta}S^0_m,\;{\Delta}G^0_m,$) for the formatoin of micelle were also obtained. Experiments gave the following results; at the temperature range between 40 and 60$^{\circ}C, CMC of Hexadecyl-, Octadecyl-, Eicosyl-, and Docosyl-Pyridinium Bromide were $7.64{\times}10^{-4}{\sim}9.13{\times}10^{-4},\;3.85{\times}10^{-4}{\sim}4.60{\times}10^{-4},\;2.00{\times}10^{-4}{\sim}2.39{\times}10^{-4},\;and\;1.07{\times}10^{-4}{\sim}1.28{\times}10^{-4}$ mol/l, respectively. Surface tension, ${\Gamma}_{CMC}$, of those were 33.49${\sim}$36.00, 34.78${\sim}$37.61, 35.49${\sim}$37.61 and 38.76${\sim}$55.80 dyne/cm, respectively, The relationship between CMC and the mumber of carbon atoms in the hydrophobic radical, N was expressed as follows : Log(CMC)=A-BN where A and B are constants. At the temperature range between 40 and 60$^{\circ}C$, the change of Gibbs evergy (${\Delta}G_m$) for one methylene group ($-CH_2-$) were -0.65RT, respectively, The minus values of enthalpy change (${\Delta}H_m$) suggest that the formation of micelle is exothermic. Additionally, the overall increase in the entropy change (${\Delta}S_m$) with respect to the temperature increase suggests that the formation of micelle is attained by a exothermic enthalpy directed process.

ON RADICALLY-SYMMETRIC IDEALS

  • Hashemi, Ebrahim
    • Communications of the Korean Mathematical Society
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    • v.26 no.3
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    • pp.339-348
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    • 2011
  • A ring R is called symmetric, if abc = 0 implies acb = 0 for a, b, c ${\in}$ R. An ideal I of a ring R is called symmetric (resp. radically-symmetric) if R=I (resp. R/$\sqrt{I}$) is a symmetric ring. We first show that symmetric ideals and ideals which have the insertion of factors property are radically-symmetric. We next show that if R is a semicommutative ring, then $T_n$(R) and R[x]=($x^n$) are radically-symmetric, where ($x^n$) is the ideal of R[x] generated by $x^n$. Also we give some examples of radically-symmetric ideals which are not symmetric. Connections between symmetric ideals of R and related ideals of some ring extensions are also shown. In particular we show that if R is a symmetric (or semicommutative) (${\alpha}$, ${\delta}$)-compatible ring, then R[x; ${\alpha}$, ${\delta}$] is a radically-symmetric ring. As a corollary we obtain a generalization of [13].

Contribution of Different Types of $Ca^{2+}$ channels to Catecholamine Secretion in Rat Adrenal Chromaffin Cells (부신수질 Chromaffin 세포의 $Ca^{2+}$ 통로유형이 카테콜아민 분비에 미치는 영향에 관한 정량적 연구)

  • Goo, Yang-Soak;Roh, Jin-A;Lee, Jung-Hwa;Chao, Eun-Jong
    • Progress in Medical Physics
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    • v.8 no.1
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    • pp.3-15
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    • 1997
  • Adrenal chromaffin cells secrete catecholamine in response to acetylcholine. The secretory response has absolute requirement for extracellular calcium, indication that $Ca^{2+}$ influx through voltage dependent $Ca^{2+}$ channel (VDCC) is the primary trigger of the secretion cascade. Although the existence of various types of $Ca^{2+}$ channels has been explored using patch clamp technique in adrenal chromaffin cells, the contribution of different types of $Ca^{2+}$ channels to catecholamine secretion remains to be established. To investigate the quantative contribution of different types of $Ca^{2+}$ channels to cate-cholamine secretion, $Ca^{2+}$ current($I_{Ca}$) and the resultant membrane capacitance increment($\Delta{C}_{m}$) were simultaneoulsy measured. Software based phasor detector technique was used to monitor $\Delta{C}_{m}$. After blockade of L type VDCC with nicardipine (1$\mu$M), $I_{ca}$ was blocked to 43.85$\pm$6.72%(mean$\pm$SEM) of control and the resultant ㅿC$_{m}$ was reduced ot 30.10$\pm$16.44% of control. In the presence of nicardipine and $\omega$-conotoxin in GVIA(l$\mu$M), an N type VDCC antagonist, $I_{ca}$ was blocked to 11.62$\pm$2.96% of control and the resultant $\Delta{C}_{m}$ was reduced to 26.13$\pm$8.25% of control. Finally, in the presence of L, N, and P type $Ca^{2\pm}$ channel antagonists(nicardipine, $\omega$-Conotoxin GVIA, and $\omega$-agatoxin IVA, respectively), $I_{ca}$ and resultant $\Delta{C}_{m}$ were almost completely blocked. From the observation of parallel effects of $Ca^{2+}$ channel antagonists on $I_{ca}$ and $\Delta{C}_{m}$, it was concluded that L, N, and also P type $Ca^{2+}$ channels served and $Ca^{2+}$ source for exocytosis and no difference was observed in their efficiency to evoke exocytosis amost L, N, and P type $Ca^{2+}$ channels.

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Determination of the Origin of Particulate Organic Matter at the Lake Paldang using Stable Isotope Ratios (${\delta}^{13}C$, ${\delta}^{15}N$) (입자성 유기물의 안정동위원소비를 이용한 팔당호 수계내의 유기물 기원 연구)

  • Kim, Min-Seob;Kim, Jong-Min;Hwang, Jong-Yeon;Kim, Bo-Kyong;Cho, Hang-Soo;Youn, Seok Jea;Hong, Suk-Young;Kwon, Oh-Sang;Lee, Won-Seok
    • Korean Journal of Ecology and Environment
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    • v.47 no.2
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    • pp.127-134
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    • 2014
  • Organic carbon and nitrogen stable isotope ratios of particulate organic matter (POM) were determined at 7 stations (6 stations in Han river and Paldang dam outflow station) from May to October 2013, in order to understand the origin of POM at the Han river. ${\delta}^{13}C$ values of POM in four stations showed significant seasonal changes season, but ${\delta}^{15}N$ values were enriched in around Kyeongan stream (K). POC, PN and Chl-a concentration showed a similar seasonal pattern in Kyeongan stream, with an apparent decrease from July to August. POC and PN concentration has a higher correlation with Chl-a concentration in Kyeongan stream (K). ${\delta}^{13}C$ and ${\delta}^{15}N$ values of POM has a lighter value during lower Chl-a concentration peroid, compared to other seasons. Our results revealed that Kyeongan stream (K) seemed to be influenced by substantial amount of organic manure or fertilizer input in 2013, compared to the previous year (2012). These results suggest that the analysis of stable isotope ratios is a simple but useful tool for the identification of organic matter origin in aquatic environments.

Translocation of Protein Kinase C Isozymes in the Breast Cancer Cell Line (유방 암세포에서 Protein Kinase C 동위효소의 전위)

  • Won Chul Choi;Joo Young Son;Seok Jin Seo
    • Journal of Life Science
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    • v.8 no.6
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    • pp.638-647
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    • 1998
  • Protein Kinase C (PKC) activators, phorbol 12-myristate 13-acetate (PMA), bryostatin, and dioctanoyl glycerol (DiC8), induce translocation of PKC isozymes from cytoplasm to plasma membrane or into nucleus. The activated PKC negatively modulates growth of human breast cancer cells. Antiproliferative effect and translocation of PKC were investigated in MCF-7 cells. The translocation of activated PKC isozymes by PMA, bryostatin and DiC8 was occurred at the various different regions in MCF-7 cell. PKC $\alpha$ and $\beta$ could be translocated to the nucleus or the nuclear mem-brane, and PKC $\delta$and $\varepsilon$ to cell membrane by PMA while DiC8 and bryostatin induced the translocation of PKC $\alpha$ and $\beta$ to the nucleus or plasma membrane, respectively. In the antiproliferative effect of PKC activators, PMA ($IC_{50}$/ values of 1.2$\pm$0.3nM) and DiC8 ($IC_{50}$/ values of 5.0$\pm$1.1$\mu$M) inhibited the cell growth. Bryostatin also inhibited the cell growth but to a much less degree than one obser-ved with PMA : 16% growth reduction by 100nM bryostatin. However, PMA treated with bryostatin induced gro-wth inhibition, but PMA with DiC8 at 10$\mu$M was not effective. These results suggest that each PKC isozyme is tran-slocated to various specific sites, and that especially, PKC $\alpha$ isozyme plays an important role in control of antiprolife-raive function of cell growth.

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Intraspecific diet shifts of the sesarmid crab, Sesarma dehaani, in three wetlands in the Han River estuary, South Korea

  • Yang, Dongwoo;Han, Donguk;Park, Sangkyu
    • Journal of Ecology and Environment
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    • v.43 no.1
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    • pp.31-42
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    • 2019
  • Background: Han River estuary is a national wetland reserve near the Demilitarized Zone (DMZ) between South Korea and North Korea. This trans-boundary estuary area has been well preserved and shows distinctive plant communities along the salinity gradient. To elucidate energy flows and nutrient cycling in this area, we studied trophic relations between the dominant sesarmid crab, Sesarma dehaani, and food sources in three wetlands with different environments along the estuarine gradients. Results: Stable isotope signatures (${\delta}^{13}C$ and ${\delta}^{15}N$) of the crabs were significantly different among the sites and body size classes. Seasonal changes in ${\delta}^{13}C$ of small crabs were distinct from those of large individuals at all the sites. The isotopic values and fatty acid profiles of the crabs were more different among the sites in September than in May. In May, large-sized crabs utilized more plant materials compared to other dietary sources in contrast to small-sized crabs as revealed by a stable isotope mixing modeling, whereas contributions to diets of crabs were not dominated by a specific diet for different body size in September except at site 1. Based on PCA loadings, fatty acid content of $18:3{\omega}3$, known as a biomarker of plant materials, was the main factor to separate size groups of crabs in May and September. The ${\delta}^{13}C$ value of sediment had high correlation with those of small-sized crabs at site 1 and 2 when 1-month time lag was applied to the value for crabs during the surveyed period. Conclusions: Based on the stable isotope and fatty acid results, the consumption habits of S. dehaani appear to be distinguished by sites and their size. In particular, smaller size of S. dehaani appears to be more dependent on fewer food sources and is influenced more by the diet sources from the sediments in Han River estuary.