• 제목/요약/키워드: ${\delta}^{13}$C

검색결과 464건 처리시간 0.025초

고체산화물 연료전지의 Samarium Oxide 혼합 공기극에 대한 열특성 분석 (Thermal Characteristics of Samarium-based Composite Cathode ($Sm_{0.5}Sr_{0.5}CoO_{3-\delta}/ Sm_{0.2}Ce_{0.8}O_{1.9}$) for Intermediate Temperature-operating Solid Oxide Fuel Cell)

  • 백승욱;배중면
    • 대한기계학회:학술대회논문집
    • /
    • 대한기계학회 2007년도 춘계학술대회B
    • /
    • pp.2021-2025
    • /
    • 2007
  • Performance of single cell at solid oxide fuel cell (SOFC) system is largely affected by electrocatalytic and thermal properties of cathode. Samarium-based perovskite oxide material is recently recognized as promising cathode material for intermediate temperature-operating SOFC due to its high electrocatalytic property. Perovskite structured $Sm_{0.5}Sr_{0.5}CoO_{3-\delta}$ and its composite material, $Sm_{0.5}Sr_{0.5}CoO_{3-\delta}/Sm_{0.2}Ce_{0.8}O_{1.9}$ were investigated in terms of area specific resistance (ASR), thermal expansion coefficient (TEC), thermal cycling and long term performance. $Sm_{0.2}Ce_{0.8}O_{1.9}$ was used as electrolyte material. Electrochemical ac impedance spectroscopy (EIS) and dilatometer were used to measure the cathodic properties. Composite cathode ($Sm_{0.5}Sr_{0.5}CoO_{3-\delta}$: $Sm_{0.2}Ce_{0.8}O_{1.9}$ = 6:4) showed a good ASR of 0.13${\Omega}$ $cm^2$ at 650$^{\circ}C$ and its TEC value was 12.3${\times}$10-6/K at 600$^{\circ}C$ which is similar to the value of ceria-based electrolyte of 11.9${\times}$10-6/K. Performance of composite cathode was maintained with no degradation even after 13 times thermal cycle test.

  • PDF

탄산염암 층준교대형 백전광상의 천열수 금-은 광화작용과 생성환경 (Epithermal Gold-Silver Mineralization and Depositional Environment of Carbonate-hosted Replacement Type Baegjeon Deposits, Korea)

  • 이찬희;박희인
    • 자원환경지질
    • /
    • 제29권2호
    • /
    • pp.105-117
    • /
    • 1996
  • The Baegjeon Au-Ag and Sb deposits, small of disseminated-type gold deposits are formed as a result of epithermal processes associated a shallow-seated Cretaceous Yeogdun granitoids intrusion. The orebodies are formed by the replacement of carbonate minerals in thin-bedded oolitic limestone beds favorable for mineralization within the upper-most Cambrian Pungchon Limestone Formation. The mineralization can be recognized one stage, ore minerals composed of base metal sulfides, electrum, AgSb-S, Ag-Cu-S, and Sb-S minerals. Gold-bearing minerals consist of electrum and submicroscopic invisible gold in pyrite and arsenopyrite. The composition of electrums ranges from 33.58 to 63.48 atomic % Ag. Fluid inclusion studies reveal that ore fluids were low saline $NaCl-CO_2-H_2O$ system. Temporary fluid mixing and boiling occured in later stage. Fluid inclusion data indicates the homogenization temperatures and salinities of NaCl eqivalent wt% were 176 to $246^{\circ}C$ and from 0.0 to 4.8 wt%, respectively. And $-logfs_2$, of mineralization obtained by thermodynamic considerations as 12.4 to 13.8 atm. The ${\delta}^{34}S_{H_2S}$, values of hydrothermal sulfides were calculated to be 6.8 to 10.2‰ which was of sedimentary origin. The ${\delta}^{18}O_{H_2O}$ and ${\delta}^{13}C_{CO_2}$, range from -3.9 to 9.6‰, from -1.1 to -2.2‰, and ${\delta}D$ range from -89 to -118‰, respectively. The Au deposition during mineralization seems to have occurred as a result of decrease of temperature, $fs_2$, $fo_2$, and pH probably due to oxidation by meteoric water mixing, which destabilized original $Au(HS)^-{_2}$. The mineralization of the Baegjeon deposits is similar to the Carlin-type deposits characterized by sediments-hosted epithermal bedding replacement disseminated gold deposits.

  • PDF

Food web structure in a $Salix$ $subfragilis$ dominated wetland in Hangang estuary using stable isotopes and fatty acid biomarkers

  • Han, Dong-Uk;Yang, Dong-Woo;Lee, Eun-Joo;Park, Sang-Kyu
    • Animal cells and systems
    • /
    • 제16권2호
    • /
    • pp.162-171
    • /
    • 2012
  • We investigated food webs of a $Salix$ $subfragilis$-dominated wetland in the Janghang wetland in the Hangang estuary, which is very close to the Demilitarized Zone, along the west coast of Korea. Our study focused on understanding sesarmine crab ($Sesarma$ $dehaani$)-related food webs in a $S.$ $subfragilis$ forest. For our study, we used carbon and nitrogen stable isotopes and fatty acid biomarkers. We collected samples of plants, animals, and detrital sediment from four quadrats ($5{\times}5m^2$) set in the $S.$ $subfragilis$ community. Samples were collected from September 2006 to June 2009, except during the winter hibernation period of $S.$ $dehaani$. In the wet season, the sediment showed relatively high ${\delta}^{13}C$ and low ${\delta}^{15}N$ signatures compared with relatively low ${\delta}13C$ and high ${\delta}15N$ signatures in the dry season. Mature $S.$ $dehaani$ appeared to feed on fresh leaves and other carbon sources, such as immature individuals or fish, in addition to detrital sediment, which appeared to be the main carbon source for immature crabs. Principal component analysis of fatty acid biomarkers of $S.$ $dehaani$ showed a clear difference between immature individuals (10-30 mm) and mature ones (larger than 30 mm), indicating that the main food source for immature crabs was detrital sediment, whereas mature crabs foraged plants in addition to consuming detrital sediment. On the basis of our results from stable isotope and fatty acid analyses, mature $S.$ $dehaani$ appeared to feed on detrital sediment and fresh leaves of $S.$ $subfragilis$ in summer in addition to engaging in cannibalism of immature individuals.

Permanent Pleats 가공이 산성염료로 염색된 모직물의 색변화에 미치는 영향 (The Effect of Permanent Pleats Finish on the Color Change of Acid dyed Wool Fabrics)

  • 유화숙;김은애
    • 한국의류학회지
    • /
    • 제13권4호
    • /
    • pp.380-387
    • /
    • 1989
  • The Purpose of this study was to investigate the color changes of acid dyed wool fabrics after imparting permanent pleats with si-ro-set finish. Monoethanolamine sulfite was used as a reducing agent. Color changes were determined by measuring CIELAB values after treating the dyed fabrics with various setting temperatures, times and concentrations of MEAS. Setting temperature affected the color changes: in the order of $150^{\circ}C>130^{\circ}C>170^{\circ}C$ Setting time had a tendency to increase the color change. As the concentration of MEAS increased, $\delta$ E was increased. Azo dye was more affected than anthraquinone dye by MEAS treatment. Color changes were mainly due to $\delta$ L.

  • PDF

PULSATIONAL CHARACTERISTICS OF $\delta$ SCUTI VARIABLE HR1170

  • Kim, Seoung-Li;Lee, See-Woo
    • 천문학회지
    • /
    • 제23권1호
    • /
    • pp.1-13
    • /
    • 1990
  • New uvby photoelectric photometry was carried out for a $\delta$ Scuti variable, HR1170. By applying the Fourier method and the linear least square method, three frequencies were derived: $f_1=10.06134c/d$ ($P_1=0.^d0994$). $f_2=11.91754c/d$ ($P_2=0.^d0839$). $f_3=18.96776c/d$ ($P_3=0.^d0527$). From the observed pulsational constants and from the phase difference and amplitude ratios for color(b-y) and magnitude y. three different pulsation modes (n, l) of $f_1(0,0)$, $f_2(1,2)$, $f_3(3,2)$ are deduced, indicating the existence of nonradial mode in HR1170. Some physical parameters indicate that HR1170 is evolving at the stage of H-shell burning.

  • PDF

Molecular Characterization, Chromosomal Localizations, Expression Profile, and Association Analysis of the Porcine PECI Gene with Carcass Traits

  • Gao, H.;Fan, B.;Zhu, M.J.;Liu, Bang
    • Asian-Australasian Journal of Animal Sciences
    • /
    • 제23권1호
    • /
    • pp.7-12
    • /
    • 2010
  • The full-length cDNA of the porcine peroxisomal ${\Delta}^3$,${\Delta}^2$-enoyl-CoA isomerase (PECI) gene encodes a monofunctional peroxisomal ${\Delta}^3$,${\Delta}^2$-enoyl-CoA isomerase. Cloning and sequencing of the porcine PECI cDNA revealed the presence of an 1185-base pair open reading frame predicted to encode a 394-amino acid protein by the 5'rapid amplification of cDNA ends (5'RACE) and EST sequences. The porcine PECI gene was expressed in seven tissues (heart, liver, spleen, lung, kidney, skeletal muscle, fat) which was revealed by reverse transcriptase-polymerase chain reaction (RT-PCR). The porcine PECI was mapped to SSC71/2 p11-13 using the somatic cell hybrid panel (SCHP) and the radiation hybrid panel (RH) (LOD score 12.84). The data showed that PECI was closely linked to marker S0383. A C/T single nucleotide polymorphism in PECI exon 10 (3'UTR) was detected as a PvuII PCR-RFLP. Association analysis in our experimental pig population showed that different genotypes of PECI gene were significantly associated with the Average Backfat thickness (ABF) (p<0.05) and Buttock backfat thickness (p<0.01).

Gas Chromatography/Mass Spectrometry를 이용한 뇨중 Amineptine과 그 대사체 분석방법에 관한 연구 (Analysis of Amineptine and its Metabolites in Human Urine by Gas Chromatography/Mass Spectrometry)

  • 이정애;김영림;노동석
    • 분석과학
    • /
    • 제13권3호
    • /
    • pp.385-393
    • /
    • 2000
  • 뇨시료 중 amineptine의 (dihydro-10, 11-dibenzo[a, d] cycloheptenyl-5-amino-7-heptanoic acid) metabolites를 분석하기 위한 최적조건을 찾기 위하여 pH 변화에 따른 추출률과 세가지의 유도체화시약에 대한 반응성을 조사해본 결과 pH는 9.5, 유도체화시약은 carboxylic acid group에 MSTFA로 반응 시켰을 경우 좋은 결과를 나타내었다. GC/MS를 이용하여 amineptine을 복용한 사람의 뇨를 분석한 결과 amineptine과 그 대사물질인 dihydro-10, 11-dibenzo[a, d] cycloheptenyl-5-amino-5-pentanoic acid ($C_5$-metabolite)와 $C_5$-metabolite의 lactamized product인 ${\delta}$-lactam을 확인하였다. Amineptine과 그 metabolite들을 GC/MS-SIM mode로 분석하기 위한 monitoring ion들은 m/z 192를 공통 이온으로 선정하였으며, 각각의 분자이온을 선정하였다. Amineptine의 excretion study 결과, amineptine, ${\delta}$-lactam 및 $C_5$-metabolite는 4시간이내에 70-90%가 배설되었고 20시간 이내에 거의 배설이 완결되었다.

  • PDF

GST2 is Required for Nitrogen Starvation-Induced Filamentous Growth in Candida albicans

  • Lee, So-Hyoung;Chung, Soon-Chun;Shin, Jongheon;Oh, Ki-Bong
    • Journal of Microbiology and Biotechnology
    • /
    • 제24권9호
    • /
    • pp.1207-1215
    • /
    • 2014
  • Candida albicans, the major human fungal pathogen, undergoes morphological transition from the budding yeast form to filamentous growth in response to nitrogen starvation. In this study, we identified a new function of GST2, whose expression was required for filamentous growth of C. albicans under nitrogen-limiting conditions. The Gst2p showed Gst activity and required response to oxidative stress. The ${\Delta}gst2$ mutant displayed predominantly yeast phase growth in low ammonium media. Such morphological defect of ${\Delta}gst2$ mutants was not rescued by overexpression of Mep2p, Cph1p, or Efg1p, but was rescued by either overexpression of a hyperactive $RAS1^{G13V}$ allele or through exogenous addition of cyclic AMP. In addition, the ${\Delta}gst2$ mutants had lower levels of RAS1 transcripts than wild-type cells under conditions of nitrogen starvation. These results were consistent with the Ras1-cAMP pathway as a possible downstream target of Gst2p. These findings suggest that Gst2p is a significant component of nitrogen starvation-induced filamentation in C. albicans.

Effect of Calcium Doping in Low Angle Grain Boundaries of $YBa_2Cu_3O_{7-\delta}$ on Textured Metal Substrates

  • Kang, B.W.;A. Goyal;F.A. List;D.K. Christen;H. R. Kerchner;S. Sathyamurthy;Lee, D.F.;Martin, P.M.;Koreger, D.M.
    • Progress in Superconductivity
    • /
    • 제4권1호
    • /
    • pp.10-13
    • /
    • 2002
  • We report the effect of Ca doping in $YBa_2Cu_3O_{7-\delta}$ (YBCO) thin films grown on the Rolling- Assisted, Biaxially Textured Substrates (RABiTS) with the architecture of $CeO_2/YSZ/CeO_2/Ni$. Critical currents of bilayer and trilayer structures of $YBCO/Y_{0.7}Ca_{0.3}Ba_2Cu_3O_{7-\delta}$/(YCaBCO) as well as undoped YBCO for comparison have been measured in a wide range of temperatures and fields. For $6-8^{\circ}$ grain boundaries, 30% Ca-doping in bilayer structure enhances $J_c$ as high as 35%. The enhancement is larger at low temperatures and at magnetic fields. On the other hand, 30% Ca-doping in trilayer structure reduces $J_c$ as high as 60%. Combined with slightly lower $T_c$, this indicates that Ca is overdoped in this structure and degrades GBs.

  • PDF

경남(慶南) 동남부지역(東南部地域) 철광상(鐵鑛床)의 성인(成因)에 관(關)한 연구(硏究) (Genesis of Iron Ore Deposits in the south-eastern Part of Gyeongnam Porvince, Korea)

  • 우영균
    • 자원환경지질
    • /
    • 제21권1호
    • /
    • pp.45-56
    • /
    • 1988
  • Many hydrothermal skarn-type iron ore deposits inchiding Mulgeum, Yangseong, Maeri and Kimhae mines are distributed in the south-eastern Gyeongnam Province, Korea. The deposits are magnetite veins which occurred in propylitized andesitic rock near the contact with late Cretaceous Masanite. Symmetrical zoned skarns are commonly developed around the magnetite veins. The order of the skarn zones from the vein is garnet-quartz skarn, epidote skarn, and epidote-orthoclase skarn. The garnets include isotropic or anisotropic andradite($Ad_{100{\sim}70}$), and the epidotes are composed of pistacite($Ps_{21-31}$). Fe contents of the epidotes generally increase toward the magnetite veins. Epidotes and garnets often show compositional variations from grain to grain, that is, their Fe and Al contents vary inversely. This suggests that the variations depend mainly upon $fo_2$ during the skarnization. Oxygen and carbon isotope analyses of minerals from andesitic rock, micrographic granite, major skarn zones and post-mineralization zones were conducted to provide the information on the formation temperature, the origin and the evolution of the hydrothermal solution forming the iron ore deposits. Becoming more distant from the ore vein, temperatures of skarn zones represent the decreasing tendency, but most ${\delta}O^{18}$ and ${\delta}O^{18}_{H_2O}$ values of skarn minerals represent no variation trend, and also the values are relatively low. Judging from all the isotopic data from the ore deposits, the major source of hydrothemal solution altering the skarn zones and precipitating the ore bodies was magmatic water derived from the more deeply seated micrographic granite. This high temperature hydrothermal solution rising through the fissures of propylitized andesitic rock was mixed with some meteoric water, and the extensive isotopic exchange occurred with the propylitized andesitic rock. During this process, the temperature and ${\delta}O^{18}_{H_2O}$ value of hydrothermal solution were lowered gradually. At the stage of iron ore precipitation, because after all the alteration was already finished, the oxygen isotopic exchange with the wall rock was nearly not taken. The relatively high ${\delta}O^{18}$ and ${\delta}O^{18}_{H_2O}$, and relatively low ${\delta}C^{13}$ values of calcites of post mineralization stage, are the results of leaching of the high ${\delta}O^{18}$ chert xenolith in the andesitic rock and low ${\delta}C^{13}$ andesitic rock.

  • PDF