• Title/Summary/Keyword: ${\beta}$-Sulfenylation

Search Result 3, Processing Time 0.014 seconds

Total Synthesis of 11-Deoxy-$\beta$-rhodomycinone Antitumor Antibiotics (항암항생제 11-Deoxy-$\beta$-rhodomycinone의 합성)

  • 노영쇠;강혼수;신홍식
    • YAKHAK HOEJI
    • /
    • v.37 no.6
    • /
    • pp.555-560
    • /
    • 1993

  • Methyl 3-[(phenylsulfonyl)methyl]-1, 4, 8-trimethoxy-2-naphthoate(7) preparad by 3 steps was condensed with 5-ethyl-2-cyclohexen-1-one(8) to afford the teracyclic aromatic ring system compound 10, which was stepwise converted into the precursor of 11-Deoxy-$\beta$-rhodomycinone by means of various functional groups transformation.

  • PDF