• Journal of the Korean Applied Science and Technology
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• v.14 no.3
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• pp.39-46
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• 1997

Ultraviolet spectrophotometric investigation has been carried out on the rate constants for 1,3-dipolar cycloaddition of 4-substituted-3-phenyloxadiazole derivatives with dipolarophiles such as phenyl acetylene, propiolic acid methyl ester and dimethylacetylene dicarboxylate. From there, the rate constants for 1,3-dipolar cycloaddition were determined at 80, 100 and $120^{\circ}C$, and the reaction rates were increased with increasing temperature. From these rate constants, the values of the thermodynamic activation parameters were obtained. Some thermodynamic activation parameters such as $E_{\alpha}$, ${\Delta}H^{\ast}$, ${\Delta}S^{\ast}$ and ${\Delta}G^{\ast}$ from Arrhenius equation were also calculated for the electrophilic 1,3-dipolar cycloaddition of 3-phenyloxadiazole derivatives with dipolarophiles. In order to the proposal the mechanism and reactivity of 1,3-dipolar cycloaddition reaction, the effect of substituents having various kinds of electron withdrawing or releasing groups were examinated. Considering the effect of substituents, an electron withdrawing group attached at the 4-carbon position in 3-phenyloxadiazole derivatives decreases the reaction rate because of the lack of electron density in 3-phenyloxadiazole ring.

• The Pure and Applied Mathematics
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• v.10 no.4
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• pp.199-206
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• 2003

Let N be a right near-ring. N is said to be strongly reduced if, for $a\inN$, $a^2 \in N_{c}$ implies $a\;\in\;N_{c}$, or equivalently, for $a\inN$ and any positive integer n, $a^{n} \in N_{c}$ implies $a\;\in\;N_{c}$, where $N_{c}$ denotes the constant part of N. We will show that strong reducedness is equivalent to condition (ⅱ) of Reddy and Murty's property $(^{\ast})$ (cf. [Reddy & Murty: On strongly regular near-rings. Proc. Edinburgh Math. Soc. (2) 27 (1984), no. 1, 61-64]), and that condition (ⅰ) of Reddy and Murty's property $(^{\ast})$ follows from strong reducedness. Also, we will investigate some characterizations of strongly reduced near-rings and their properties. Using strong reducedness, we characterize left strongly regular near-rings and ($P_{0}$)-near-rings.

• Publications of The Korean Astronomical Society
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• v.30 no.2
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• pp.517-519
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• 2015

A large-scale neutral hydrogen ($H\small{I}$) ring serendipitously found in the Leo I galaxy group is 200 kpc in diameter with $M_{H\small{I}}{\sim}1.67{\times}10^9M_{\odot}$, unique in size in the Local Universe. It is still under debate where this $H\small{I}$ ring originated - whether it has formed out of the gas remaining after the formation of a galaxy group (primordial origin) or been stripped during galaxy-galaxy interactions (tidal origin). We are investigating the optical and $H\small{I}$ gas properties of the dwarf galaxies located within the gas ring in order to probe its formation mechanism. In this work, we present the photometric properties of the dwarfs inside the ring using the CFHT MegaCam $u^{\ast}$, $g^{\prime}$, $r^{\prime}$ and $i^{\prime}$-band data. We discuss the origin of the gas ring based on the stellar age and metal abundance of dwarf galaxies contained within it.

• Kyungpook Mathematical Journal
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• v.61 no.1
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• pp.23-32
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• 2021

Let D be an integral domain with quotient field K, X an indeterminate over D, ∗ a star operation on D, and Cl∗ (D) be the ∗-class group of D. The ∗w-operation on D is a star operation defined by I∗w = {x ∈ K | xJ ⊆ I for a nonzero finitely generated ideal J of D with J∗ = D}. In this paper, we study two star operations {∗} and [∗] on D[X] defined by A{∗} = ∩P∈∗w-Max(D) ADP [X] and A[∗] = (∩P∈∗w-Max(D) AD[X]P[X]) ∩ AK[X]. Among other things, we show that Cl∗(D) ≅ Cl[∗](D[X]) if and only if D is integrally closed.

• Applied Biological Chemistry
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• v.39 no.2
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• pp.140-146
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• 1996

Imidacloprid and a series of the related compounds were synthesized, and influence of 3-N substituents(R) on the insecticidal activities against Brown plant hopper(Nilaparvata lugens) and Green peach aphid(Myzus persicae) were examined quantitatively from the structure-activities relationships(Shh) techniques. The results indicated that the molecular hydrophobicity$({\pi})$ and inductive substituent constant$({\sigma}^{\ast})$ of substituents(R) at 3-nitrogen position on the imidazolidine ring were important factors. Variations in the potency were parabolically related to the both constants. In case of Brown plant hopper, optimum value of ${\pi}$ constant was 0.52, whereas the value of ${\sigma}^{\ast}$ constant against Green peach aphid was 1.17, respectively. Among them, the strong electron withdrawing groups$({\sigma}^{\ast}>0)$ such as methyl and benzenesulfonyl group(7 & 8) showed lower insecticidal activity and non-substituted, 1(imidacloprid) showed the best insecticidal activity. It seems that the intramolecular associated(H-bond) form between 2-N-nitro group and 3-imid group may contribute to the higher insecticidal activity to the both sucking insects. And in aqueous solution, 1 showed higher residual activity below pH 6.0, and the half-life$(T_{1/2})$ was about 6 month at pH 7.0 $(ca.\;k_{obs.}:5{\times}10^{-8}sec.^{-1})$ and $45^{\circ}C$.

• Analytical Science and Technology
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• v.24 no.3
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• pp.173-182
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• 2011

This research examined prostanozol and its metabolites in urine of women who took the medicine (prostanozol). Prostanozol and its metabolites were successfully separated and detected by using LC/ESI/MS and GC/TOF-MS. Mass spectrum of LC/ESI/MS estimated molecular weight of Prostanozol and its metabolites and that of GC/TOF-MS verified them. For M1, carbon number 17 of Prostanozol substituted to a keto group and it is called 17-keto-Prostanozol. M2 turned out to be hydroxy-17-keto-Prostanozol. It came from substitution of one hydroxyl group of pyrazole nucleus and A-ring of M1. Substitution of one hydroxyl group of B-ring or C-ring became M3, hydroxy-17-keto-Prostanozol. M4 was found to be a hydroxy-17-keto-Prostsnozol transposed from one hydroxyl group to a D-ring. M5 has a hydroxyl group of carbon number 17. One hydroxyl group is substituted from B-ring or C-ring and it is assumed to be hydroxy-17-hydroxy-Prostanozol. M6 was turned out to be dihydroxy-17-keto-Prostanozol transposed from one hydroxyl group to pyrazole nucleus or A-ring and to B-ring or C-ring. Like M6, M7 has a keto group at carbon number 17 and was identified as dihydroxy-17-keto-Prostanozol. M7 has one hydroxyl group at pyrazole nucleus or A-ring and also at D-ring. At last M8 was found to be dihydroxy-17-hydroxy-Prostanozol. Pyrazole nucleus or A-ring has got one hydroxyl group and other rings were substituted to another hydroxyl group. From above, M5, M7 and M8 were verified as new metabolites that were not discovered yet. Prostanozol and all of the 8 metabolites formed glucuronic conjugates as a result of conjugation reaction test in human body. Some of 8 metabolites were excreted without forming conjugates. Particularly M6 and M7 were excreted as sulfate conjugates.

• 한국연소학회:학술대회논문집
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• 2003.05a
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• pp.159-165
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• 2003

Self-excited noise generation from laminar flames in thin annular jets of methane/air premixture has been investigated experimentally. Various flames were observed in this flow configuration, including conical shape flames, ring shape flames, steady crown shape flames, and oscillating crown shape flames. Self-excited noise with the total sound pressure level of about 70dB was generated from the oscillating crown shape flames for the equivalence ratio larger than 0.95. Sound pressure and $CH^{\ast}$ chemiluminescence were measured by using a microphone and a photomultiplier tube. The frequency of generated noise was measured as functions of equivalence ratio and premixture velocity. A frequency doubling phenomena have also been observed. The measured $CH^{\ast}$ chemiluminescence data were analyzed from which the corresponding sound pressure has been calculated. By comparing the data with those of measured ones, the noise source can be attributed to the flame front fluctuation near the edge of the oscillating crown-shape flames. The flame stability regime was influenced sensitively to the supplying air through the inner tube.

• Journal of the Korean Chemical Society
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• v.42 no.4
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• pp.391-397
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• 1998

The geometry of furan, relevant to the binding of bis-furan lexitropsin that contains this ring to the base pair of minor groove of DNA, is optimized by semiempirical (MNDO) and ab initio (Hartree-Fock) methods. The proton affinity and electronic structure are evaluated at the 6-31G and $6-31G^{\ast}$ level of theory for the optimized geometry. The proton affinities are also studied for various substituted furans with the electrondonating and -withdrawing groups to estimate the substituent effect on the proton affinity of furans. It has been found that the electron-donating substituents increase the proton affinity of furan, whereas the electron-withdrawing substituents decrease it. This result can be explained with atomic charge and electron density at oxygen of substituted furans.

• The Bulletin of The Korean Astronomical Society
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• v.44 no.1
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• pp.59.1-59.1
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• 2019

Immediate vicinity of a supermassive black hole (SMBH) is an important place to test general relativity in strong gravity regime. Also, this is a place where mass accretion and jet formation actively occurs at the centers of active galaxies. Theoretical studies predict presence of bright ring-like emission encircling an accreting SMBH with a diameter of about 5 Schwarzschild radii, and a flux depression at the center (i.e., BH shadow). Direct imaging of the BH shadow is accordingly of great importance in modern astrophysics. However, the angular sizes of the horizon-scale structures are desperately small (e.g., ~40-50 microarcseconds (uas) diameter for the nearest best candidates). This poses serious challenges to observe them directly. Event Horizon Telescope (EHT) is a global network of sensitive radio telescopes operating at 230 GHz (1.3 mm), providing ultra-high angular resolution of 20 uas by cutting-edge very long baseline interferometry techniques. With this resolution, EHT aims to directly image the nearest SMBHs; M87 and the galactic center Sgr $A{\ast}$ (~40-50 uas diameters). In Spring 2017, the EHT collaboration conducted a global campaign of EHT and multiwavelength observations of M87 and Sgr $A{\ast}$, with addition of the phased ALMA to the 1.3mm VLBI array. In this talk, I review results from past mm-VLBI and EHT observations, provide updates on the results from the 2017 campaign, and future perspectives.

• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.226-226
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• 2006

Ethylene was polymerized with a catalyst having sterically hindered pentamethylcyclopentadienyl ligand, $Cp^{\ast}_{2}ZrCl_{2}/MAO$, and the polymerization mixture were treated with dry oxygen (oxidative workup) to produce hydroxyl-terminated polyethylenes (PE-OH). Polyethylene-block-Poly (${\Box}-caprolactone$) was synthesized from PE-OH and ${\cdot}\^{A}-caprolactone$A by using stannous octoate as a catalyst for ring opening polymerization of ${\cdot}\^{A}-caprolactone$. Polyethylene-block-Poly(methyl methacrylate) was obtained by transforming the hydroxyl-terminated polyethylenes to macroinitiators for atom transfer radical polymerization (ATRP) and by reacting them with MMA.