• Title/Summary/Keyword: ${\alpha}-Fe_2O_3$ nanocrystals

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Removal of Heavy Metals from Wastewater using α-Fe2O3 Nanocrystals

  • Tsedenbal, Bulgan;Lee, Ji Eun;Huh, Seok Hwan;Koo, Bon Heun;Lee, Chan Gyu
    • Korean Journal of Materials Research
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    • v.30 no.9
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    • pp.447-452
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    • 2020
  • In this work, α-Fe2O3 nanocrystals are synthesized by co-precipitation method and used as adsorbent to remove Cr6+, Cd2+, and Pb2+ from wastewater at room temperature. The prepared sample is evaluated by XRD, BET surface area, and FESEM for structural and morphological characteristics. XRD patterns confirm the formation of a pure hematite structure of average particle size of ~ 40 nm, which is further supported by the FESEM images of the nanocrystals. The nanocrystals are found to have BET specific surface area of ~ 39.18 m2 g-1. Adsorption experiments are carried out for the different values of pH of the solutions, contact time, and initial concentration of metal ions. High efficiency Cr6+, Cd2+, and Pb2+ removal occur at pH 3, 7, and 5.5, respectively. Equilibrium study reveals that the heavy metal ion adsorption of the α-Fe2O3 nanocrystals followed Langmuir and Freundlich isotherm models. The Cr6+, Cd2+, and Pb2+ adsorption equilibrium data are best fitted to the Langmuir model. The maximum adsorption capacities of α-Fe2O3 nanocrystals related to Cr6+, Cd2+, and Pb2+ are found to be 15.15, 11.63, and 20 mg g-1, respectively. These results clearly suggest that the synthesized α-Fe2O3 nanocrystals can be considered as potential nano-adsorbents for future environmental and health related applications.