• Title/Summary/Keyword: ${\Gamma}$-ring

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Crystal Structure of Thiamin Tetrahydrofurfuryl Disulfide

  • Shin, Whan-Chul;Kim, Young-Chang
    • Bulletin of the Korean Chemical Society
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    • v.7 no.5
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    • pp.331-334
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    • 1986
  • The crystal structure of thiamin tetrahydrofurfuryl disulfide, one of the ring-opened derivatives of thiamin, has been determined by the X-ray diffraction methods. The crystal is monoclinic with cell dimensions of a = 8.704 (1), b = 11.207 (2), c = 21.260 (3) ${\AA}$ and ${\beta}$ = 92.44 (2)$^{circ}$, space group P2$_{1}$/c and Z = 4. The structure was solved by direct methods and refined to R = 0.076 for 1252 observed reflections measured on a diffractometer. The molecule assumes a folded conformation in which the pyrimidine and the tetrahydrofurfuryl rings are on the same side of the ethylenic plane. The pyrimidinyl, N-formyl and ethylenic planes are mutually perpendicular to each other and the N(3)-C(4) bond retains a single bond character. The structure is stabilized by an intramolecular N(4'${\alpha})-H{\cdots}O(2{\alpha}$) hydrogen bond. The molecules are connected via N(4'${\alpha}$)-H{\cdots}(N3')$ and O(5${\gamma})-H{\cdots}(N1')$ hydrogen bonds, forming a two-dimensional hydrogen-bonding network. The tetrahydrofurfuryl ring is dynamically disordered. The overall conformation as well as the packing mode is very similar to that of thiamin propyl disulfide.

GRADED INTEGRAL DOMAINS AND PRÜFER-LIKE DOMAINS

  • Chang, Gyu Whan
    • Journal of the Korean Mathematical Society
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    • v.54 no.6
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    • pp.1733-1757
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    • 2017
  • Let $R={\oplus}_{{\alpha}{\in}{\Gamma}}R_{\alpha}$ be an integral domain graded by an arbitrary torsionless grading monoid ${\Gamma}$, ${\bar{R}}$ be the integral closure of R, H be the set of nonzero homogeneous elements of R, C(f) be the fractional ideal of R generated by the homogeneous components of $f{\in}R_H$, and $N(H)=\{f{\in}R{\mid}C(f)_v=R\}$. Let $R_H$ be a UFD. We say that a nonzero prime ideal Q of R is an upper to zero in R if $Q=fR_H{\cap}R$ for some $f{\in}R$ and that R is a graded UMT-domain if each upper to zero in R is a maximal t-ideal. In this paper, we study several ring-theoretic properties of graded UMT-domains. Among other things, we prove that if R has a unit of nonzero degree, then R is a graded UMT-domain if and only if every prime ideal of $R_{N(H)}$ is extended from a homogeneous ideal of R, if and only if ${\bar{R}}_{H{\backslash}Q}$ is a graded-$Pr{\ddot{u}}fer$ domain for all homogeneous maximal t-ideals Q of R, if and only if ${\bar{R}}_{N(H)}$ is a $Pr{\ddot{u}}fer$ domain, if and only if R is a UMT-domain.

Star Formation Activity in Infra-Red Dark Cloud at ${\Gamma}53.2^{\circ}$

  • Kim, Hyun-Jeong;Koo, Bon-Chul
    • The Bulletin of The Korean Astronomical Society
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    • v.36 no.1
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    • pp.82.2-82.2
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    • 2011
  • Infra-Red Dark Clouds (IRDCs) seen silhouette against the bright Galactic background in mid-IR are a class of interstellar clouds that are dense and cold with very high column densities. While IRDCs are believed to be the precursors to massive stars and star clusters, individual IRDCs show diverse star forming activities within them. We report a remarkable example of such cloud, the IRDC at ${\Gamma}53.2^{\circ}$, and star formation activity in this cloud. The IRDC was previously identified in part as three separate, arcmin-size clouds in the catalogue of MSX IRDC candidates, but we found that the IRDC is associated with a long, filamentary CO cloud at 2 kpc from the Galactic Ring Survey data of $^{13}CO$ J = 1-0 emission, and that its total extent reaches ~ 30pc. The Spitzer MIPSGAL 24mm data show a number of reddened mid-IR sources distributed along the IRDC which are probably young stellar objects (YSOs), and the UWISH2 $H_2$ data (2.122mm) reveal ubiquitous out flows around them. These observations indicate that the IRDC is a site of active star formation with YSOs in various evolutionary stages. In order to investigate the nature of mid-IR sources, we have performed photometry of MIPSGAL data, and we present a catalogue of YSOs combining other available point source catalogues from optical to IR. We discuss the evolutionary stages and characteristics of YSOs from their IR colors and spectral energy distributions.

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Approach for Microwave Frequency Measurement Based on a Single Photonic Chip Combined with a Phase Modulator and Microring Resonator

  • Zhang, Jiahong;Zhu, Chuyi;Yang, Xiumei;Li, Yingna;Zhao, Zhengang;Li, Chuan
    • Current Optics and Photonics
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    • v.2 no.6
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    • pp.576-581
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    • 2018
  • A new approach for identification of a microwave frequency using an integrated optical waveguide chip, combined with a phase modulator (PM) and two microring resonators (MRRs), is proposed, theoretically deduced, and verified. By wavelength tuning to set the PM under the condition of a double side band (DSB), the measurement range can be started from the dc component, and the measurement range and response slope can be adjusted by designing the radius and transmission coefficient of the MRR. Simulations reveal that the amplitude comparison function (ACF) has a monotonic relationship from dc to 32.5 GHz, with a response slope of 5.15 dB under conditions of DSB modulation, when the radius values, transmission coefficients, and the loss factors are designed respectively as $R_1=400{\mu}m$, $R_2=600{\mu}m$, $t_1=t_2=0.63$, and ${\gamma}_1={\gamma}_2=0.66$. Theoretical calculations and simulation results both indicate that this new approach has the potential to be used for measuring microwave frequencies, with the advantages of compact structure and superior reconfigurability.

FUV Spectral Images of the Vela Supernova Remnant: Comparisons with X-ray and $H{\alpha}$ images

  • Kim, Il-Joong;Seon, Kwang-Il;Min, Kyoung-Wook;Han, Wonyong;Edelstein, Jerry
    • The Bulletin of The Korean Astronomical Society
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    • v.37 no.2
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    • pp.99.2-99.2
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    • 2012
  • We updated the far-ultraviolet (FUV) spectral images of the entire Vela supernova remnant (SNR) using newly processed FIMS/SPEAR data. In the present study, we compare the newly produced FUV images with the X-ray and $H{\alpha}$ images, and examine how the Vela SNR evolves and interacts with the ambient medium on a global scale. The comparison with X-ray images has revealed a FUV filamentary feature corresponding with the boundary of the northeast-southwest asymmetry of the X-ray shell. The relatively low O IV] ${\lambda}1404$ to O III] ${\lambda}{\lambda}1661$, 1666 ratio estimated on the FUV filament is compatible with the previous proposal that the observed asymmetry of the Vela SNR could be due to the ${\gamma}2$ Velorum stellar wind bubble (SWB). The southwest FUV features surrounding a faint extended X-ray region are characterized as the region where the Vela SNR is interacting slightly stronger with ambient mediums within the dim X-ray southwest section. From a comparison with the $H{\alpha}$ image, we identify a ring-like $H{\alpha}$ feature overlapped with an extended hot X-ray feature of similar size and two local peaks of C IV ${\lambda}{\lambda}1548$, 1551 emission. Their morphologies are consistent with the expected shape when the $H{\alpha}$ ring is in direct contact with the near or far side of the Vela SNR. We suggest that the B3V-type star HD 76161 found at the center of the $H{\alpha}$ ring would be the exciting source of the H II region.

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Chromosomal Aberrations Induced in Human Lymphocytes by in vitro Irradiation with $^{60}Co\;{\gamma}-rays$ (체외 방사선조사시 인체 말초혈액 임파구의 염색체이상 빈도에 관한 연구)

  • Ahn, Yong-Chan;Ha, Sung-Whan
    • Journal of Radiation Protection and Research
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    • v.18 no.2
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    • pp.1-16
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    • 1993
  • As guides to decision-making in the management of the victims in case of acute whole body or partial body radiation exposure, we studied the relationship between radiation dose and the frequency of chromosomal aberrations observed in peripheral lymphocytes that were irradiated in vitro with $^{60}Co\;{\gamma}-rays$ at doses ranging from 2Gy to 12Gy. The yields of cells with unstable chromosomal aberrations (dicentric chromosomes, ring chromosomes, and acentric fragment pairs) were 32% at 2Gy, 47% at 4Gy, 80% at 6Gy, 94% at 8Gy, and 100% at 10Gy and over. Ydr, which reflect average dose to the whole body in case of acute whole body exposure, were 1.373 at 2Gy, 0.669 at 4Gy, 1.734 at 6Gy, 2.773 at 8Gy, 3.746 at 10Gy and 5.454 at 12Gy. The relationship between radiation dose (D) and the frequency of dicentric plus ring chromosomes per cell(Ydr) could be expressed as $Ydr=9.322{\times}10^{-2}/Gy {\times}D+2.975{\times}10^{-2}/Gy^2{\times}D^2$. Qdr, which are used in estimating dose of partial body exposure and dose of past exposure, were 1.166 at 2Gy, 1.436 at 4Gy, 2.173 at 6Gy, 2.945 at 8Gy, 3.746 at 10Gy and 5.454 at 12Gy. To see how confidently this dosimetry system may be used, we obtained Qdr values from those who received one fraction of homogenous partial body irradiation of 1.BGy, 2.5Gy, and 7.OGy therapeutically; in vivo Qdr values were 1.109, 1.222 and 2.222 respectively. The estimated doses calculated from these in vivo Qdr values using the equation $Qdr=Ydr/(1- e^{-Ydr})$ were 1.52Gy, 2.48Gy, and 6.54Gy respectively, which were very close to the doses actually given.

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CLASS FIELDS FROM THE FUNDAMENTAL THOMPSON SERIES OF LEVEL N = o(g)

  • CHOI So YOUNG;Koo JA KYUNG
    • Journal of the Korean Mathematical Society
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    • v.42 no.2
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    • pp.203-222
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    • 2005
  • Thompson series is a Hauptmodul for a genus zero group which lies between $\Gamma$o(N) and its normalizer in PSL2(R) ([1]). We construct explicit ring class fields over an imaginary quadratic field K from the Thompson series $T_g$($\alpha$) (Theorem 4), which would be an extension of [3], Theorem 3.7.5 (2) by using the Shimura theory and the standard results of complex multiplication. Also we construct various class fields over K, over a CM-field K (${\zeta}N + {\zeta}_N^{-1}$), and over a field K (${\zeta}N$). Furthermore, we find an explicit formula for the conjugates of Tg ($\alpha$) to calculate its minimal polynomial where $\alpha$ (${\in}{\eta}$) is the quotient of a basis of an integral ideal in K.

AN AFFINE MODEL OF X0(mn)

  • Choi, So-Young;Koo, Ja-Kyung
    • Bulletin of the Korean Mathematical Society
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    • v.44 no.2
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    • pp.379-383
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    • 2007
  • We show that the modular equation ${\phi}^{T_n}_m$ (X, Y) for the Thompson series $T_n$ corresponding to ${\Gamma}_0$(n) gives an affine model of the modular curve $X_0$(mn) which has better properties than the one derived from the modular j invariant. Here, m and n are relative prime. As an application, we construct a ring class field over an imaginary quadratic field K by singular values of $T_n(z)\;and\;T_n$(mz).

GALKIN'S LOWER BOUND CONJECURE FOR LAGRANGIAN AND ORTHOGONAL GRASSMANNIANS

  • Cheong, Daewoong;Han, Manwook
    • Bulletin of the Korean Mathematical Society
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    • v.57 no.4
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    • pp.933-943
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    • 2020
  • Let M be a Fano manifold, and H🟉(M; ℂ) be the quantum cohomology ring of M with the quantum product 🟉. For 𝜎 ∈ H🟉(M; ℂ), denote by [𝜎] the quantum multiplication operator 𝜎🟉 on H🟉(M; ℂ). It was conjectured several years ago [7,8] and has been proved for many Fano manifolds [1,2,10,14], including our cases, that the operator [c1(M)] has a real valued eigenvalue 𝛿0 which is maximal among eigenvalues of [c1(M)]. Galkin's lower bound conjecture [6] states that for a Fano manifold M, 𝛿0 ≥ dim M + 1, and the equality holds if and only if M is the projective space ℙn. In this note, we show that Galkin's lower bound conjecture holds for Lagrangian and orthogonal Grassmannians, modulo some exceptions for the equality.

The crystal structure of pirprofen$(C_{3},\; H_{14},\; ClNO_2$), a non-steroidal antiinflammmatory agent

  • Kim, Yang-Bae;Park, Il-Yeong
    • Archives of Pharmacal Research
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    • v.19 no.1
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    • pp.71-73
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    • 1996
  • The molecular structure of pirprofen, 3-chloro-4-(2,5-dihydro-1H-pyrrol-1-yl)-.alpha.-methyl-benzeneacetic acid, was determined by single crystal X-ray diffraction analysis. The compound was recrystallized from a mixture of chloroform and toluene in triclinic, space group P over $\bar1,\; with\; a=4.577(1),\; b=11.213(2),\; C=12.485(2){\AA},\alpa.=107.39(1),\;\beta=97.79(1),\;\gamma=92.03(2),\; and Z=2$ The calculated density is $1.384 g/cm^3$. The structure was solved by the direct method and refined by full matrix least-squares procedure to the final R value of 0.034 for 1681 independent reflections. The non-aromatic dihydropyrrol group is found to be coplanar to the central aromatic ring. The molecules are dimerized through the intermolecular hydrogen bonds at the carboxyl group in the crystal.

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