• Title/Summary/Keyword: ${\Delta}$-mixing

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Critical Suspension Condition of Particles in a Shaking Vessel of Solid-Liquid System (고-액계 진동교반에서 입자의 부유화 한계조건)

  • Lee, Young-Sei;Kim, Moon-Gab;Kato, Yoshihito
    • Journal of the Korean Society of Industry Convergence
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    • v.2 no.2
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    • pp.73-81
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    • 1999
  • Shake mixing has been widely used in cell culture. The mixing performance for shake mixing, however, has not been reported quantitatively. The critical circulating frequency and the power consumption for complete suspension of particles, based on the definition of Zwietering, were measured in a shaking vessel containing a solid-liquid system. The critical suspension frequency was correlated by the equation from Baldi's particle suspension model modified with the physical properties of the particles. Critical suspension frequency was correlated as following ; $$N_{JS}={\frac{0.58\;d{_p}^{0.06}(g{\Delta}{\rho}/{\rho}_L)^{0.004}X^{0.03}}{D^{0.35}d^{0.17}{\upsilon}^{0.04}}}$$ The power consumption at the critical suspension condition in the shaking vessel was less than that in an agitated vessel with impeller.

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Thermally Stratified Hot Water Storage (태양열의 성층축열과 주택이용에 관한 연구(성층축열))

  • Pak, Ee-Tong
    • Solar Energy
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    • v.10 no.3
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    • pp.3-12
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    • 1990
  • This paper deals with experimental research to increase thermal storage efficiency of hot water stored in an actual storage tank for solar application. The effect of increased energy input rate due to stratification has been discussed and illustrated through experimental data, which was taken by changing dynamic and geometric parameters. Ranges of the parameters were defined for flow rate, the ratio of diameter to height of the tank and inlet-exit water temperature difference. During the heat storage, when the flow was lower, the temperature difference was larger and the ratio of diameter to height of the tank was higher, the momentum exchange decreased. As for this experiment, when the flow rate was 8 liter/min, the temperature difference was $30^{\circ}C$ and the ratio of diameter to height of the tank was 3, the momentum exchange was minimized resulting in a good thermocline and a stable stratification. In the case of using inlet ports, if the modified Richardson number was less than 0.004, full mixing occured and so unstable stratification occured, which mean that this could not be recommended as storage through thermal stratification. Using a distributor was better than using inlet ports to form a sharp thermocline and to enhance the stratification. It was possible to get storage efficiency of 95% by using the distributor, which was higher than a storage efficiency of 85% obtained by using inlet ports in same operation condition. Furthermore, if the distributor was manufactured so that the mainpipe decreases in diameter toward the dead end to maintain constant static pressure, it might be predicted that further stable stratification and higher storage efficiency are obtainable(ie:more than 95%).

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Epithermal Gold-Silver Mineralization and Depositional Environment of Carbonate-hosted Replacement Type Baegjeon Deposits, Korea (탄산염암 층준교대형 백전광상의 천열수 금-은 광화작용과 생성환경)

  • Lee, Chan Hee;Park, Hee-In
    • Economic and Environmental Geology
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    • v.29 no.2
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    • pp.105-117
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    • 1996
  • The Baegjeon Au-Ag and Sb deposits, small of disseminated-type gold deposits are formed as a result of epithermal processes associated a shallow-seated Cretaceous Yeogdun granitoids intrusion. The orebodies are formed by the replacement of carbonate minerals in thin-bedded oolitic limestone beds favorable for mineralization within the upper-most Cambrian Pungchon Limestone Formation. The mineralization can be recognized one stage, ore minerals composed of base metal sulfides, electrum, AgSb-S, Ag-Cu-S, and Sb-S minerals. Gold-bearing minerals consist of electrum and submicroscopic invisible gold in pyrite and arsenopyrite. The composition of electrums ranges from 33.58 to 63.48 atomic % Ag. Fluid inclusion studies reveal that ore fluids were low saline $NaCl-CO_2-H_2O$ system. Temporary fluid mixing and boiling occured in later stage. Fluid inclusion data indicates the homogenization temperatures and salinities of NaCl eqivalent wt% were 176 to $246^{\circ}C$ and from 0.0 to 4.8 wt%, respectively. And $-logfs_2$, of mineralization obtained by thermodynamic considerations as 12.4 to 13.8 atm. The ${\delta}^{34}S_{H_2S}$, values of hydrothermal sulfides were calculated to be 6.8 to 10.2‰ which was of sedimentary origin. The ${\delta}^{18}O_{H_2O}$ and ${\delta}^{13}C_{CO_2}$, range from -3.9 to 9.6‰, from -1.1 to -2.2‰, and ${\delta}D$ range from -89 to -118‰, respectively. The Au deposition during mineralization seems to have occurred as a result of decrease of temperature, $fs_2$, $fo_2$, and pH probably due to oxidation by meteoric water mixing, which destabilized original $Au(HS)^-{_2}$. The mineralization of the Baegjeon deposits is similar to the Carlin-type deposits characterized by sediments-hosted epithermal bedding replacement disseminated gold deposits.

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Evaluation of Organic Matter Sources of Phytoplankton in Paldang Reservoir using Stable Isotope Analysis (팔당호 내 식물플랑크톤 안정동위원소 분석을 통한 유기물 기원 평가)

  • Kim, Jongmin;Kim, Bokyong;Kim, Minseob;Shin, Kisik
    • Journal of Korean Society on Water Environment
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    • v.31 no.2
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    • pp.159-165
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    • 2015
  • The organic matter sources of phytoplankton and related environmental factors influencing algal bloom in Paldang reservoir were studied using nitrogen and carbon isotope ratio(${\delta}^{15}N$, ${\delta}^{13}C$). Phytoplankton samples for stable isotope analysis were collected from four points in reservoir using a plankton net. Physicochemical water quality, algal taxa and hydrological data were collected from published monitoring material. Phytoplankton samples were analyzed by IRMS. CN ratio of each sample was very similar to that of phytoplankton from literature cited. ${\delta}^{15}N$ of each sample was decreased during July. Mixing and dilution of nitrogen sources due to increment of influx by concentrated rainfall were considered as the main reason for the decline of ${\delta}^{15}N$. Based on analyzed ${\delta}^{15}N$ value of each sample, nitrogen source of Bughan river sample was presumed to come from soil. The nitrogen sources of Namhan river and Kyeongan stream samples seemed to be sewage or animal waste. Low ${\delta}^{15}N$ value in August (2012) seemed to be influenced by isotope fractionation due to the blooming of nitrogen-fixation blue-green algae (Anabaena spp.). Variation in ${\delta}^{15}N$ values particularly by blue-green algal bloom was considered the important factor for estimating the organic matter sources of phytoplankton.

Hydrogeochemistry of Some Abandoned Metal Mine Creeks in the Hwanggangri Mining District, Korea : A Preliminary Study (황강리 광화대에 분포하는 일부 폐금속 광산수계의 수리지구화학적 특성 : 예비연구)

  • 이현구;이찬희;이종창
    • Journal of the Korean Society of Groundwater Environment
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    • v.6 no.4
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    • pp.194-205
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    • 1999
  • Hydrogeochemical variation and environmental isotope at the some abandoned metal mine (Sanggok, Keumsil, Jangpung and Samdeok) creeks of the Hwanggangri mining district were carried out based upon the physicochemical properties for surface water collected of February in 1998. Hydrogeochemical composition of the all water samples are characterized by the relatively significant enrichment of Ca$^{2}$, alkaline ions, N $O_3$$^{-}$ and Cl$^{-}$ in normal surface water, whereas the surface waters near the mining area are relatively enriched in Ca$^{2+$, Mg$^{2+}$, heavy metals. HC $O_3$$^{-}$ and S $O_4$$^{2-}$. Surface waters of the mining creek have low pH, high EC and extremely high concentrations of TDS compared with surface water of the non-mining creeks. The range of $\delta$D and $\delta$$^{18}$O values (SMOW) in the waters are shown in -65.0 to-71.2$\textperthousand$ and -9.1 to-10.2$\textperthousand$. The d($\delta$D-$\delta$$^{18}$O) value with those of water samples ranged from 7.3 to 10.9. These $\delta$D and $\delta$$^{18/}$ of the acid mine water are more heavy values than those of surface water. The values have revealed the positive correlation between isotopic compositions and major elements, because those $\delta$D and $\delta$$^{18}$O values increase with increasing TDS. HC $O_3$$^{-}$ , S $O_4$$^{2-}$ and Ca$^{2+}$ concentration. Using WATEQ4F, saturation index of albite calcite, dolomite and mostly clay minerals in water of the mining area show undersaturated and progressively evolved toward the equilibrium condition due to fresh water mixing, however, surface waters of the non-mining area are nearly saturated and/or supersaturated. Geochemical modeling showed that mostly toxic heavy metals within water in the mining creek may exist largely in the from of metal-sulfate (MS $O_4$$^{2-}$), free metal (M$^{2+}$/), C $O_3$$^{-}$ and/or OH$^{-}$ complex ions. Based on the geology, water chemistry and environmental istopic data the water compositions from the Sanggok and Keumsil mine creek (consist mainly of Cambro-Ordovician carbonate rocks of the Cho-seon Supergroup) show higher PH, Ca$^{2+}$, Mg$^{2+}$ , HC $O_3$$^{-}$ and more heavy $\delta$D and $\delta$$^{18}$O values than those from the Jangpung and Samdeok mine creek (consist of age -unknown metasedimentary rocks of the Ogcheon Supergroup and/or Jurassic grani-toids), but each of these waters represents a similar hydrogeochemical evolution path by the mine water mixing.

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Experiments of Turbulent Thermal Mixing Phenomena Using Parallel Non-Isothermal Water Jets

  • Kim, Y.K.;Kim, J.M.;Lee, Y.B.;J.S. Hwang;H.Y. Nam
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.05b
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    • pp.36-41
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    • 1996
  • Turbulent thermal mixing experiments by the injection of two parallel non-isothermal water jets have been performed. The turbulent velocities and fluctuations under the isothermal conditions have been measured using LDV system. The velocity vectors have been plotted in two dimensions from the data measured at 29$\times$16 points. The thermal mixing experiments also have been conducted, where we used 45 K-type thermocouples with a sheath diameter of 0.020" which were fixed with 5 mm distance in a line at a measured height. The measured heights were 5, 10, 20, 30, 40 cm from the upper end of rectangular nozzles. We measured the turbulent temperatures under the various flow velocity conditions with 12$^{\circ}C$ $\leq$ $\Delta$T $\leq$4$0^{\circ}C$. The sampling frequency and sampling time were about 420 Hz and 10 seconds, respectively. The measured results of equal velocity parallel jets were analyzed axially and radially to obtain the variation of temperature fluctuation.tion.

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CO2 Decomposition Characteristics of Activated(Fe1-xMnx)3O4-δ and (Fe1-xCox)3O4-δ (활성화된(Fe1-xMnx)3O4-δ과 (Fe1-xCox)3O4-δ의 이산화탄소 분해 특성)

  • Park, Won-Shik;Oh, Kyoung-Hwan;Rhee, Sang-In;Suhr, Dong-Soo
    • Korean Journal of Materials Research
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    • v.23 no.4
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    • pp.219-226
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    • 2013
  • Activated magnetite ($Fe_3O_{4-{\delta}}$) has the capability of decomposing $CO_2$ proportional to the ${\delta}$-value at comparatively low temperature of $300^{\circ}C$. To enhance the $CO_2$ decomposition capability of $Fe_3O_{4-{\delta}}$, $(Fe_{1-x}Co_x)_3O_{4-{\delta}}$ and $(Fe_{1-x}Mn_x)_3O_{4-{\delta}}$ were synthesized and then reacted with $CO_2$. $Fe_{1-x}Co_xC_2O_4{\cdot}2H_2O$ powders having Fe to Co mixing ratios of 9:1, 8:2, 7:3, 6:4, and 5:5 were synthesized by co-precipitation of $FeSO_4{\cdot}7H_2O$ and $CoSO_4{\cdot}7H_2O$ solutions with a $(NH_4)_2C_2O_4{\cdot}H_2O$ solution. The same method was used to synthesize $Fe_{1-x}Mn_xC_2O_4{\cdot}2H_2O$ powders having Fe to Mn mixing ratios of 9:1, 8:2, 7:3, 6:4, 5:5 with a $MnSO_4{\cdot}4H_2O$ solution. The thermal decomposition of synthesized $Fe_{1-x}Co_xC_2O_4{\cdot}2H_2O$ and $Fe_{1-x}Mn_xC_2O_4{\cdot}2H_2O$ was analyzed in an Ar atmosphere with TG/DTA. The synthesized powders were heat-treated for 3 hours in an Ar atmosphere at $450^{\circ}C$ to produce activated powders of $(Fe_{1-x}Co_x)_3O_{4-{\delta}}$ and $(Fe_{1-x}Mn_x)_3O_{4-{\delta}}$. The activated powders were reacted with a mixed gas (Ar : 85 %, $CO_2$ : 15 %) at $300^{\circ}C$ for 12 hours. The exhaust gas was analyzed for $CO_2$ with a $CO_2$ gas analyzer. The decomposition of $CO_2$ was estimated by measuring $CO_2$ content in the exhaust gas after the reaction with $CO_2$. For $(Fe_{1-x}Mn_x)_3O_{4-{\delta}}$, the amount of $Mn^{2+}$ oxidized to $Mn^{3+}$ increased as x increased. The ${\delta}$ value and $CO_2$ decomposition efficiency decreased as x increased. When the ${\delta}$ value was below 0.641, $CO_2$ was not decomposed. For $(Fe_{1-x}Co_x)_3O_{4-{\delta}}$, the ${\delta}$ value and $CO_2$ decomposition efficiency increased as x increased. At a ${\delta}$ value of 0.857, an active state was maintained even after 12 hours of reaction and the amount of decomposed $CO_2$ was $52.844cm^3$ per 1 g of $(Fe_{0.5}Co_{0.5})_3O_{4-{\delta}}$.

Effect of temperature on the rheological properties of dental interocclusal recording materials

  • Pae, Ahran;Lee, Ho-Rim;Kim, Hyeong-Seob
    • Korea-Australia Rheology Journal
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    • v.20 no.4
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    • pp.221-226
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    • 2008
  • The purpose of this study was to compare rheological properties of six dental interocclusal recording materials and to investigate the effect of temperature on the rheological properties during setting. Five polyvinylsiloxane materials and one polyether material were investigated in this study. The storage modulus (G') and the loss factor ($tan{\delta}$) were measured from 30s after mixing during setting, using the universal dynamic spectrometer. Viscoelastic properties were evaluated by means of G' and $tan{\delta}$ from 5 repeats at $21^{\circ}C$ and $33^{\circ}C$. Individual changes during setting were also evaluated. All data were statistically analyzed using one-way ANOVA and multiple comparison $Scheff{\acute{e}}$ test at the significance level of 0.05. The mean of G was checked at $t_{set}$ (the setting time provided from manufacturer) and $t_{300}$ (the end of experimental time) and the mean of $tan{\delta}$ was checked at to and $t_{set}$. Whereas the increase of the G' value showed generally exponential changes at $21^{\circ}C$, the change of the G' value at $33^{\circ}C$ displayed sigmoidal curves during setting. The change of loss factor $tan{\delta}$ during setting varied. Within the limitations of this study, dental interocclusal recording materials had different viscoelastic properties and most of the materials showed different fluidity at $21^{\circ}C$ and $33^{\circ}C$.

Ore Minerals, Fluid Inclusions and Stable Isotopes of the Yucheon Bismuth Deposits, Korea (류천(柳川) 창연광상(蒼鉛鑛床) 광석광물(鑛石鑛物), 유체포유물(流體包有物) 및 안정동위원소(安定同位元素))

  • Lee, Hyun Koo;Yoo, Bong-Cheal;Kim, Sang Jung
    • Economic and Environmental Geology
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    • v.29 no.2
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    • pp.139-150
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    • 1996
  • The Yucheon Bi deposits at Cheongha, Gyeongsangbugdo, is of a middle Paleogene (49 Ma) vein type, and is hosted in sandstone and shale of Banyawal formation in Cretaceous age. Based on mineral paragenesis, vein structure and mineral assemblages, two minera1ization stages were distinguished. The stage I consists of quartz with small amount of chlorite, pyrite, epidote, hal1oysite, vermiculite, serpentine and rutile associated with sericitization. The stage II is characterized by Bi minera1ization such as bismuthinite, Bi-Cu-Pb-S mineral, tetradymite, native gold, pyrite, pyrrhotite, arsenopyrite, wolframite, rutile, hematite, sphalerite, chalcopyrite, galena with alteration of sericite, chlorite, K-feldspar, albite and epidote. Fluid inclusion data indicate that fluid temperature and NaCl equivalent wt.% salinity range from 431 to $150^{\circ}C$ and from 19.2 to 0.18wt.% in the stage II. Evidence of boiling during the base-metal minera1ization indicates pressures 241 to 260 bars. Sulfur fugacity($-log\;f_{S2}$) deduced by mineral assemblages and compositions ranges from 5.1 to 5.7atm in early stage, from > 8.4 atm in middle stage and from 13.5 to 19.3 atm in late stage. It suggests that complex histories of progressive coo1ing, dilution and boiling were occurred by the mixing of the fluids. The ${\delta}^{34}S$, ${\delta}^{18}O$ and ${\delta}D$ data range from 2.5 to 3.9%, -0.5 to -4.1% and -29.7 to -47%, respectively. It indicated that hydrothermal fluids may be magmatic origin with boiling and mixing of meteoric water increasing paragenetic time.

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Effect of Color Developing by Alkali and Heating of Cotton Fabrics Dyed with Persimmon Extract (알칼리와 열처리에 의한 면직물의 감즙염색 발색효과)

  • Kim, Ok-Soo;Jang, Jeong-Dae
    • Fashion & Textile Research Journal
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    • v.13 no.6
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    • pp.972-982
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    • 2011
  • The purpose of this study is to improve the method of color developing with alkali solution as a promotor of color developing for feasible use. Cotton fabric was dyed with persimmon extract ranged with 0~3% alkali component with 5 types of strong to mild alkali solution. Heat treatment for color developing was applied to fabric dyed with persimmon extract and alkali mixing solution. Tests were carried out to analyze the change of surface color, ${\Delta},Ea^*b^*$, and water repellent of the dyed cotton fabric. The alkali mixing sample showed higher ${\Delta},Ea^*b^*$ value than control one without alkali mixing on the base of dyed fabric due to high color developing by alkali in the initial step of dyeing process. As alkali concentration increased, deeper dark color appeared on the fabric. The fabric color was changed to more dark in the application of sodium hydroxide, sodium carbonate, potassium carbonate in the initial step of dyeing process but color was not changed by increased heating time. However, the fabric showed a slight dark color with sodium acetate and more color change than that of the fabric dyed with persimmon extract without alkali. Therefore, sodium acetate seemed to a suitable promotor for color developing in persimmon extract dyeing. Property of water repellent was showed after color developing by heating with low concentration of alkali treatment.