• Title/Summary/Keyword: $^1$O$_2$ generation

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Effects of Light and Photosynthetic Electron Transport System on the Generation of Singlet Oxygen ($^1$O$_2$) in Ginseng Thylakoid Membrane (인삼 틸라코이드에서 Singlet Oxygen($^1$O$_2$) 생성에 미치는 전자전달계의 영향)

  • Yang, Deok-Cho;Chae, Quae;Lee, Sung-Jong;Kim, Yong-Hae;Kang, Young-Hee
    • Journal of Ginseng Research
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    • v.14 no.1
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    • pp.57-62
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    • 1990
  • In order to Investigate the mechanism of the leaf-burning disease of ginseng (Panax ginseng C.A. Meyer), studies on the generation of singlet oxygen (1O2) and the photooxidation of the pigments were carried out in comparison with the ones of soybean (G1ycine max L). The studies were mainly focalized on the effects of light intensity, light intensity, inhibitor and electron donor/acceptor of the Photosynthetic electron transport system. When we measured the amounts of 1O2 generated in the thylakoids of ginseng and soybean by the irradiation of light (300 w/m2) as a function its time. It was identified that a higher amount of 1O2 was formed in the ginseng thylakoid than the case of soybean. A generation ratio of lO2 between ginseng and soybean sltbstantially identical in the range of light intensities 50∼150w/m2 However much higher amount of 1O2 was generated in ginseng by irradiation of strong intensity of light (200 500w/m2). Wave length dependency on the generation of 1O2 and the pigment photooxidation was observed on ginseng thylakoids; red light (600-700 nm) gave a maximum effect in the contrast with blur green light (400-60 nm). When the ginseng thylalioid was treated with the electron donor (Mn2+) and acceptors (DCPIP, FeCy) of the photosynthetic electron transport system. a drastic inhibition of 1O2 generation was observed. However, treatment with its inhibitors (DCMU, KCW) activated 1O2 generation. An interesting fact that an electron donor or acceptor of the photosystem II(P680) Inhibited 1O2 generation, suggests an intimate relationship between 1O2 generation and photosystem II.

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The Research of Vibration Power Generation with Two Degree of Freedom Using Ocean Wave (파도를 이용한 2자유도 파력진동발전시스템에 대한 연구)

  • Han, Ki-Bong;Lee, Hyoung-Woo
    • Journal of Advanced Marine Engineering and Technology
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    • v.35 no.8
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    • pp.1028-1034
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    • 2011
  • This paper have been studied that ocean wave power vibration generation system with two D.O.F.(degree of freedom) consists of buoy and vibration generation system with two D.O.F. for using efficiency of ocean wave energy. It selected main frequencies ${\omega}_1$, ${\omega}_2$ in frequency with ocean wave and it fitted them to the natural frequencies of vibration system with two D.O.F. in the vibrational power generation system. Then each the relative velocity of between the winding coil and the permanent magnet is faster than the velocity of ocean wave up and down motion by resonance phenomenon. Also the ocean wave power generation with two D.O.F. obtained the more electric energy then the ocean wave power generation with one D.O.F. by coupling effect for two D.O.F. vibration system. Therefore ocean wave power vibration generation system with two degree of freedom that is proposed in this paper has merits which not only using more energy in the ocean wave but also obtaining more electronic energy.

Study on the Generation of Chemically Active Species using Air-plasma Discharging System (공기-플라즈마 방전 시스템에서 화학적 활성종의 생성에 대한 연구)

  • Kim, DongSeog;Park, YoungSeek
    • Journal of Korean Society on Water Environment
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    • v.28 no.3
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    • pp.401-408
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    • 2012
  • High-voltage dielectric discharges are an emerging technique in environmental pollutant degradation, which that are characterized by the production of hydroxyl radicals as the primary degradation species. The initiation and propagation of the electrical discharges depends on several physical, chemical, and electrical parameters such as 1st and 2nd voltage of power, gas supply, conductivity and pH. These parameters also influence the physical and chemical characteristics of the discharges, including the production of reactive species such as OH, $H_2O_2$ and $O_3$. The experimental results showed that the optimum 1st voltage and air flow rate for RNO (N-Dimethyl-4-nitrosoaniline, indicator of the generation of OH radical) degradation were 160 V (2nd voltage of is 15 kV) and 4 L/min, respectively. As the increased of the 2nd voltage (4 kV to 15 kV), RNO degradation, $H_2O_2$ and $O_3$ generation were increased. The conductivity of the solution was not influencing the RNO degradation and $H_2O_2$ and $O_3$ generation. The effects pH was not high on RNO degradation. However, the lower pH and the conductivity, the higher $H_2O_2$ and $O_3$ generation were observed.

A study on reactive chlorine species generation enhanced by heterojunction structures on surface of IrO2-based anodes for water treatment (IrO2 기반 수처리용 산화 전극의 표면 이종 접합 구성에 따른 활성 염소종 발생 증진 특성 연구)

  • Hong, Sukhwa;Cho, Kangwoo
    • Journal of Korean Society of Water and Wastewater
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    • v.32 no.4
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    • pp.349-355
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    • 2018
  • This study interrogated multi-layer heterojunction anodes were interrogated for potential applications to water treatment. The multi-layer anodes with outer layers of $SnO_2/Bi_2O_3$ and/or $TiO_2/Bi_2O_3$ onto $IrO_2/Ta_2O_5$ electrodes were prepared by thermal decomposition and characterized in terms of reactive chlorine species (RCS) generation in 50 mM NaCl solutions. The $IrO_2/Ta_2O_5$ layer on Ti substrate (Anode 1) primarily served as an electron shuttle. The current efficiency (CE) and energy efficiency (EE) for RCS generation were significantly enhanced by the further coating of $SnO_2/Bi_2O_3$ (Anode 2) and $TiO_2/Bi_2O_3$ (Anode 3) layers onto the Anode 1, despite moderate losses in electrical conductivity and active surface area. The CE of the Anode 3 was found to show the highest RCS generation rate, whereas the multi-junction architecture (Anode 4, sequential coating of $IrO_2/Ta_2O_5$, $SnO_2/Bi_2O_3$, and $TiO_2/Bi_2O_3$) showed marginal improvement. The microscopic observations indicated that the outer $TiO_2/Bi_2O_3$ could form a crack-free layer by an incorporation of anatase $TiO_2$ particles, potentially increasing the service life of the anode. The results of this study are expected to broaden the usage of dimensionally stable anodes in water treatment with an enhanced RCS generation and lifetime.

Decomposition of $H_2O$ with Ferrite Powders for Hydrogen Generation (페라이트를 이용한 $H_2O$ 분해를 통한 수소제조)

  • 신현창;정광덕;한성환;최승철
    • Journal of the Korean Ceramic Society
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    • v.37 no.1
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    • pp.90-95
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    • 2000
  • The ferrites, CuFe2O4 and SrFe12O129, were applied to decompose H2O for H2 generation. The ferrites prepared by the coprecipitation were reduced by CH4 gas to make the oxygen deficient ferrite. H2O was decomposed to form H2 by the oxygen deficient iron oxide, and the decomposition reactions were accelerated by the addition of divalent metals such as Cu and Sr in the ferrites. The spinel type CuFe2O4 containing a relatively large amount of divalent metals was more effective to H2 generation than magnetoplumbite type SrFe12O19 in H2O decomposition.

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Analysis of a Fire Case Caused by Heat Generation due to Cu2O Breeding (아산화동증식 발열에 의한 화재 사례의 분석)

  • Park, Jin-Young;Lee, Eui-Pyeong
    • Fire Science and Engineering
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    • v.34 no.2
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    • pp.54-63
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    • 2020
  • Although fires caused by heat generation due to Cu2O breeding in wire connections are well-known among fire investigators, there are few papers on the analysis and introduction of fire cases by heat generation due to Cu2O breeding. This study analyzed fire statistics caused by heat generation in electrical connections and the phenomena and features of heat generation due to Cu2O breeding. Then, a fire which occurred in the wire connection in a university lab by heat generation due to Cu2O breeding was analyzed in more detail. This fire case could reach a conclusion that heat generation due to Cu2O breeding caused a fire in the wire connection through the fire pattern investigation of fire origin, the visual investigation of wire connection, 3D CT, power-on-test, and stereoscopic microscopy, SEM and EDS analysis.

A Study for Oxidants Generation on Oxygen-plasma Discharging Process Discharging System (산소-플라즈마 공정에서 산화제의 생성에 대한 연구)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Science International
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    • v.22 no.12
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    • pp.1561-1569
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    • 2013
  • This study carried out a laboratory scale plasma reactor about the characteristics of chemically oxidative species (${\cdot}OH$, $H_2O_2$ and $O_3$) produced in dielectric barrier discharge plasma. It was studied the influence of various parameters such as gas type, $1^{st}$ voltage, oxygen flow rate, electric conductivity and pH of solution for the generation of the oxidant. $H_2O_2$ and $O_3$.) $H_2O_2$ and $O_3$ was measured by direct assay using absorption spectrophotometry. OH radical was measured indirectly by measuring the degradation of the RNO (N-Dimethyl-4-nitrosoaniline, indicator of the generation of OH radical). The experimental results showed that the effect of influent gases on RNO degradation was ranked in the following order: oxygen > air >> argon. The optimum $1^{st}$ voltage for RNO degradation were 90 V. As the increased of $1^{st}$ voltage, generated $H_2O_2$ and $O_3$ concentration were increased. The intensity of the UV light emitted from oxygen-plasma discharge was lower than that of the sun light. The generated hydrogen peroxide concentration and ozone concentration was not high. Therefore it is suggested that the main mechanism of oxidation of the oxygen-plasma process is OH radical. The conductivity of the solution did not affected the generation of oxidative species. The higher pH, the lower $H_2O_2$ and $O_3$ generation were observed. However, RNO degradation was not varied with the change of the solution pH.

Mechanism of DNA Cleavage Induced by Fe2+ Autoxidation

  • Kim, Jong-Moon;Kim, Seog-K.
    • Bulletin of the Korean Chemical Society
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    • v.32 no.3
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    • pp.964-972
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    • 2011
  • This work investigated the difference between $Fe^{2+}$ autoxidation-induced and Fenton-type cleavage of pBR322 plasmid DNA. $^{\cdot}OH$ generation reactions in the absence and presence of $H_2O_2$ under various conditions were also investigated. Although both the $Fe^{2+}$ autoxidation and Fenton-type reactions showed DNA cleavage and $^{\cdot}OH$ generation, there were significant differences in their efficiencies and reaction rates. The rate and efficiency of the cleavage reaction were higher in the absence of 1.0 mM of $H_2O_2$ than in its presence in 20 mM phosphate buffer. In contrast, the $^{\cdot}OH$ generation reaction was more prominent in the presence of $H_2O_2$ and showed a pH-independent, fast initial reaction rate, but the rate was decreased in the absence of $H_2O_2$ at across the entire tested pH range. Studies using radical scavengers on DNA cleavage and $^{\cdot}OH$ generation reactions in both the absence and presence of $H_2O_2$ confirmed that both reactions spontaneously involved the active oxygen species $^{\cdot}OH$, ${O_2}^{\cdot-}$, $^1O_2$ and $H_2O_2$, indicating that a similar process may participate in both reactions. Based on the above observations, a new mechanism for the $Fe^{2+}$ autoxidation-induced DNA cleavage reaction is proposed.

High Power Characteristics of $Pb(Y_{2/3}W_{1/3})O_3-Pb(Zr,Ti)O_3$Ceramics ($Pb(Y_{2/3}W_{1/3})O_3-Pb(Zr,Ti)O_3$계 세라믹스의 고출력 특성)

  • ;Kenji Uchino
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.5
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    • pp.394-399
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    • 1998
  • High power characteristics with vibration velocity were studied in $Pb(Y_{2/3}W_{1/3})O_3-Pb(Zr,Ti)O_3$(PYW-PZT) ceramics by using the constant current method. Young s modulus $Y_0^E$ and mechanical quality factor $Q_m$ are a function of the square of effective vibration velocity \upsilon_0$. The nonlinear proportional constants of the above functions indicate the degree of stability under the vibration level change. The stability of PYW-PZT ceramics estimated by these constants coincides with the results obtained through the heat generation. It was found that $Q_m$ was markedly decreased with increasing the vibration velocity, accompanying a lot of heat generation. The vibration hysteresis and dielectric loss according to the vibration velocity was reduced by doping $Fe_2O_3$to the ceramics. On the contrary, these losses was increased by doping $Nb_2O_5$.

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Study on the Generation of Chemically Active Species Using Gas-liquid Mixing Plasma Discharging System (기-액 혼합 플라즈마 방전 시스템에서 화학적 활성종의 생성)

  • Kim, DongSeog;Park, YoungSeek
    • Journal of Korean Society on Water Environment
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    • v.30 no.4
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    • pp.394-402
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    • 2014
  • High-voltage dielectric discharges are an emerging technique in environmental pollutant degradation, which are characterized by the production of hydroxyl radicals as the primary degradation species. The initiation and propagation of the electrical discharges depends on several physical, chemical, and electrical parameters such as 1st and 2nd voltage of power, gas supply, conductivity and pH. These parameters also influence the physical and chemical characteristics of the discharges, including the production of reactive species such as OH, $H_2O_2$ and $O_3$. The experimental results showed that the optimum 1st voltage and oxygen flow rate for RNO (N-Dimethyl-4-nitrosoaniline, indicator of the generation of OH radical) degradation were 160 V (2nd voltage of is 15 kV) and 4 L/min, respectively. As the 2nd voltage (4 kV to 15 kV) was increase, RNO degradation was increased and, generated $H_2O_2$ and $O_3$ concentration were increased. The conductivity of the solution was not influencing the RNO degradation, $H_2O_2$ and $O_3$ generation. The pH effect on RNO degradation was not high. However, the lower pH and the conductivity, the higher $H_2O_2$ and $O_3$ generation were observed.