• 제목/요약/키워드: $^{63}Ni$

검색결과 238건 처리시간 0.022초

TiN피막 코팅된 치과주조용 합금의 부식거동 (Corrosion Behaviors of TiN Coated Dental Casting Alloys)

  • 조호형;박근형;김원기;최한철
    • 대한금속재료학회지
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    • 제47권2호
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    • pp.129-137
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    • 2009
  • Corrosion behaviors of TiN coated dental casting alloys have been researched by using various electrochemical methods. Three casting alloys (Alloy 1: 63Co-27Cr-5.5Mo, Alloy 2: 63Ni-16Cr-5Mo, Alloy 3: 63Co-30Cr-5Mo) were prepared for fabricating partial denture frameworks with various casting methods; centrifugal casting(CF), high frequency induction casting(HFI) and vacuum pressure casting(VP). The specimens were coated with TiN film by RF-magnetron sputtering method. The corrosion behaviors were investigated using potentiostat (EG&G Co, 263A. USA) in 0.9% NaCl solution at $36.5{\pm}1^{\circ}C$. The corrosion morphologies were analyzed using FE-SEM and EDX. Alloy 1 and Alloy 2 showed the ${\alpha}-Co$ and ${\varepsilon}-Co$ phase on the matrix, and it was disappeared in case of TiN coated Alloy 1 and 2. In the Alloy 3, $Ni_2Cr$ second phases were appeared at matrix. Corrosion potentials of TiN coated alloy were higher than that of non-coated alloy, but current density at passive region of TiN coated alloy was lower than that of non-coated alloy. Pitting corrosion resistances were increased in the order of centrifugal casting, high frequency induction casting and vacuum pressure casting method from cyclic potentiodynamic polarization test.

고리1호기 해체시의 원자로 구조물에서의 방사회 생성물 재고량 예비평가 (Preliminary Estimation of Activation Products Inventory in Reactor Components for Kori unit 1 decommissioning)

  • 이경진;김학수;신상운;송명재;이윤근
    • Journal of Radiation Protection and Research
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    • 제28권2호
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    • pp.109-116
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    • 2003
  • 본 연구에서는 최근 국내 원자력발전소의 해체시 방사화 생성물 재고량의 평가 필요성이 대두됨에 따라 원자로 수명종로가 가까워지고 있는 고리1호기를 대상으로 원자로 각 구조물의 방사라 생성물 재고량을 ANISN과 ORIGEN2 코드를 이용하여 예비평가를 수행하였다. 코드 입력자료로는 노심에서부터 차폐콘크리트까지 반경방향으로 8개 영역으로 나누어 ANISN 코드를 사용하여 중성자속을 계산하였다. 또한 압력용기의 중성자속 분포를 가지고 주요 핵종의 단일 그룹 반응단면 적을 보정하였다. 본 연구의 결과 압력용기의 경우 원자로 정지시점에서 약 10년까지는 $^{55}Fe,\;^{59}Ni,\;^{63}Ni,\;^{60}Co$ 핵종이 총 방사능의 약 95%정도를 차지하였으며, 약 50년 이상 냉각 후의 총 방사능은 원자로 정지시점과 비교하여 약 0.2 % 이하로 감소하는 것으로 평가되었다. 또한 압력용기의 무게가 210 ton임을 고려해 볼 때, 압력용기의 총 방사화생성물 재고량은 $5.25{\times}10^6GBq$로 계산되었다. 또한 차폐콘크리트의 경우 약 10년 이상 냉각 후의 총 방사능은 원자로 정지시점과 비교하여 1 %이하로 급격히 감소하는 것으로 평가되었다.

Flip Chip Interconnection-UBM and Material Issues

  • Jang, Se-Young
    • 한국마이크로전자및패키징학회:학술대회논문집
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    • 한국마이크로전자및패키징학회 2003년도 International Symposium
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    • pp.193-215
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    • 2003
  • Fracture Mechanism of Flip Chip Electromigration Failure - Mostly caused by Cathode Depletion at the UBM/Solder Interface Guideline to Increase Electromigration Resistance Material Selection: Sn/Ag(/Cu) > Pb/63Sn Cu UBM > Ni UBM (but, Solder Material combination) UBM Design: thick UBM is preferable (but, Stress Issue) Pad open/UBM size: as large as possible (but, pad size & pitch limit)

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만경강 퇴적물의 중금속 함량 및 분포 (Heavy Metals in Fine-Grained Bed Sediments of the Mangyeong River, Korea)

  • 조영길
    • 한국환경과학회지
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    • 제16권5호
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    • pp.657-664
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    • 2007
  • The content and distribution of some heavy metals (Fe, Mn, Cr, Co, Cu, Ni, Zn and Pb) were investigated in the <$63{\mu}m$ bed sediments of the Mangyeong river to recognize the extent of contamination. Results showed that a wide range of concentrations was apparent for every metal. These variations were particularly significant at the confluence of tributaries. High levels of metals occur mainly in the confluence of tributaries. Geoaccumulation indexes have been calculated to assess whether the concentration observed represent background or contaminated levels. It is proved that the Mangyeong River is moderately to strongly polluted for Mn, Cr, Cu, Zn and Pb. The spatial extent of pollution was examined, and it was found that the most polluted area is located in the confluence of Iksan and Jeonju tributaries.

Crystallographic and Magnetic Properties of Nano-sized Nickel Substituted Cobalt Ferrites Synthesized by the Sol-gel Method

  • Choi, Won-Ok;Lee, Jae-Gwang;Kang, Byung-Sub;Chae, Kwang Pyo
    • Journal of Magnetics
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    • 제19권1호
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    • pp.59-63
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    • 2014
  • Nano-sized nickel substituted cobalt ferrite powders, $Ni_xCo_{1-x}Fe_2O_4$ ($0.0{\leq}x{\leq}1.0$), were fabricated by the sol-gel method, and their crystallographic and magnetic properties were studied. All the ferrite powders showed a single spinel structure, and behaved ferrimagnetically. When the nickel substitution was increased, the lattice constants and the sizes of particles of the ferrite powders decreased. The M$\ddot{o}$ssbauer absorption spectra of $Ni_xCo_{1-x}Fe_2O_4$ ferrite powders could be fitted with two six-line subspectra, which were assigned to a tetrahedral A-site and octahedral B-sites of a typical spinel crystal structure. The increase in values of the magnetic hyperfine fields indicated that the superexchange interaction was stronger, with the increased nickel concentration in $Ni_xCo_{1-x}Fe_2O_4$. This could be explained using the cation distribution, which can be written as, $(Co_{0.28-0.28x}Fe_{0.72+0.28x})[Ni_xCo_{0.72-0.72x}Fe_{1.28-0.28x}]O_4$. The two values of the saturation magnetization and the coercivity decreased, as the rate of nickel substitution was increased. These decreases could be explained using the cation distribution, the magnetic moment, and the magneto crystalline anisotropy constant of the substituted ions.

대합되는 재료에 따른 합성수지 인공치의 마모저항성에 관한 비교 연구 (Comparison Study of Wear Resistance Among Several Denture Teeth Opposing Various Restorative Materials)

  • 박영배
    • 대한치과기공학회지
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    • 제31권1호
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    • pp.63-74
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    • 2009
  • Partial or complete prosthesis is needed when teeth are lost due to various kinds of reason. Artificial teeth recover occlusion instead of natural teeth. Artificial teeth are required of esthetics, fragile resistance and abrasive resistance. Artificial tooth is made of acrylic resin or porcelain. Nowadays, acrylic resin artificial teeth are mainly used. Acrylic resin teeth are occluded with natural teeth, gold alloy, Ni-Cr alloy or porcelain etc. Acrylic resin teeth have similar translucency, gloss of natural teeth. And it has good chemical bond with denture base material, but it has low wear resistance. The aim of this study is to compare wear resistance among several denture teeth(Endura, SR-orthosit-PE, Planustar) and between artificial resin denture teeth and opposing 3 restorative materials(gold, Ni-Cr alloy, porcelain). Wear tests were conducted with a rotating wear testing apparatus(pin-on-disk type wear tester) under conditions of rpm 180, 75 minutes and constant loading of 50N. The upper part was the cusp of maxillary first molar and the lower part was a disk type restorative materials. To make similar oral environment, water was supplied continually. The acrylic resin teeth wear was determined by weighing the cusp each 5 minutes during 75 minutes test. Vicker's hardness tester was used to evaluate the surface hardness of test specimens. The SEM was used to evaluate the wear surfaces. The results were as follows: 1. Wear rates of acrylic resin teeth opposing to the restorative materials were high in order of Porcelain, Gold, Ni-Cr alloy (p<.05). 2. Wear resistance rate opposing to the Porcelain disk, was shown in order of Endura, SR-orthosit-PE, Planustar. The wear rate of opposing to porcelain disk was above two times more than that of other groups (p<.05). 3. Wear resistance rates opposing to the Gold, Ni-Cr alloy disk, was shown in order of Endura, SR-orthosit-PE, Planustar (p<.05). 4. A degree of the surface hardness is directly proportional to the degree of wear resistance. There are statistically significant differences between each groups (p<.05).

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압전세라믹 $(Pb_{1-x}C_{ax})((Co_{\frac{1}{2}}W_{\frac{1}{2}})_yTi_{1-y})O_3+(MnO_2, NiO)$ (Fabrication and Properties of $(Pb_{1-x}C_{ax})((Co_{\frac{1}{2}}W_{\frac{1}{2}})_yTi_{1-y})O_3+(MnO_2, NiO)$ piezoelectric ceramic)

  • 문동진;도시홍;장지원
    • 한국음향학회지
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    • 제6권4호
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    • pp.55-63
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    • 1987
  • $PbTiO_3$는 perovskite구조를 가진 강유전체로써 Curie온도가 높고 유전율이 작아 고온. 고주파재료로 주목되어왔으나 curie온도 이하에서 결정이방성(C/a)이 크기 때문에 소결 후 결정립(grain)이 입계(grain boundary)에서 분리되어 치밀하고 기계적으로 강한 세라믹을 얻을 수 없었고, 항전력이 커 분극이 어려위 실용화 되지 않았다. 본 연구에서는 $PbTiO_3$에 Pb일부를 Ca로 치환하고 Mn, Ni, Co및 W의 산화물을 첨가하여 치수가 크고 기계적으로 강한 세라믹을 제조하였고, 그 분극 조건도 PZT의 분극 조건과 같은 정도로 개선하였다. 그리고 결합계수이방성(Kt/Kp)이 $5\sim6$으로 크고, 기계적 품질계수 Qm이 $310\sim480$ 정도로 낮으며, 유전상수가 200대의 값으로 PZT보다 1/5정도 작은 고온, 고주파. 광대역 초음파 발진자 재료로 적합한 압전세라믹을 제조 연구하였다.

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SiC 나노입자를 이용하여 형성한 Ni-SiC 복합도금막의 미세구조 및 특성 (Microstructure and Properties of Ni-SiC Composite Coating Layers Formed using Nano-sized SiC Particles)

  • 이홍기;손성호;이호영;전준미
    • 한국표면공학회지
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    • 제40권2호
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    • pp.63-69
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    • 2007
  • Ni-SiC composite coating layers were formed using two kinds of SiC nano-particles by DC electrodeposition in a nickel sulfamate bath containing SiC particles. The effect of stirring rate and SiC particle type on the microstructure and properties of Ni-SiC composite coating layers were investigated. Results revealed that the trend of deposition rate is closely related to the codeposition of SiC and the deposition rate. or nickel, and the codeposition behavior of SiC can be explained by using hydrodynamic effect due to stirring. The average roughness and friction coefficient are closely related to the codeposition of SiC and SiC particle size. It was found that the Victors microhardness of the composite coating layers increased with increasing codeposition of SiC. The composite coating layers containing smaller SiC particle showed higher hardness. This can be explained by using the strengthening mechanism resulting from dispersion hardening. Anti-wear property of the composite coating layers formed using 130 nm-sized SiC nano-particles has been improved by 2,300% compared with pure electroplated-nickel layer.