• Title/Summary/Keyword: $^{55}Mn$

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Electrochemical Study of Electrode Material of Ni-MH Battery for HEV and PEMFC Fuel Cell (HEV 및 PEMFC 연료전지용 니켈수소 전지의 전극재료에 대한 전기화학적 평가)

  • Kim, Ho-Sung
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.20 no.2
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    • pp.24-28
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    • 2006
  • Electrochemical hydrogenation/dehydrogenation properties were studied for a single particle of a Mm-based(Mm : misch metal) hydrogen storage alloy($MmNi_{3.55}Co_{0.75}Mn_{0.4}Al_{0.3}$) for the anode of Ni-MH batteries. A carbon fiber microelectrode was manipulated to make electrical contact with an alloy particle, and the cyclic voltammetry and the galvanostatic charge/discharge experiments were performed. A single particle of the alloy showed the discharge capacity of 280[mAh/g], the value being 90[%] of the theoretical capacity. Data were compared with that of the composite film consisting of the alloy particles and a polymer binder, which is more practical form for Ni-MH batteries. Additionally, pulverization of the alloy particles are directly observed. Compared with the conventional composite film electrodes, the single particle measurements using the microelectrode gave more detailed, true information about the hydrogen storage alloy.

The Structural and Electrochemical Properties of Thermally Aged Li[Co0.1Ni0.15Li0.2Mn0.55]O2 Cathodes

  • Park, Yong-Joon;Lee, Ju-Wook;Lee, Young-Gi;Kim, Kwang-Man;Kang, Man-Gu;Lee, Young-Il
    • Bulletin of the Korean Chemical Society
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    • v.28 no.12
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    • pp.2226-2230
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    • 2007
  • As a cathode material of lithium rechargeable batteries, charged Li[Co0.1Ni0.15Li0.2Mn0.55]O2 electrodes, which were aged thermally at 25 oC and 90 oC respectively, were characterized by means of charge/discharger, impedance spectroscopy, and X-ray diffraction. The discharge capacity diminution of the electrodes aged at 25 oC and 90 oC for 1 week was 4% and 23%, respectively. The cell aged at 25 oC was recovered on cycling. However, the capacity loss after ageing at 90 oC was not recovered in a subsequent cycling test, which demonstrates that the reaction occurring during ageing at 90 oC is irreversible. A significant impedance increase of aged electrode at 90 oC is associated with irreversible capacity loss. The structural changes including phase transformation were not detected by XRD analysis, because it could be due to out of detection limit. After ageing, impedance was slightly decreased during subsequent cycling test. It could be explained the cyclic performance of aged sample is stable. The thermal stability was not deteriorated by ageing even at the high temperature of 90 oC.

Changes of Nutrient Composition and Antioxidative Activities of Fermented Tea during Fermentation (후발효차의 발효기간별 영양성분 및 항산화 활성의 변화)

  • Lee, Kyung-Haeng;Kim, Yong-Shik;Lee, Jong-Yeol
    • The Korean Journal of Food And Nutrition
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    • v.26 no.3
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    • pp.398-403
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    • 2013
  • To manufacture the fermented tea with hygienic quality, green tea was fermented using Bacillus subtilis, Saccharomyces cerevisiae and Lactobacillus bulgaricus and mineral composition, total amino acid content and antioxidative activity changes were evaluated during the fermentation period. Minerals detected in the fermented tea, the Ca, Fe, Zn, Mg and Mn minerals were detected. Ca and Mg are relatively large compared to other mineral content. Total amino acid content of the control was 3.57%, but total amino acid of fermented teas were higher (3.68~3.85%) during fermentation 20 days. Metal chelating activity of control was 55.11%, Metal chelating activity of the fermented tea using B. subtilis was the highest. In reducing power, O.D. value of the control was 2.27, three kinds of fermented tea were lower than that of control. The fermented teas increased lipid peroxidation inhibition compared to the blank test.

Culture Conditions of Geobacillus kaustophilus DSM 7263 for Production of Thermophilic Extracellular Lipase (내열성 extracellular lipase 생산을 위한 Geobacillus kaustophilus DSM 7263의 배양조건)

  • Jeon, Sung-Jong;Kang, Hyun-Woo
    • Journal of Life Science
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    • v.20 no.6
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    • pp.902-906
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    • 2010
  • A producer of thermophilic extracellular lipase, Geobacillus kaustophilus DSM 7263, was selected from various microorganisms of the Geobacillus genus. We investigated optimum conditions for mass production of G. kaustophilus lipase. Among the different natural oil media, olive oil was optimal for enzyme production. The maximum amount of enzyme production was obtained when G. kaustophilus was grown in a medium containing 0.5% olive oil as a carbon source. The pH and temperature for optimal growth were pH 8.0 and $55^{\circ}C$, respectively, while the optimum pH and temperature for lipase production were pH 6.0 and $50^{\circ}C$, respectively. In the presence of $Mg^{2+}$ and $Mn^{2+}$, lipase production was dramatically enhanced by 247% and 157%, respectively, whereas enzyme production was inhibited by $Zn^{2+}$, $Cu^{2+}$, and $Cd^{2+}$. The addition of 0.1% (v/v) triton X-100 increased lipase production and cell growth when compared to the negative control.

The Fabrication and Electrical Properties of PMS-PZT Ceramics using a Tape Casting Method (Tape Casting법에 의한 PMS-PZT계 세라믹스 제조 및 전기적 특성)

  • Jung, Hyun-Jae;Na, Eun-Sang;Choi, Sung-Churl
    • Journal of the Korean Ceramic Society
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    • v.38 no.9
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    • pp.860-865
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    • 2001
  • After manufacturing 2mol% CdO substitute $0.05Pb(Mn_{1/3}Sb_{2/3})O_3-0.95Pb(Zr_{0.52}Ti_{0.48})O_3$ piezoelectric ceramics powder as starting material, to manufacture green sheets using Doctor Blade method. The optimum composition of slurry was studied. Moreover, the sintering properties and the dielectric and piezoelectric properties with variation a thickness of the manufactured sheets were investigated. The optimum of slurry was investigated by the rheology with addition of additives, the sintering condition was decided by TGA. And the properties of sheet were investigated through SEM. XRD. The optimum of slurry was the stablest at dispersant 3.0 wt% to solid loading 30vol%. After, at addition of binder/plasticizer(0.75/0.25) 3.0wt%, viscosity was 7.55Pa${\cdot}$s. The dielectric and piezoelectric properties of the sheet were increased a little with the increasing of sintering temperature but were not variable with variation of sheet thickness.

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An Applicable Method of an Electromagnetic Wave Absorber for SAR Reduction in the Human Head Exposed to Electromagnetic Fields Radiated by a Cellular Phone (휴대폰 전자파에 노출된 두부내 SAR 저감을 위한 전자파 흡수체 적용 방법 연구)

  • 이윤경;백락준;홍진옥;육재림;윤현보
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.14 no.8
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    • pp.884-890
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    • 2003
  • In order to reduce the specific absorption rate(SAR) in a human head exposed to electromagnetic fields radiated by a cellular phone, we have analyzed an electromagnetic wave absorber attached to the handset. A manufactured electromagnetic wave absorber was composed of Mn - Zn, which had complex relative permittivity of 7.30-j0.05 and permeability of 2.20-i1.55. The SAR value from the electromagnetic wave absorber attachment was calculated by using the nonuniform finite difference time domain(FDTD) algorithm and measured by phantom model at 835 MHz. The SAR reduction due to the electromagnetic wave absorber are about 18 % at 835 MHz. The V.S.W.R and radiation pattern of antenna are good agreement with the normal antenna. The gain reduction due to the electromagnetic wave absorber are only 0.3 dB at 835 MHz. But the sensitivity of cellular phone generally improves about 1 dB.

Characteristics of High Frequency Induction-Hardened Bearing Steel Produced by VIM (VIM에 의해 제조된 고주파 유도경화 베어링강의 특성에 관한 연구)

  • Choe, Byeong-Yeong;Jang, Jeong-Seok
    • Korean Journal of Materials Research
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    • v.8 no.12
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    • pp.1176-1181
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    • 1998
  • Characteristics of high frequency induction- hardened bearing steel have been investigated using 0.55wt.% C-1.68wt.% Mn specimens produced by vacuum induction melting (VIM). The K4 value in DIN 57602 of the specimens was assessed to be 6.41, high level of cleanliness. The specimens were high frequency induction-hardened to form heterogeneous submicron- lath martensite in the surface hardened layer with about 2.5mm in effective depth. Rolling contact fatigue tests were conducted in elasto-hydrodynamic lubricating conditions under a maximum Hertzian contact stress of$ 492kgmm^{-2}$ . It was found that microhardness in the subsurface, up to about $500\mu\textrm{m}$ in depth, below the raceway of rolling contact fatigued specimens was increased in comparison with that of induction-hardened layers. The depth of maximum microhardness- increased region was about $100\mu\textrm{m}$ from surface, showing white etching area. Crack initiation and propagation in the white etching area below the raceway of rolling contact fatigued specimens were observed.

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Electrochemical Study of a Single Particle of Active Material for Secondary Battery using the Microelectrode (마이크로 전극에 의한 2차 전지용 활물질 단일 입자의 전기화학적 평가)

  • Kim Ho-Sung;Lee Choong-Gon
    • Journal of the Korean Electrochemical Society
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    • v.9 no.2
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    • pp.95-99
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    • 2006
  • Electrochemical properties were studied for a single particle of active material of hydrogen storage alloy $(MmNi_{3.55}Co_{0.75}Mn_{0.4}Al_{0.3})$ and nickel hydroxides $(NiOH)_2$ for the secondary Nickel Metal Hydride (Ni-MH) batteries using the microelectrode, which was manipulated to make electrical contact with an active material particle for cyclic voltammograms (CV) and potential-step experiments. As a result of CV test, it was found that three kinds of hydrogen oxidation peaks at -0.9, -0.75 and -0.65 V and hydrogen evolution peak at -0.98 V for hydrogen storage alloy were separately observed and two kinds of peaks of proton oxidation/reduction at 0.45 and 0.32 V and oxygen evolution reaction (OER) at 0.6 V for nickel hydroxides were also more clearly observed. Furthermore hydrogen diffusion coefficient within a single particle was also found to vary the order between $10^{-9}\;and\;10^{-10}cm^2/s$ over the course of hydrogenation and dehydrogenation process for potential-step experiments.

Dielectric and Piezoelectric Properties of 0.125PMN-0.435PT-0.44PZ Ceramics for Ultrasonic footer Applications (초음파 전동기용 0.125PMN-0.435PT-0.44PZ 세라믹스의 유전 및 압전특성)

  • Kim, Jin-Soo
    • Journal of Sensor Science and Technology
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    • v.6 no.5
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    • pp.392-399
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    • 1997
  • In this study, the effect of the sintering temperature on the dielectric and piezoelectric properties of 0.5 wt% $MnO_{2}$-doped $0.125Pb(Mg_{1/2}Nb_{2/3})O_{3}-0.435PbTiO_{3}-0.44PbZrO_{3}$ ceramics were investigated aiming at ultrasonic motor applications. From experimental result, it was found that the optimal sintering temperature condition was at $1270^{\circ}C$. The sample sintered at $1270^{\circ}C$ had density of $7.72\;g/cm^{3}$, dielectric constant of 570, dielectric loss of 0.82%, remanent polarization of $19.18{\mu}C/cm^{2}$, coercive field of 9.63 kV/cm, electromechanical coupling factor of radial mode of 55.1%, mechanical quality factor of 886. Temperature and frequency dependence of dielectric constant and dielectric loss of the sintered sample at $1270^{\circ}C$ was also investigated.

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Evaluate the Activation of Linear Accelerator Components and Shielding Wall through Simulation (모의실험을 통한 선형가속기 부품과 차폐벽의 방사화 평가)

  • Lee, Dong-Yeon;Park, Eun-Tae;Kim, Jung-Hoon
    • The Journal of the Korea Contents Association
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    • v.17 no.9
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    • pp.69-76
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    • 2017
  • This study evaluated the activation of the shielding wall and the components around the accelerator by using the medical linear accelerator. We performed simulations for energy values of 20 MV with the operating time ranging from day 1 to 30 years, and linear accelerator head and shielding wall concrete were also evaluated. The results showed that neutrons in large quantities were analyzed using high energy around thetarget point where photons were formed. Based on the activation analysis with these results, radioactivity increased with an increase in operation time and activated nuclides usually start saturating in10 years. Furthermore, the general types of nuclides formed owingto the activation were Co-60, W-181, 185, 187, Na-24, Ca-45, Mn-54, 56, and Fe-55, 59.