• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2000년도 추계학술대회 논문집
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• pp.145-148
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• 2000

In contrast to the $\pi$ -conjugated polymers which typically absorb light only in the visible spectral region, the $\sigma$-conjugated polymers can be used as efficient material absorbing light in the UV region. In this work, the electronic and optical properties of I$_2$-doped $\sigma$ -conjugated poly (methyl-phenylsilylene) (PMPSi) polymer were investigated. DC conductivity up to 1.2$\times$10$^{-4}$ S/cm was obtained by I$_2$-doping. In UV/Vis absorbance spectrum, a new peak was observed near 370 nm, which was explained by polaron model. The photoluminescence (PL) intensity decreased with increasing degree of I$_2$-doping, and the Infrared (IR) spectrum analysis revealed that the dopants are not directly coupled to the polymer, but effect motions of the methyl and phenyl groups.

• 대한기계학회논문집B
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• 제23권3호
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• pp.364-373
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• 1999

A combination of conjugate gradient and Levenberg-Marquardt method is used to estimate the spatially varying scattering coefficient, ${\sigma}(r)$, in the solid and hollow spheres by utilizing the measured transmitted beams from the solution of an inverse analysis. The direct radiation problem associated with the inverse problem is solved by using the $S_{12}-approximation$ of the discrete ordinates method. The accuracy of the computations increased when the results from the conjugate gradient method are used as an initial guess for the Levenberg-Marquardt method of minimization. Optical thickness up to ${\tau}_0=3$ is used for the computations. Three different values of standard deviation are considered to examine the accuracy of the solution from the inverse analysis.

• 대한화학회지
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• 제7권1호
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• pp.69-73
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• 1963

The basicities of 16 substituted azoxybenzenes have been measured by U.V. spectrophotometric method. The effects of substituents on the basicities are discussed in terms of Hammett's equation. The reaction constants, ${\rho}^X_Y$ and ${\rho}^Y_X$ , in a modified equation, log $K_{XY}/K_{\infty}={\sigma}_X{\rho}^Y_X+{\sigma}_Y{\rho}^X_Y$, are $2.46{\pm}0.12$ and $2.25{\pm}0.26$ respectively. The validity of the equation is analysed by a statistical method, and the structure of the conjugate acid of the substituted azoxybenzenes is proposed.

• Journal of the Korean Statistical Society
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• 제29권1호
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• pp.95-108
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• 2000

Consider the oblique factor model X=Af＋$\varepsilon$, with defining relation $\Sigma$=Λ$\Phi$Λ'＋Ψ. This paper is concerned with suggesting an optimal Bayes criterion for determining the number of factors in the model, i.e. dimension of the vector f. The use of marginal likelihood as a method for calculating posterior probability of each model with given dimension is developed under a generalized conjugate prior. Then based on an appropriate loss function, a Bayes rule is developed by use of the posterior probabilities. It is shown that the approach is straightforward to specify distributionally and to imploement computationally, with output readily adopted for constructing required cirterion.

• 대한화학회지
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• 제28권6호
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• pp.418-424
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• 1984

Cinnamonitrile의 산-가수분해 반응속도상수를 25$^{\circ}$C, HClO$_4$ 1 ~ 5M의 센산성 용액속에서 UV분광법으로 측정하고 Bunnett관계식에 적용하여 ${\omega}$ = 9.8, ${\omega}^*$ = 0.42 및 ${\phi}$=1.6등의 hydration parameter를 구하였다. 이는 질소원자에 양성자화가 이루어진 짝산에 대하여 속도결정단계에서 친핵체로 물분자가 첨가된 다음에 양성자 전달체로 작용한다는 것을 시사한다. Cinnamonitrile 분자의 궤도함수를 CNDO/2방법으로 계산한 바, 형태이성체의 안정도는 (E)-planar＞(Z)-planar이였으며 음하전의 크기는 $C_8({\beta}){\ll}N$이였고 전이상태에서 물분자는 짝산의 양하전이 큰 $C_7({\alpha}$)원자에 대하여 ${\sigma}$접근함을 알았다. 이상의 결과로 부터, 센산성속에서 cinnamonitrile의 가수분해반응은 특정 산-촉매작용을 수반하는 A-2형의 산-가수분해 반응메카니즘에 의하여 진행됨을 알았다.