• Title/Summary/Keyword: $[Cl^-]/[OH^-]$ ratio

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Sedimentary type Non-Metallic Mineral Potential Analysis using GIS and Weight of Evidence Model in the Gangreung Area (지리정보시스템(GIS) 및 Weight of Evidence 기법을 이용한 강릉지역의 퇴적기원의 비금속 광상부존가능성 분석)

  • Lee Sa-Ro;Oh Hyun-Joo;Min Kyung-Duck
    • Spatial Information Research
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    • v.14 no.1 s.36
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    • pp.129-150
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    • 2006
  • Mineral potential mapping is an important procedure in mineral resource assessment. The purpose of this study is to analyze mineral potential using weight of evidence model and a Geographic Information System (GIS) environment to identify areas that have not been subjected to the same degree of exploration. For this, a variety of spatial geological data were compiled, evaluated and integrated to produce a map of potential mineral in the Gangreung area, Korea. for this, a spatial database considering mineral deposit, topographic, geologic, geophysical and geochemical data was constructed for the study area using a GIS. The used mineral deposits were non-metallic(Kaolin, Porcelainstone, Silicastone, Mica, Nephrite, Limestone and Pyrophyllite) deposits of sedimentary type. The factors relating to mineral deposits were the geological data such as lithology and fault structure, geochemical data, including the abundance of Al, As, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Mo, Na, Ni, Pb, Si, Sr, V, Zn, $Cl^-,\;F^-,\;{PO_4}^{3-},\;{NO_2}^-,\;{NO_3}^-,\;SO_{42-}$, Eh, PH and conductivity and geophysical data, including the Bouguer and magnetic anomalies. These factors were used with weight of evidence model to analyze mineral potential. Probability models using the weight of evidence were applied to extract the relationship between mineral deposits and related factors, and the ratio were calculated. Then the potential indices were calculated by summation of the likelihood ratio and mineral potential maps were constructed from Geographic Information System (GIS). The mineral potential maps were then verified by comparison with the known mineral deposit areas. The result showed the 85.66% in prediction accuracy.

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Effects of Nb Addition on Corrosion Resistance and Cytotoxicity Behavior of Ti Alloys (Nb이 첨가된 Ti합금의 내식성 및 생체안정성)

  • Lee, Doh-Jae;Lee, Kwang-Min;Lee, Kyung-Ku;Ryu, Chang-Nam;Oh, Tae-Wook;Kim, Soo-Hag;Yoon, Tack-Lim
    • Korean Journal of Materials Research
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    • v.13 no.11
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    • pp.761-768
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    • 2003
  • The corrosion resistance and cytotoxicity behavior of Ti alloys were studied as a function of Nb contents(3wt.%Nb, 20wt.%Nb, 40wt.%Nb). Ti-Nb alloys were melted by vacuum arc furnace and then rolled to 50% reduction ratio after homogenized at 105$0^{\circ}C$ for 24hrs. The corrosion resistance of Ti-Nb alloys were investigated by potentiodynamic polarization test in the 0.9% NaCl and 5% HCI solution. Biocompatibility of Ti-Nb alloys was evaluated by cytotoxicity test. The results can be summarized as follows 1) The microstructure change from equiaxial to acicular and the increased $\beta$ phase in Ti-Nb alloys were obtained as the Nb content increased. 2) For the corrosion test in the solution of 0.9% NaCl and 5% HCI, the corrosion behavior of Ti-Nb alloys was similar to ASTM grade 2 CP Ti. 3) For the cytotoxicity test, Ti-Nb alloys showed excellent biocompatibility compared to ASTM grade 2 CP Ti, 316L STS and Co-Cr alloys.

Regeneration of PCB Etchants and Copper Recovery in a Batch-type Electrolytic Cell (회분식 전해조에서 PCB 식각폐수의 재생 및 구리의 회수)

  • Nam, Sang Cheol;Nam, Chong Woo;Tak, Yongsug;Oh, Seung Mo
    • Applied Chemistry for Engineering
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    • v.8 no.2
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    • pp.161-171
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    • 1997
  • Anodic regeneration of PCB enchant and cathodic deposition of copper using electrochemical method has been studied. Cu(I)/Cu(II) concentration ratio as a function of Cu(I) oxidation at the anode was measured from the potential difference between platinum and Ag/AgCl/4M KCl electrodes. Chlorine gas evolution was minimized by maintaining Cu(I) concentration above a specific concentration and using non-porous graphite electrode. Dendritic copper deposition was observed at the cathode and the optimum conditions for Cu deposition was identified as the current density of $360mA/cm^2$, and copper concentration of 12 g/l. Titanium was the most effective cathode material which showed a higher current efficiency and copper recovery. The current efficiency decreased with increasing temperature, but the highest power efficiency was achieved at $50^{\circ}C$.

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The Leaching of Gold-silver from Refractory Gold Concentrate by Chlorine-hypochlorite Solution (염소-차아염소산 용액에 의한 저항성 금 정광으로부터 Gold-silver 용출)

  • Cho, Kang-Hee;Kim, Bong-Ju;Oh, Su-Ji;Choi, Seoung-Hwan;Choi, Nag-Choul;Park, Cheon-Young
    • Journal of the Mineralogical Society of Korea
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    • v.25 no.3
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    • pp.123-130
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    • 2012
  • Leaching experiments of gold and silver from roasted concentrate were carried out using a chlorine-hypochlorite solution. The leaching rate of gold was 75% at 1.5:1 ratio of chlorine and hypochlorite and increased to 81% with adding 1 M NaCl. However, at 1% pulp density and at $65^{\circ}C$, the leaching rates of Au were close to 100%. XRD analysis identified quartz in the solid residues after digestion of roasted concentrate with aqua regia or chlorine-hypochloride leaching solution. This suggests that the gold may not be leached out of the quartz in aqua regia or chlorine-hypochlorite solution. In order to leach the gold from the quartz, the concentrate will have to be pre-treated through ultra-fine grinding or treated with stronger oxidative agents.

Studies on Manufacturing Possibility of Paper Sludge-Cement Boards (II) - Physical and Mechanical Properties and SEM Observation - (제지(製紙) 슬러지-시멘트보드이 제조가능성(製造可能성)에 관(關)한 연구(硏究)(II) - 물리(物理)·기계적(機械的) 성질(性質) 및 SEM 측정(測定) -)

  • Kim, Sa-Ick;Oh, Jung-Soo
    • Journal of the Korean Wood Science and Technology
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    • v.22 no.2
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    • pp.37-45
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    • 1994
  • The possibility of reusing the paper sludge as a raw material of composition board mixed with cement was investigated. For the measurement of physical and mechanical properties, wood coment board and sludge combinend cement boards were fabricated with the three weigh ratios of paper sludge 10 % (SI), 20 % (S II) and 30 % (S III) to cement weight. For adding the cement hardning, $CaCl_2$ was also added to each mixed paste with the ratio of 1 %, 3 % and 5 % to cement weight, respectively. Crystal formation in paper sludge-, wood-cement composites was observed by scanning electron microscope. The results were summarized as follows. 1. Density and partial compressive strength of each specimens were relatively high in the order of sludge I, sludge II, Korean pine, Italian poplar and sludge III, sludge I, Korean pine, sludge II, Italian poplar and sludge III. 2. The mechanical properties of sludge-cement boards (S I and II) were higher than that of wood-cement boards prepared with Korean pine and Italian poplar. But the mechanical properties of wood-cement boards were improved by the adding of $CaCl_2$. 3. Water absorption and thickness swelling were increased with increase of sludge content to cement weight. 4. In SEM observation, sludge-cement composites showed sufficiently formed crystals but wood-cement composites showed poorly formed crystals.

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Evaluation of Vulnerability to Groundwater Contamination using Groundwater Quality Characteristics and DRASTIC Index in Miryang City (밀양시 지하수 수질 특성과 DRASTIC 지수를 이용한 지하수 오염취약성 평가)

  • SeongYeon Jung;Sieun Kim;Sul-Min Yun;Jeheon Oh;Chung-Mo Lee
    • Journal of Soil and Groundwater Environment
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    • v.29 no.3
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    • pp.23-36
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    • 2024
  • Miryang City, the study area, has a water supply rate of 87.4%, which is 12% lower than the national water supply rate of 99.4%, but has a high dependence on groundwater due to the high ratio of farms. In agricultural areas, contamination becomes relatively more critical, requiring significant attention to the management and conservation of groundwater resources. This study aims at estimate groundwater vulnerability of Miryang City using the DRASTIC index map, Piper diagram, and water quality data to correlated with the DRASTIC index. The results from DRASTIC map were divided into five classes: very high, high, moderate, low, and very low. The areas in central and southern part of study area, which are characterize by a very high index with [Ca-Cl] and [Na-Cl] water types, covering a large alluvium with the Miryang River and Nakdonggang River. In addition, a correlation analysis between groundwater quality parameters and the DRASTIC index was carried out. Chloride, sodium, and sulfate ions showed a weak relationship with DRASTIC index, with correlation coefficient was 0.507, 0.487 and 0.344, respectively. These results suggest that aquifer media, soil media, hydraulic conductivity, and chloride ion are important factors for groundwater vulnerability.

Manufacturing Method and Characteristics of the Dongrok(copper chloride) pigments (동록(염화동) 안료의 제조방법 및 특성에 관한 연구)

  • KANG Yeongseok;PARK Juhyun;MUN Seongwoo;HWANG Gahyun;KIM Myoungnam;LEE Sunmyung
    • Korean Journal of Heritage: History & Science
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    • v.56 no.2
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    • pp.148-169
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    • 2023
  • Hayeob pigment is known as one of the traditional dark green pigments, but the color, raw material, and manufacturing method have not been clearly identified. However, comparing the analysis results of the particle shape and constituent minerals of Hayeob pigments revealed through pigment analysis studies of colored cultural properties such as Dancheong, Gwaebul, and paintings, Hayeob pigments appear to be the same as Dongrok pigments produced by salt corrosion. Therefore, in order to restore Hayeob pigment, the manufacturing method of Dongrok pigment was studied based on the records of old literature. The Dongrok pigment manufacturing method confirmed in the old literature records is a natural corrosion method in which copper powder and a caustic are mixed and then left in a humid condition to corrode. Based on this, artificial corrosion using a corrosion tester was adopted to corrode the copper powder more efficiently, and an appropriate mixing ratio was selected by analyzing the state of corrosion products according to the mixing ratio of the caustic agent. In addition, the manufacturing method of Dongrok pigment was established by adding a salt removal process to remove residual caustic agents and a purification process to increase chroma during pigment coloring. The prepared Dongrok pigments have a bluish green or green color, show an elliptical particle shape and a form in which small particles are aggregated, and a porous surface is observed. The main constituent elements are copper(Cu) and chlorine(Cl), and the main constituent mineral is identified as atacamite [Cu2Cl(OH)3]. As a result of an accelerated weathering test to evaluate the stability of the prepared Dongrok pigments, it was found that the greenness partially decreased and the yellowness significantly increased as deterioration progressed. Before deterioration, the Dongrok pigments had lower yellowness compared to the Hayeob pigments of the old Dancheong, but after deterioration, yellowness increased significantly, and it was found to have a similar chromaticity range as Dancheong's Hayeob pigments. As a result, the prepared Dongrok pigments were confirmed to be similar to Dancheong's Hayeob pigments in terms of color as well as particle shape and constituent minerals.

Catalytic hydrogenation-assisted preparation of melt spinnable pitches from petroleum residue for making mesophase pitch based carbon fibers

  • Lee, Dong Hun;Choi, Jisu;Oh, Young Se;Kim, Yoong Ahm;Yang, Kap Seung;Ryu, Ho Jin;Kim, Yong Jung
    • Carbon letters
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    • v.24
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    • pp.28-35
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    • 2017
  • We demonstrated an effective way of preparing melt spinnable mesophase pitches via catalytic hydrogenation of petroleum residue (fluidized catalytic cracking-decant oil) and their subsequent thermal soaking. The mesophase pitches thus obtained were analyzed in terms of their viscosity, elemental composition, solubility, molecular weight, softening point and optical texture. We found that zeolite-induced catalytic hydrogenation under high hydrogen pressure contributed to a large variation in the properties of the pitches. As the hydrogen pressure increased, the C/H ratio decreased, and the solubility in n-hexane increased. The mesophase pitch with entirely anisotropic domains of flow texture exhibited good meltspinnability. The mesophase carbon fibers obtained from the catalytically hydrogenated petroleum residue showed moderate mechanical properties.

Isolation and Characterization of a Naphthalene-Degrading Strain,Alcaligenes sp,A111 (Naphthalene 분해균주 Alcaligenes sp. A111의 분리 및 특성)

  • Oh, Hee-Mock;Kang, Jung-Hyun;Lee, Chang-Ho;Park, Chan-Sun;Ahn, Sung-Ku;Yoon, Byung-Dae;Kho, Yung-Hee
    • Microbiology and Biotechnology Letters
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    • v.22 no.4
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    • pp.423-429
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    • 1994
  • A bacterial strain which formed a distinct colony on agar plate containing naphthalene as a vapor phase and grew well ina liquid minimal medium was isolated and identified as Alcaligenes sp. A111. Optimum temperature and pH for the cultivation of Alcaligenes sp. A111 were 30$\cir$C and 7.0, respectively. Cell growth increased dramatically from 12 hours after inoculation and revealed a stationary phase at about 48 hours. Relative growth rate ($\mu$')increased hyperbolically depending on the conceration of naphthalene up to 500 ppm and reached to the maximum value pf 2.8/day, but $\mu$' didn't change within a range of 500~4000 ppm naphthalene. NH$_{4}$Cl or NH$_{4}$NO$_{3}$ was preferrd as a nitrogen source and a P : N ratio by weight og 6 : 1 was favorable to cell growth. Alcaligenes sp. A111 utilized the intermediates of degradation of naphthalene and showed tolerance to benzene, toluene, and octane. therefore, it is suggested that Alcaligenes sp. A111 could be effectively used for the biological treatment of wastewater containing naphthalene in the presence of some aromatic compounds.

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Properties of Te Fine Particle Doped SiO2 Gel by the Sol-Gel Method (졸-겔법에 의한 Te 미립자분산 SiO2 겔의 특성)

  • Mun, Shong-Soo;Jo, Bum-Rae;Kang, Bong-Sang
    • Korean Journal of Materials Research
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    • v.12 no.8
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    • pp.650-655
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    • 2002
  • $SiO_2$ gels containing dispersed fine Te metal particles have been prepared by the sol- gel method using a starting solution containing Tetraethoxy Silane (Si($OC_2$ $H_{5}$ )$_4$), $H_2$O, Ethylalchol ($C_2$$H_{5}$OH), Nitric Acid ($HNO_3$) and Tellurium Tetracholoride ($TeCl_4$) in a several molar ratio. Gelling time of sols was about 3 days and viscosity of solution was very low about 2~3 cP for 3 days. Heat-treatments of the gel have been performed at 500, 700, 900, 1100 and $1300^{\circ}C$ for 1 hour, respectively. We have investigated TG-DTA, X-ray diffraction patterns and SEM of heat-treatmented gels. The size of Te fine particles dispersed in $SiO_2$ gel was about 0.8~1 $\mu\textrm{m}$ and the shape was almost quadrangle.