• 제목/요약/키워드: $[^{13}N]NH_3$

검색결과 298건 처리시간 0.063초

Effect of Different Levels of Rumensin in Diet on Rumen Fermentation, Nutrient Digestibility and Methane Production in Cattle

  • Singh, G.P.;Mohini, M.
    • Asian-Australasian Journal of Animal Sciences
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    • 제12권8호
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    • pp.1215-1221
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    • 1999
  • Twelve rumen fistulated cross-bred calves were divided into three groups and fed wheat straw and concentrate mixture according to their maintenance requirement. Animals in group II and III were fed 50 and 100mg rumensin per day, in addition to basal feed. Supplementation of rumensin in the diet decreased the dry matter intake significantly (p<0.05) along with a significant decrease in the straw intake. Digestibility coefficients of all the nutrients were not affected significantly except that of CF digestibility which was lower (p<0.05) in groups II and III as compared to group I. Among N-parameters in the rumen fluid, mean $NH_3-N$ was significantly lower in groups II and III (19.13 and 18.63 mg N/100 ml respectively) than in group I (22.68); total-N and TCA-ppt-N did not differ among the three groups. Total VFA concentration did also not differ among the three groups, however, propionate increased from 24.33 molar % to 32.73 while acetate and butyrate decreased respectively from 65.85 to 58.81% and 9.79 to 8.46%. Total VFA, bacteria and protozoa production rates were not affected significantly due to rumensin in diet. Methane production per kg DDM as well as % of methane in total gas were reduced at both the levels of rumensin on different concentrate ratios with wheat straw as roughage. Similar trend was also observed with rice straw and concentrate mixture as substrate with rumensin addition.

둔촌동 습지에서 미지형이 식물 군락 구성에 미치는 영향 (Effects of Micro-topography on Vegetation Pattern in Dunchon-dong Wetland)

  • 남종민;전승혜;최호;김재근
    • 한국습지학회지
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    • 제16권4호
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    • pp.353-362
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    • 2014
  • 본 연구에서는 둔촌동 습지에서 미지형이 식물 군락 구성에 미치는 영향을 연구하기 위하여 2007~2008년에 걸쳐 지형에 따른 수위 변화와 식물 군락의 변화를 조사하였다. 조사 지역을 지대가 낮은 지형부터 높은 지형까지 4개 구역으로 구분하여 조사하였으며, 각각의 구역은 조사 지역 면적 대비 약 11%, 10%, 18%, 24%의 면적을 가지고 있었다. 조사 기간동안 수환경의 pH는 6.10(${\pm}0.13$), 전기전도도는 $51.5({\pm}6.0){\mu}s/cm$이었으며, $PO_4$-P, $NO_3$-N, $NH_4$-N은 각각 $0.04({\pm}0.02)mg/L$, $0.14({\pm}0.07)mg/L$ 그리고 0.01mg/L 이하로 유지되었다. 2008년 3~4월 누적 강수량이 2007년 대비 약 56%로 적었던 것이 지대가 낮은 지형에서 수위 환경 차이를 유발하여 식물 군락 형성에 매우 큰 영향을 미쳤으며, 지형의 높이에 따라 해당 구역을 우점하는 식물 길드가 다르게 나타났다. 이러한 결과는 종자로부터 생활사가 시작되는 1년생 식물 종들이 조사 지역을 전체적으로 우점하였기 때문이며, 다양한 길드의 식물들이 혼재하기 위해서는 높이 구배가 있는 미지형이 조성되어야 한다는 것을 의미한다.

AC and DC anodization on the electrochemical properties of SS304L: A comparison

  • Nur S. Azmi;Mohd N. Derman;Zuraidawani Che Daud
    • Advances in materials Research
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    • 제13권3호
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    • pp.153-160
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    • 2024
  • This study investigates the application of alternating current (AC) and direct current (DC) anodization techniques on stainless steel 304L (SS304L) in an ethylene glycol and ammonium fluoride (NH4F) electrolyte solution to produce a nano-porous oxide layer. With limited research on AC anodizing of stainless steel, this study focuses on comparing AC and DC anodization in terms of current density versus time response, phase analysis using X-ray diffraction (XRD), and corrosion rate determined by linear polarization. Both AC and DC anodization were performed for 60 minutes at 50 V in an electrolyte solution containing 0.5% NH4F and 3% H2O in ethylene glycol. The results show that AC anodization exhibited higher current density compared to DC anodization. XRD analysis revealed the presence of ferrite (α-Fe) and austenite (γ-Fe) phases in the as-received specimen, while both AC and DC anodized specimens exhibited only the γ-Fe phase. The corrosion rate of the AC-anodized specimen was measured at 0.00083 mm/year, lower than the corrosion rate of the DC-anodized specimen at 0.00197 mm/year. These findings indicate that AC anodization on stainless steel offers advantages in terms of higher current density, phase transformation, and lower corrosion rate compared to DC anodization. These results highlight the need for further investigation and exploration of AC anodization as a promising technique for enhancing the electrochemical properties of stainless steel.

금호강 오염의 종합적 조사 (A Survey of the Kumho River Pollution)

  • 배준웅;이상학;이성호
    • 분석과학
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    • 제15권1호
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    • pp.54-66
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    • 2002
  • 금호강 수계의 수질판정과 낙동강 본류에 미치는 영향을 조사하기 위해 2000년 5월부터 2001년 2월까지 5월, 8월 및 12월 3회에 걸쳐 16개 지점에서 BOD 등 총 24개 항목의 수질을 측정하였다. 각 지점별 항목별 대표적인 특징을 조사기간 전 3년간의 연구결과("전 연구결과")와 비교하여 다으과 같은 결론을 얻었다. 조사기간의 금호강 전 지점에 대한 각 항목의 평균값은 다음과 같다. 수온 $17.71^{\circ}C$, pH 8.06, BOD $2.26{\mu}g/mL$ COD $5.58{\mu}g/mL$, DO $7.13{\mu}g/mL$ SS $4.73{\mu}g/mL$ 전기전도도 $570.0{\mu}S/cm$ 유지류 $0.20{\mu}g/mL$ ABS $0.016{\mu}g/mL$ Phenol $0.29{\mu}g/mL$ 영양염류인 Total-N $5.03{\mu}g/mL$ Total-P $0.27{\mu}g/mL$ 이 었다. 중금속류인 Cu $0.005{\mu}g/mL$, Zn $0.007{\mu}g/mL$ Fe $0.044{\mu}g/mL$, Mn $0.001{\mu}g/mL$ 이었다. 한편 As, Cd, Cr 및 Pb는 불검출되었다. 금호강 전 지점에서 평균값으로 "전 연구결과" 와 비교할 때에 오염이 증가된 항목은 페놀 $NH_3-N$$NO_2-N$이며, 감소된 항목은 BOD, COD, SS, 유지류 ABS 등이고, 기타 항목은 비슷한 결과를 보였다. 금호강 수질이 낙동강의 수질에 미치는 영향의 정도는 다음과 같다. 금호강 하천수의 유입 전 지점 14와 유입 후 지점 16의 평균값으로서 BOD 1.07 에서 $1.42{\mu}g/mL$ COD 1.99에서 $2.44{\mu}g/mL$ 전기 전도도 221에서 $392{\mu}S/cm$ 총질소 2.21에서 $2.81{\mu}g/mL$ 총인 0.08에서 $0.19{\mu}g/mL$ 유지류 0.15에서 $0.16{\mu}g/mL$ ABS 0.006에서 $0.015{\mu}g/mL$ 페놀 0.06에서 $0.07{\mu}g/mL$으로 변화를 보였다.

Chemical Changes during Ensilage and In sacco Degradation of Two Tropical Grasses: Rhodesgrass and Guineagrass Treated with Cell Wall-degrading Enzymes

  • Zhu, Yu;Nishino, Naoki;Xusheng, Guo
    • Asian-Australasian Journal of Animal Sciences
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    • 제24권2호
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    • pp.214-221
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    • 2011
  • Effects of the cell wall-degrading enzymes derived from Acremonium cellulolyticus and Trichoderma viride on the silage fermentation and in sacco degradation of tropical grasses i.e. rhodesgrass (Chloris gayana Kunth. cv. Callide) and guineagrass (Panicum maximum Jacq. cv. Natsukaze) were investigated in laboratory-scale experiments. These two grasses were either treated with or without the enzymes before ensiling. Untreated rhodesgrass produced acetate fermentation silage (lactate, $13.0\;g\;kg^{-1}$ DM; acetate, $38.7\;g\;kg^{-1}$ DM) with high final pH value and $NH_3$-N content (5.84 and $215\;g\;kg^{-1}$ DM). Addition of enzymes significantly increased (p<0.01) the lactate production (lactate, 45.6; acetate, $34.0\;g\;kg-^{1}$ DM) and decreased (p<0.01) the pH and $NH_3$-N (4.80 and $154\;g\;kg^{-1}$ DM) in the ensiled forages when compared with the control silages. Untreated guineagrass was successfully preserved with a high lactate proportion (lactate, 45.5; acetate, $24.1\;g\;kg^{-1}$ DM), and the addition of enzymes further enhanced the desirable fermentation (lactate, $57.5\;g\;kg^{-1}$ DM; acetate, $19.4\;g\;kg^{-1}$ DM). The content of NDF was lowered (p<0.05) by enzymes in both silages, but the extent appeared greater in the enzyme-treated rhodesgrass (rhodesgrass, $48\;g\;kg^{-1}$ DM; guineagrass, $21\;g\;kg^{-1}$ DM). Changes in the kinetics of in sacco degradation showed that enzyme treatment increased (p<0.01) the rapidly degradable DM (rhodesgrass, 299 vs. $362\;g\;kg^{-1}$ DM; guineagrass, 324 vs. $343\;g\;kg^{-1}$ DM) but did not influence the potential degradation, lag time and degradation rate of DM and NDF in the two silages.

ORP profile을 이용한 연속 회분식 반응기(Sequencing Batch Reactor)에서 무산소공정 추론 (Inference of Sequencing Batch Reactor Process using Oxidation Reduction Potential)

  • 심문용;부경민;임정훈;우혜진;김창원
    • 한국환경과학회지
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    • 제13권3호
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    • pp.245-250
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    • 2004
  • The SBR(Sequencing Batch Reactor) process is ideally suited to treat high loading wastewater due to its high dilution rate. SBR operates by a cycle of periods consisting of filling, reacting, settling, decanting and idling. The react phases such as aeration or non-aeration, organic oxidation, nitrification, denitrification and other bio-logical reactions can be achieved in a reactor. Although the whole reactions can be achieved in a SBR with time distributing, it is hard to manage the SBR as a normal condition without recognizing a present state. The present state can be observed with nutrient sensors such as ${NH_{4}}^{+}-N$, ${NO_{2}}^{-}-N$, ${NO_{3}}^{-}-N} and ${PO_{4}}^{ 3-}-P.$ However, there is still a disadvantage to use the nutrient sensors because of their high expense and inconvenience to manage. Therefore, it is very useful to use common on-line sensors such as DO, ORP and pH, which are less expensive and more convient. Moreover, the present states and unexpected changes of SBR might be predicted by using of them. This study was conducted to get basic materials for making an inference of SBR process from ORP(oxidation reduction potential) of synthetic wastewater. The profiles of ORP, DO, and pH were under normal nitrification and denitrification were obtained to compare abnormal condition. And also, nitrite and nitrate accumulation were investigated during reaction of SBR. The bending point on ORP profile was not entirely in the low COD/NOx ratio condition. In this case, NOx was not entirely removed, and minimum ORP value was presented over -300mV. Under suitable COD/NOx ratio which complete denitrification was achieved, ORP bending point was observed and minimum ORP value was under -300m V. Under high COD/NOx ratio, ORP bending point was not detected at the first subcycle because of the fast denitrification and minimum ORP value was under -300mV at the time.

낙동강 하구수역의 영양염류와 유기현탁물질 (Nutrients and Suspended Organic Particulates in the Estuary of NakDong River)

  • 최상;정태화
    • 한국해양학회지
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    • 제7권1호
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    • pp.1-14
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    • 1972
  • 낙동강은 유로연장 525km, 유역면적 23,852$\textrm{km}^2$에 달하는 남한 제1의 하천수계를 이루고 있고, 그 수원은 멀리 강원도 삼척군 삼장면 함백산에서 이루어져, 많은 지류수가 합류되어 경남 김해군 명지면과 부산시 서구를 거쳐 남해의 동부해역으로 유입된다. 하구일대는 우리나라에서도 굴지의 해태어장이 형성되고, 인근해역에서는 많은 어패류가 생산된다. 낙동강 하구수역의 수질에 관해서는 원(1964)이 간헐지 수질의 연간변화에 관한 조사가 이루어졌고, 또 원(1970)은 가덕도와 용원리 사이의 해역에서 3월 17-23일에 걸친 조석에 따른 영양염조사를 보고하였고, 최 외(1970)는 낙동강 하구일대의 해태어장개발을 목적으로 한 영양염, 유기현탁물, 조석류, 저질 등에 관한 일련의 결과를 보고하고 있다.

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슬러리형 돈사폐수에서 자원회수와 질소제거를 위한 순차적 결합공정 제안 (A Proposal of Sequencing the Combined Processes for Resources Recovery and Nitrogen Removal from Piggery Waste)

  • 황인수;민경석;배진연
    • 대한환경공학회지
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    • 제28권1호
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    • pp.61-66
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    • 2006
  • 슬러리 형태의 돈사폐수로부터 자원회수와 질소제거를 위하여 순차적으로 ADEPT(Anaerobic digestion elutriated phased treatment) 공정과 SHARON(Single reactor system High Ammonium Removal Over nitrite)-ANAMMOX(Anaerobic ammonium oxidation)공정을 결합하여 운전하였다. ADEPT 공정은 부하율 3.95 gSCOD/L-day에서 운전되었고, SCOD 생성율과 산생성율은 각각 5.3 gSCOD/L-day와 3.3 gVFAs/L-day(as COD)였다. 가수분해에 의한 VS감소와 SCOD생성율은 각각 13%와 0.19 $gSCOD_{prod}/gVS_{feeding}$였으며, 산생성율은 0.80 $gVFAs/gSCOD_{prod.}$였다. 메탄발효조에서 가스생성율과 메탄함량은 각각 2.8 L/day($0.3m^3CH_4/kgCOD_{removal}\;@STP$) 및 77%였다. 운전조건에서 $NH_4-N$ 94.1% (TKN으로서 86.5%) 및 T-P 87.3%가 제거되었다.

지도지생태계의 물리화학적환경과 식물성 플랭크톤군집의 생산성 (Physico-Chemical Environment and Productivity of the Phytoplankton Community in the Jido Pond Ecosystem)

  • Song Seung-Dal;M. Anwarul Huque
    • 환경위생공학
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    • 제5권2호
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    • pp.117-122
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    • 1990
  • 인공지인 지도지생태에 대하여 1979년 4월부터 1980년 3월까지 수온, pH, $Cl^-,\; Mg^{++}$, alkalinity, detergent, $SiO_2-Si, PO_4-P\;^{3-}, NO_3-N\;NO_2-N\;NH_4-N$, BOD, COD, DO, OM 및 OC등의 물리화학적 수질환경의 동태를 분석하고 일차생산자인 식물성플랭크톤의 다양성 및 생장과 생산성을 측정하여 생태계의 물직대사와 에너지이효율을 정량화하였다. 식물성플랭크톤의 분포는 총 28종의 우점종(Chlorophyta 11종, Bacillariophyta 9종 및 Cyanophyta 3종)이 출현하였고, chlorophyta는 전체 algal counts의 75%를 점하였다. 다양성지수는 d=0.85~2.80, $\={H}$=1.10~2.40, e=0.56~0.90였다. 현재량은 0.043~0.385g chl/$m^2$의 범위였고, 광합성율 및 호흡율의 변화는 각각 0.36~4.50와 0.10~1.40mg $O_2$/l/hr이며, 동화량은 0.6~3.8mg C/$m^2$, 태양에너지 이용효율은 연평균 2.44%였다. 인과 질소의 turnover time은 각각 20days와 3days였다.

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Application of upflow multi-layer bioreactor (UMBR) for domestic wastewater treatment in HCMC

  • Cao, Duc Hung;Nguyen, Ngoc Han;Nguyen, Phuoc Dan;Bui, Xuan Thanh;Kwon, J.C.;Shin, H.S.;Lee, E.T.
    • Membrane and Water Treatment
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    • 제3권2호
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    • pp.113-121
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    • 2012
  • Up-flow multi-layer bioreactor (UMBR) is a hybrid system using dual sludge that consists of an up-flow multi-layer bioreactor as anaerobic/anoxic suspended growth microorganisms followed by an aeration tank. The UMBR acts as a primary settling tank, anaerobic/anoxic reactor, thickener which requires low energy due to mixing by up-flow stream. This study focused on using a pilot UMBR plant with capacity of 20-30 $m^3$/day for domestic wastewater in HCMC. HRTs of UMBR and aeration tank were 4.8 h and 7.2 h, respectively. The average MLSS of UMBR ranged from 10,000-13,600 mg/l SS. Internal recycle rate and sludge return were 200-300% and 150-200%, respectively. The results obtained from this study at flow rate of 20 $m^3$/day showed that removal of COD, SS, TKN, N-$NH_4$, T-N, and color were 91%, 87%, 86%, 80%, 91% and 91%, respectively.