• Title/Summary/Keyword: $[^{13}N]NH_3$

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Temporal Variations of Sea Water Environment and Nutrients in the East Coast of Korea in 2013~2017: Sokcho, Jukbyeon and Gampo Coastal Areas (2013~2017년 동해 연안의 해양환경과 영양염의 시간적 변동 : 속초, 죽변, 감포 연안)

  • Kwon, Kee-Young;Shim, Jeong Hee;Shim, Jeong-Min
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.25 no.4
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    • pp.457-467
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    • 2019
  • To investigate the long-term variation characteristics of nutrients in the east coast of Korea, water temperature, salinity, dissolved oxygen, and nutrients were measured at three stations of Sokcho, Jukbyeon and Gampo coasts for five years from 2013 to 2017. For five years, the water temperature of the East Sea coast was in the range of $1.2{\sim}28.8^{\circ}C$, the salinity was in the range of 30.63~34.79 and the dissolved oxygen (DO) was in the range of 3.53~7.64 mL/L. Distribution and variation of the water environment factors in the study area were determined by the vertical stratification of water column and distribution of water temperature. The high DO concentration in Sokcho coast From 2015 to August 2016 is presumed to be the result of the southward inflow of North Korean Cold Water (NKCW). Concentrations of dissolved inorganic nitrogen (DIN, $NH_4-N+NO_2-N+NO_3-N$) ranged $0.11{\sim}24.19{\mu}M$, phosphate concentration ranged $0.01{\sim}1.75{\mu}M$, and silicate ranged $0.17{\sim}32.80{\mu}M$. The N:P ratio was in the range of 0.7~54.3 (mean 15.2) and the N:P slope was in the range of 11.67~13.75. The N:P ratios in this study were lower than the Redfield ratio (16), indicating that nitrate did act as a limiting factor in phytoplankton growth. The correlation ($R^2$) of total N:P ratio was as high as 0.95, indicating that the effect of the surrounding land or non-point sources was not significant. In conclusion, the spatial and temporal variation of nutrients in the east coast of Korea was determined by the vertical mixing of water mass with thermocline and mainly affected by physical factors such as influx of external water masses and coastal upwelling, and the influences from inflows from the land were minimal.

Agricultural Water Quality along the Keum River (금강수계 농업용수의 수질)

  • Lee, Jong-Tae;Lee, Jin-Il;Nam, Yun-Gyu;Han, Kyu-Heung
    • Korean Journal of Environmental Agriculture
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    • v.18 no.2
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    • pp.122-125
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    • 1999
  • The water quality of the Keum river was surveyed at 4 sites from April to September in 1995 and 1997. Average values of inorganic contents analyzed in 1997 were pH 7.2, EC 0.18dS/m, $NH_4-N$ 0.60mg/l, $K^+$ 4.12mg/l, $Ca^{2+}$ 12.12 mg/l, $Mg^{2+}$ 2.75mg/l, $Na^+$ 15.1mg/l, $NO_3-N$ 1.97mg/l, $PO_4^{3-}$ 0.15mg/l, $PO_4^-$ 18.9mg/l, $Cl^-$ 21.8mg/l, Fe 0.22mg/l, COD 19.7mg/l. On the basis of these values, it was suitable for the irrigation source. Water pH of the Keum river ranged from 6.7 to 8.0. EC of the Daecheong-dam was maintained below 0.13dS/m, but those of the middle and lower stream were ranged from 0.13dS/m to 0.32dS/m. Monthly average values of all the ration contents were the highest in April and were decreased thereafter. And it was slightly increased in September. However $NO_3-N$, $SO_4^{2-}$ contents were higher in June than any other months. All the inorganic contents were the highest at Taepyeong-ri, Yeongi-gun due to sewage water and livestock wastes. The inorganic contents were negatively correlated with precipitation, generally.

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Factors Influencing Nitrite Build-up Nitrification of High Strength Ammonia Wastewater (고농도 암모니아성 폐수의 질산화과정에서 아질산염 축적의 영향인자)

  • 한동준;강성환;임재명
    • Journal of environmental and Sanitary engineering
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    • v.13 no.2
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    • pp.128-138
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    • 1998
  • This study was focused to find how each factors effect on the biological nitrification in wastewater treatment under high ammonia nitrogen concentration. Batch reactors in aerobic conditions were used to test the treatment efficiency of mixed liquor, nightsoil and piggery wastewater. The results are summeried as follows; Initial ammonia nitrogen concentration and pH were the direct influencing factors of nitrite build-up. More than 250 mg NH$_{4}$$^{+}$ - N/L in initial concentration built up nitrite and then the inhibition rate to Nitrobacter was above 70 percentage. And maximum nitritation rate was showed at pH 8.3 and nitrification could be completely achieved by pH control. Temperature and dissolved oxygen were the indirect influencing factors of nitrite build-up. These were a great effect on the activity of nitrifying microbes and ammonia nitrogen removal. Maximum nitritation rate was showed at 30 $\circ $C. The effect of DO concentration was negligible at more than 3 mg/L.

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Effects of Polyurethane Coated Urea Supplement on In vitro Ruminal Fermentation, Ammonia Release Dynamics and Lactating Performance of Holstein Dairy Cows Fed a Steam-flaked Corn-based Diet

  • Xin, H.S.;Schaefer, D.M.;Liu, Q.P.;Axe, D.E.;Meng, Q.X.
    • Asian-Australasian Journal of Animal Sciences
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    • v.23 no.4
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    • pp.491-500
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    • 2010
  • Three experiments were conducted to investigate the effects of polyurethane coated urea on in vitro ruminal fermentation, ammonia release dynamics and lactating performance of Holstein dairy cows fed a steam-flaked corn-based diet. In Exp. 1, a dual-flow continuous culture was run to investigate the effect of polyurethane coated urea on nutrient digestibility, rumen fermentation parameters and microbial efficiency. Three treatment diets with isonitrogenous contents (13.0% CP) were prepared: i) feedgrade urea (FGU) diet; ii) polyurethane coated urea (PCU) diet; and iii) isolated soy protein (ISP) diet. Each of the diets consisted of 40% steam-flaked corn meal, 58.5% forages and 1.5% different sources of nitrogen. PCU and FGU diets had significantly lower digestibility of NDF and ADF (p<0.01) than the ISP diet. Nitrogen source had no significant effect (p = 0.62) on CP digestibility. The microbial efficiency (expressed as grams of microbial N/kg organic matter truly digested (OMTD)) in vitro of the PCU diet (13.0 g N/kg OMTD) was significantly higher than the FGU diet (11.3 g N/kg OMTD), but comparable with the ISP diet (14.7 g N/kg OMTD). Exp. 2, an in vitro ruminal fermentation experiment, was conducted to determine the ammonia release dynamics during an 8 h ruminal fermentation. Three treatment diets were based on steam-flaked corn diets commonly fed to lactating cows in China, in which FGU, PCU or soybean meal (SBM) was added to provide 10% of total dietary N. In vitro $NH_3-N$ concentrations were lower (p<0.05) for the PCU diet than the FGU diet, but similar to that for the SBM diet at all time points. In Exp. 3, a lactation trial was performed using 24 lactating Holstein cows to compare the lactating performance and blood urea nitrogen (BUN) concentrations when cows were fed PCU, FGU and SBM diets. Cows consuming the PCU diet had approximately 12.8% more (p = 0.02) dietary dry matter intake than those consuming the FGU diet. Cows fed the PCU diet had higher milk protein content (3.16% vs. 2.94%) and lower milk urea nitrogen (MUN) concentration (13.0 mg/dl vs. 14.4 mg/dl) than those fed the FGU diet. Blood urea nitrogen (BUN) concentration was significantly lower for cows fed the PCU (16.7 mg/dl) and SBM (16.4 mg/dl) diets than the FGU (18.7 mg/dl) diet. Cows fed the PCU diet had less surplus ruminal N than those fed the FGU diet and produced a comparable lactation performance to the SBM diet, suggesting that polyurethane coated urea can partially substitute soybean meal in the dairy cow diet without impairing lactation performance.

Tubular Alumina Microfiltration Membrane System with Periodic N2-back-flushing for Water Treatment

  • Park, Jin-Yong;Park, Seong-Jae;Kim, Geun-Su
    • Korean Membrane Journal
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    • v.10 no.1
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    • pp.26-32
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    • 2008
  • The Gongji stream water of Chuncheon city was filtrated by 2 kinds of tubular alumina ceramic MF membranes with periodic $N_2$-back-flushing. $N_2$-back-flushing time (BT) was changed in $0{\sim}50$ sec at fixed filtration time (FT), or back-flushing period, of 4 min for NCMT-5231 membrane ($0.05\;{\mu}m$). Then, FT was changed in $0{\sim}32$ min at fixed BT of 40 sec for NCMT-7231 $0.1{\mu}m)$). In the viewpoints of total permeate volume ($V_T$), dimensionless permeate flux ($J/J_0$) and resistance of membrane fouling ($R_f$), the optimal $N_2$-BT was 50 sec, which was the longest BT, at 4 min FT for NCMT-5231. It means the longest BT was the most effective to minimize the membrane fouling, and we could acquire the most $V_T$. But the optimal FT for NCMT-7231 was 16 min in the viewpoint of $V_T$, and was 8 min in the viewpoints of $J/J_0$ and $R_f$ at fixed BT of 40 sec. The rejection rates were excellent as $80.6{\sim}96.6\;%$ for turbidity, $35.2{\sim}58.4%$ for $NH_3$-N, $16.3{\sim}45.2%$ for T-P and $16.3{\sim}45.2%$ for $COD_{Mn}$. However, the rejection rate of T-N was very low as $2.7{\sim}13.4%$ and it of TDS below 6.1%.

Development of Root Media Containing Pine Bark for Cultivation of Horticultural Crops (소나무 수피를 포함한 원예작물 재배용 혼합상토의 개발)

  • Park, Eun Young;Choi, Jong Myung
    • Horticultural Science & Technology
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    • v.32 no.4
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    • pp.499-506
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    • 2014
  • This research was conducted to develop root media containing ground and aged pine bark (GAPB) and ground and raw pine bark (GRPB). After analysis of physico chemical properties, the pine barks were blended with peat moss (PM) or coir dust (CD) in various ratios to formulate 12 root media. Then, two out of 12 root media were chosen based on the physical properties for further experiments. The pre-planting nutrient charge fertilizers (PNCF) were incorporated into two root media and chemical properties were analysed again. The total porosity (TP), container capacity (CC), and air-filled porosity (AFP) of GAPB were 78.7%. 39.4%, and 38.3%, respectively, while those of GRPB were 74.7%, 41.2%, and 33.4%, respectively. The percentage of easily available water (EAW, from CC to 4.90 kPa tension) and buffering water (BW, 4.91-9.81 kPa tension) in GAPB were 12.7% and 8.5%, respectively, which were a little lower than the 13.5% and 8.8% in GRPB. The pH and EC were not different significantly, but cation exchange capacity was different between the two pine barks (GAPB: pH 5.26, EC $0.61dS{\cdot}m^{-1}$, CEC $15.7meq{\cdot}100g^{-1}$; GRPB: pH 5.19, EC $0.32dS{\cdot}m^{-1}$, CEC $9.32meq{\cdot}100g^{-1}$). The concentrations of exchangeable cations in GAPB were Ca 0.32, K 0.05, Mg 0.27 and $0.12cmol+{\cdot}kg^{-1}$, whereas those in GRPB were Ca 0.28, K 0.08, Mg 0.25 and $0.09cmol+{\cdot}kg^{-1}$. The concentrations of $PO_4$-P, $NH_4$-N and $NO_3$-N were 485.8, 0.62 and $0.91mg{\cdot}L^{-1}$ in GAPB and 578, 1.00 and $0.82mg{\cdot}L^{-1}$ in GRPB, respectively, when those were analyzed in the solution of the saturated paste. The TP, CC and AFP in the two selected media were 89.3 and 76.3, and 13.0% in PM+GAPB (8:2, v/v) and 88.2, 68.2 and 20.0% in CD+GRPB (8:2), respectively. The pHs and ECs were 3.8 and $0.24dS{\cdot}m^{-1}$ in PM+GAPB which were a little lower than 5.8 and $0.65dS{\cdot}m^{-1}$ in CD+GRPB. However, the pHs analysed before and after incorporation of PNCF in the two root media did not show large differences. This is because the solubility of dolomitic lime is very low, and the pH it is expected to rise gradually when crops are cultivated int he root media. The information obtained in this study should facilitate effective formulation of root media containing pine bark.

Changes in Crop Growth and Nutrient Concentrations of Tissue and Soil Solution in Raising of Hot Pepper Plug Seedlings as Influenced by Various Pre-planting Nitrogen Levels Incorporated into a Inert Medium (상토 조제과정에서 혼합된 질소 시비 수준 차이가 고추 플러그 묘 생장과 상토 및 식물체 무기염 농도 변화에 미치는 영향)

  • Oh, Sang Se;Kim, Yun-Seob;Park, Myong Sun;Kim, Hyun Cheul;Choi, Jong Myung
    • Journal of Bio-Environment Control
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    • v.27 no.2
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    • pp.173-179
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    • 2018
  • Investigation of the optimum levels of pre-plant nitrogen for raising of hot pepper (cv. Nokkwang) plug seedlings was the objective of this research. To achieve this, the pre-plant nitrogen levels were varied to 0, 100, 250, 500, 750, 1,000, and $1,500mg{\cdot}L^{-1}$ and the other essential nutrients were controlled to equal concentrations in all treatments. All the fertilizers were added during the formulation of the mixed medium of coir dust, peatmoss, and perlite with the ratio of 35, 35, and 30% (v/v/v). The root medium containing pre-plant fertilizer was packed into 50-cell plug trays and seeds were sown. The measurement of pH and EC in every week, soil solution analysis for nutrients in week 0, 3, and 7 and growth measurements as well as tissue analysis for nutrient contents in week 7 were conducted. The pHs measured before seed sowing did not show significant differences, but the differences among treatments became significant as seedlings grow bigger. The soil solution ECs were significantly different among treatments in week 0 and these differences were diminished by degrees after week 3, resulting in no significant differences among treatments in week 7. The trends in changes of $NH_4-N$, $NO_3-N$, and other the macro-element concentrations in soil solution of root media were similar to those of ECs. The treatments of 500 and $750mg{\cdot}L^{-1}$ N were more effective than other treatments on seedling growth. The seedling growths in the treatments containing higher N than $1,000mg{\cdot}L^{-1}$ and control were severely suppressed. The elevated pre-plant N concentrations in the root medium resulted in the increase of tissue N contents. The treatments of 500 and $750mg{\cdot}L^{-1}$ N shown the highest seedling growths had 5.13% and 5.31%, respectively, in tissue N contents based on the dry weight of above ground tissue at week 7. The results of this study indicated that the optimum level of pre-plant N is 500 to $750mg{\cdot}L^{-1}$ for the raising of hot pepper plug seedlings.

Effect of Level of Crude Protein and Use of Cottonseed Meal in Diets Containing Cassava Chips and Rice Straw for Lactating Dairy Cows

  • Promkot, C.;Wanapat, M.
    • Asian-Australasian Journal of Animal Sciences
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    • v.18 no.4
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    • pp.502-511
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    • 2005
  • The effects of different levels of crude protein (CP) and cottonseed meal replacing for soybean meal in cassava chips and rice straw-based diets for mid-lactating cows (100-150 day in milk [DIM]), were studied using 32 multiparous Holstein Fresian crossbred dairy cows. Diets containing 10.5, 12.5, 13.7, 14.4% CP of the rations and 0, 12.1, 14.9, 17.8% cottonseed meal were fed to cows for 60 days. Thirty two cows were randomly divided into four dietary treatments using a Randomized complete block design. Four dietary treatments were offered in the form of total mixed ration (TMR) with concentrate to roughage (chopped rice straw) at 60:40 and offered ad libitum. Dry matter (DM) and neutral detergent fiber (NDF) intakes tended to linearly increase with increasing dietary CP levels. Intakes and digestibility of crude protein increased linearly with increasing dietary CP level (p<0.01). Crude protein digestibility of the 10.5% CP diet was lower (p<0.05) than that in diets with higher levels of CP, while there were no significant differences among the other three levels of CP (12.5, 13.7 and 14.4%). Daily milk yield tended to increase with increased CP from 10.5 to 14.4%. Income over feed in terms of US$/kg of milk increased with increased CP from 10.5 to 13.7% and decreased when the CP level was higher than 13.7% (quadratic effect p<0.09). Milk composition was not significantly affected by increasing level of CP, however there were relatively high contents of protein and fat among treatments. The proportion of milk-urea N (MUN), ammonia-N ($NH_3$-N) and bloodurea N (BUN) were closely correlated and increased linearly with increasing CP levels (p<0.01). Balanced diet was found in diet containing 12.5 and 13.7% CP of the rations when BUN and MUN were used as indicators of the protein to energy ratio in the diet. Conclusions can be made that increasing dietary CP levels from 10.5 to 13.7% using cottonseed meal as the main source to completely replace soybean meal was beneficial to cows consuming rice straw and cassava chips based-diets. Increasing the CP level above 13.7% of total ration did not additionally improve milk yield and composition or net income.

Statistical Analyses of Long-Term Water Quality Variation in the Geumgang-Reservoir: Focused on the TP Load by Migrating Birds Excrement (금강호의 장기 수질 변화요인 분석: 철새배설물에 의한 TP부하의 중요성)

  • Jeong, Yong-Hoon;Kim, Hyun-Soo;Yang, Jae-Sam
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.13 no.4
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    • pp.223-233
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    • 2010
  • Spatio-temporal variations of long-term water qualities (COD, SS, $Chl-{\alpha}$, N-related nutrients (TN, TDN, $NO_3^-$, $NH_4^+$), P-related nutrients (TP, TDP, $PO_4^{3-}$)) at two stations (St. SD, St. GG) in the Geumgang Reservoir were investigated from August 2001 to July 2008. Statistical methods such as t-test, factor analysis, and multi-regression analysis were applied to the water quality data in the reservoir as well as mass balances on TP. From the temporal comparisons of the water qualities between 2002 and 2007, average concentrations of $NH_4^+$, $PO_4^{3-}$, and TDP gradually decreased down by 60%, 24%, 52% in 2007. However, those of TP and $Chl-{\alpha}$ increased to 99% and 423% during the period. From the spatial comparisons between the two stations, St. GG showed higher concentrations for all of the N- and P-related nutrients than in St. SD, while opposite result for the $Chl-{\alpha}$. The factor analysis showed that "the seasonal variations of N- and P-related nutrients" were the two dominant factors occupying 49% of total variances of water qualities. Based on this result, multi-regression analysis executed for the two most influential parameters (TP and $Chl-{\alpha}$) focusing on the seasonal variations of these parameters: SS and $Chl-{\alpha}$ has contributed decisively to the concentrations of TP during the wet and dry season, respectively. On the other hand, COD and TP has been important for the $Chl-{\alpha}$ during the wet and dry season, respectively. From the established mass balances of TP loadings in the Geumgang Reservoir, Other Sources (60%) occupied the greatest contribution and Fluvial Input (38%) and Sediment (1%) during the wet season. However, both Fluvial Water (48%) and Other Sources (47%) supplied comparable amount of inputs and Sediment (5%) showed significantly increased input during the dry seasons. Recently especially during the dry winter seasons, migrating bird's excretion was estimated to contribute up to 8% of total TP input and 21% of Other Sources.

Characterization of NOx Emission from Soils in Southwest Korea and Their Atmospheric Chemistry (질소산화물의 토양배출량 추정과 지구 환경에 미치는 대기화학적 특성 연구)

  • 김득수
    • Journal of Korean Society for Atmospheric Environment
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    • v.13 no.6
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    • pp.451-461
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    • 1997
  • The soil NO flux measurements in Korea were made from 17 May 1997 to 16 June 1997 on grass land at Kunsan National University in southwestern Korea by using flow-through chamber technique. The experiment was conducted in an effort to determine the role of natural emissions of NO on rural atmospheric photochemistry, and to understand the soil NO emission mechanism with respect to soil parameters. Soil NO fluxes were measured every minutes and averaged in every 15 minutes as well as soil temperature. Soil samples were analyzed for $NO_3^-, NH_4^+$, and moisture in soil. Soil nitrate was not detected in most times, and total N-containing was limited in site soils. There was a optimum range of soil moisture and temperature for soil NO flux. The overall average of soil NO emission rates were found to be 1.30 $\pm 0.92 ngNm^{-2}s^{-1}$ (n=1219), and ranged from 0.01 ngNm^{-2}s^{-1}$ to 5.62 ngNm^{-2}s^{-1}$. Diurnal variation of soil NO emission was typical, which was in higher level during daytime, and was in lower level over the night. NO flux showed a strong soil temperature dependence $(r^2=0.78)$, but not with soil moisture and soil N-containing during this experimental period; NO fluxes increased exponentially as soil temperature increased. In order to assure the relevant relationship between soil NO flux and the soil parameters, long-term soil flux measurement on different types of land use should be planned and conducted continuously.

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