• Title/Summary/Keyword: $[^{13}N]NH_3$

Search Result 298, Processing Time 0.022 seconds

Effect of Different Levels of Rumensin in Diet on Rumen Fermentation, Nutrient Digestibility and Methane Production in Cattle

  • Singh, G.P.;Mohini, M.
    • Asian-Australasian Journal of Animal Sciences
    • /
    • v.12 no.8
    • /
    • pp.1215-1221
    • /
    • 1999
  • Twelve rumen fistulated cross-bred calves were divided into three groups and fed wheat straw and concentrate mixture according to their maintenance requirement. Animals in group II and III were fed 50 and 100mg rumensin per day, in addition to basal feed. Supplementation of rumensin in the diet decreased the dry matter intake significantly (p<0.05) along with a significant decrease in the straw intake. Digestibility coefficients of all the nutrients were not affected significantly except that of CF digestibility which was lower (p<0.05) in groups II and III as compared to group I. Among N-parameters in the rumen fluid, mean $NH_3-N$ was significantly lower in groups II and III (19.13 and 18.63 mg N/100 ml respectively) than in group I (22.68); total-N and TCA-ppt-N did not differ among the three groups. Total VFA concentration did also not differ among the three groups, however, propionate increased from 24.33 molar % to 32.73 while acetate and butyrate decreased respectively from 65.85 to 58.81% and 9.79 to 8.46%. Total VFA, bacteria and protozoa production rates were not affected significantly due to rumensin in diet. Methane production per kg DDM as well as % of methane in total gas were reduced at both the levels of rumensin on different concentrate ratios with wheat straw as roughage. Similar trend was also observed with rice straw and concentrate mixture as substrate with rumensin addition.

Effects of Micro-topography on Vegetation Pattern in Dunchon-dong Wetland (둔촌동 습지에서 미지형이 식물 군락 구성에 미치는 영향)

  • Nam, Jong Min;Jeon, Seung-Hye;Choi, Ho;Kim, Jae Geun
    • Journal of Wetlands Research
    • /
    • v.16 no.4
    • /
    • pp.353-362
    • /
    • 2014
  • The purpose of this study is to investigate the effect of micro-topography to vegetation pattern in Dunchon-dong wetland. To characterize the effect of micro-topography, changes in water level and vegetation pattern were monitored from 2007 to 2008. Depending on the relative elevation, the study site was divided into 4 sectors. The relative areas of sectors in ascending order were 11%, 10%, 18% and 24%, respectively. During investigation period, average water pH was 6.10 (${\pm}0.13$), electron conductivity was $51.5({\pm}6.0){\mu}s/cm$, $PO_4$-P, $NO_3$-N and $NH_4$-N concentration were $0.04({\pm}0.02)mg/L$, $0.14({\pm}0.07)mg/L$, and lower than 0.01mg/L, respectively. Water level was very changeable in low-water season because the area of lowest sector was small. This characteristic increased the effect of difference of accumulated precipitation from March to April in 2007 and 2008 to plant community composition in lower sectors. Different plant guilds dominated respective sectors and annual plants were major dominant species in the study site. This study suggested that the elevation gradients are necessary to create the habitats for various plant guilds in wetland.

AC and DC anodization on the electrochemical properties of SS304L: A comparison

  • Nur S. Azmi;Mohd N. Derman;Zuraidawani Che Daud
    • Advances in materials Research
    • /
    • v.13 no.3
    • /
    • pp.153-160
    • /
    • 2024
  • This study investigates the application of alternating current (AC) and direct current (DC) anodization techniques on stainless steel 304L (SS304L) in an ethylene glycol and ammonium fluoride (NH4F) electrolyte solution to produce a nano-porous oxide layer. With limited research on AC anodizing of stainless steel, this study focuses on comparing AC and DC anodization in terms of current density versus time response, phase analysis using X-ray diffraction (XRD), and corrosion rate determined by linear polarization. Both AC and DC anodization were performed for 60 minutes at 50 V in an electrolyte solution containing 0.5% NH4F and 3% H2O in ethylene glycol. The results show that AC anodization exhibited higher current density compared to DC anodization. XRD analysis revealed the presence of ferrite (α-Fe) and austenite (γ-Fe) phases in the as-received specimen, while both AC and DC anodized specimens exhibited only the γ-Fe phase. The corrosion rate of the AC-anodized specimen was measured at 0.00083 mm/year, lower than the corrosion rate of the DC-anodized specimen at 0.00197 mm/year. These findings indicate that AC anodization on stainless steel offers advantages in terms of higher current density, phase transformation, and lower corrosion rate compared to DC anodization. These results highlight the need for further investigation and exploration of AC anodization as a promising technique for enhancing the electrochemical properties of stainless steel.

A Survey of the Kumho River Pollution (금호강 오염의 종합적 조사)

  • Bae, Zun-Ung;Lee, Sang-Hak;Lee, Sung-Ho
    • Analytical Science and Technology
    • /
    • v.15 no.1
    • /
    • pp.54-66
    • /
    • 2002
  • In order to study systematic survey of Kumho river pollution, water analysis for 24 items was conducted at 16 sites surrounding the Kumho river system for 3 times from May 2000 to February 2001. Analytical items for the study of water quality are as follows; water temperature, pH, BOD, COD, DO, SS, electrical conductivity, oil & grease, ABS, phenol, T-P, ${PO_4}^{3-}-P$, T-N, $NH_3-N$, ${NO_2}^--N$, ${NO_3}^--N$, Cu, Zn, Cr, Cd, Mn, Fe, Pb and As. The mean values obtained for water temperature, pH, BOD, COD, DO, SS, electrical conductivity, oil & grease, ABS, phenol T-P, T-N, Cu, Zn, Fe and Mn showed $17.84^{\circ}C$, 8.04, $2.54{\mu}g/mL$, $5.64{\mu}g/mL$, $7.07{\mu}g/mL$, $8.75{\mu}g/mL$, $600.4{\mu}S/cm$, $0.19{\mu}g/mL$, $0.015{\mu}g/mL$, $0.29{\mu}g/mL$, $0.21{\mu}g/mL$, $5.22{\mu}g/mL$, $0.005{\mu}g/mL$, $0.007{\mu}g/mL$, $0.044{\mu}g/mL$ and $0.001{\mu}g/mL$ respectively. As, Cd, Cr and Pb are not detected. The mean concentration of phenol, $NH_3-N$ and $NO_2-N$ were found to be increased compared to the prior study for 3 years from January 1997 to December 1999, that of BOD, COD, SS, oil & grease and ABS were found to be decreased and the others are nearly constant. The effect of Kumho river to the Nakdong river pollution are as follows. The mean concentration of BOD changed from $1.07{\mu}g/mL$ to $1.42{\mu}g/mL$ before and after of introducing of Kumho river water respectively. The mean concentration of COD, electrical conductivity, oil & grease, ABS, phenol, T-N and T-P changed from $1.99{\mu}g/mL$, $221{\mu}S/cm$, $0.15{\mu}g/mL$, $0.006{\mu}g/mL$, $0.06{\mu}g/mL$, $2.21{\mu}g/mL$ and $0.08{\mu}g/mL$ to $2.44{\mu}g/mL$, $392{\mu}S/cm$, $0.16{\mu}g/mL$, $0.015{\mu}g/mL$, $0.07{\mu}g/mL$, $2.81{\mu}g/mL$ and $0.19{\mu}g/mL$ respectively.

Chemical Changes during Ensilage and In sacco Degradation of Two Tropical Grasses: Rhodesgrass and Guineagrass Treated with Cell Wall-degrading Enzymes

  • Zhu, Yu;Nishino, Naoki;Xusheng, Guo
    • Asian-Australasian Journal of Animal Sciences
    • /
    • v.24 no.2
    • /
    • pp.214-221
    • /
    • 2011
  • Effects of the cell wall-degrading enzymes derived from Acremonium cellulolyticus and Trichoderma viride on the silage fermentation and in sacco degradation of tropical grasses i.e. rhodesgrass (Chloris gayana Kunth. cv. Callide) and guineagrass (Panicum maximum Jacq. cv. Natsukaze) were investigated in laboratory-scale experiments. These two grasses were either treated with or without the enzymes before ensiling. Untreated rhodesgrass produced acetate fermentation silage (lactate, $13.0\;g\;kg^{-1}$ DM; acetate, $38.7\;g\;kg^{-1}$ DM) with high final pH value and $NH_3$-N content (5.84 and $215\;g\;kg^{-1}$ DM). Addition of enzymes significantly increased (p<0.01) the lactate production (lactate, 45.6; acetate, $34.0\;g\;kg-^{1}$ DM) and decreased (p<0.01) the pH and $NH_3$-N (4.80 and $154\;g\;kg^{-1}$ DM) in the ensiled forages when compared with the control silages. Untreated guineagrass was successfully preserved with a high lactate proportion (lactate, 45.5; acetate, $24.1\;g\;kg^{-1}$ DM), and the addition of enzymes further enhanced the desirable fermentation (lactate, $57.5\;g\;kg^{-1}$ DM; acetate, $19.4\;g\;kg^{-1}$ DM). The content of NDF was lowered (p<0.05) by enzymes in both silages, but the extent appeared greater in the enzyme-treated rhodesgrass (rhodesgrass, $48\;g\;kg^{-1}$ DM; guineagrass, $21\;g\;kg^{-1}$ DM). Changes in the kinetics of in sacco degradation showed that enzyme treatment increased (p<0.01) the rapidly degradable DM (rhodesgrass, 299 vs. $362\;g\;kg^{-1}$ DM; guineagrass, 324 vs. $343\;g\;kg^{-1}$ DM) but did not influence the potential degradation, lag time and degradation rate of DM and NDF in the two silages.

Inference of Sequencing Batch Reactor Process using Oxidation Reduction Potential (ORP profile을 이용한 연속 회분식 반응기(Sequencing Batch Reactor)에서 무산소공정 추론)

  • Sim, Mun Yong;Bu, Gyeong Min;Im, Jeong Hun;U, Hye Jin;Kim, Chang Won
    • Journal of Environmental Science International
    • /
    • v.13 no.3
    • /
    • pp.245-250
    • /
    • 2004
  • The SBR(Sequencing Batch Reactor) process is ideally suited to treat high loading wastewater due to its high dilution rate. SBR operates by a cycle of periods consisting of filling, reacting, settling, decanting and idling. The react phases such as aeration or non-aeration, organic oxidation, nitrification, denitrification and other bio-logical reactions can be achieved in a reactor. Although the whole reactions can be achieved in a SBR with time distributing, it is hard to manage the SBR as a normal condition without recognizing a present state. The present state can be observed with nutrient sensors such as ${NH_{4}}^{+}-N$, ${NO_{2}}^{-}-N$, ${NO_{3}}^{-}-N} and ${PO_{4}}^{ 3-}-P.$ However, there is still a disadvantage to use the nutrient sensors because of their high expense and inconvenience to manage. Therefore, it is very useful to use common on-line sensors such as DO, ORP and pH, which are less expensive and more convient. Moreover, the present states and unexpected changes of SBR might be predicted by using of them. This study was conducted to get basic materials for making an inference of SBR process from ORP(oxidation reduction potential) of synthetic wastewater. The profiles of ORP, DO, and pH were under normal nitrification and denitrification were obtained to compare abnormal condition. And also, nitrite and nitrate accumulation were investigated during reaction of SBR. The bending point on ORP profile was not entirely in the low COD/NOx ratio condition. In this case, NOx was not entirely removed, and minimum ORP value was presented over -300mV. Under suitable COD/NOx ratio which complete denitrification was achieved, ORP bending point was observed and minimum ORP value was under -300m V. Under high COD/NOx ratio, ORP bending point was not detected at the first subcycle because of the fast denitrification and minimum ORP value was under -300mV at the time.

Nutrients and Suspended Organic Particulates in the Estuary of NakDong River (낙동강 하구수역의 영양염류와 유기현탁물질)

  • Choe, Sang;Chung Tai Wha
    • 한국해양학회지
    • /
    • v.7 no.1
    • /
    • pp.1-14
    • /
    • 1972
  • Seasonal changes in nutrients and suspended organic particulates were measured in the estuary of Nak-dong River in relation to the black laver bed. Monthly measurements of water temperature, pH, dissolved oxygen, nutrients ( $NH_4$-N, $NO_2$-N, $NO_3$\-N, $PO_4$-P and $SiO_2$-Si) and organic suspended particulates (organic carbon and nitrogen) were determined at five stations from February through December, 1970. PH varied 7.6-8.4 with an average of 8.0, and percent saturation of dissolved oxygen were 71-147% with an average of 100.8%. Studies gave evidence that Nak-dong River estuary is strongly enriched with nutrients. Concentrations of nutrients were: 0.13-12.54 ${\mu}g$-atoms/${\iota}$ (averaging 1.63 ${\mu}g$-atoms/${\iota}$) for $NH_4-N$, 0.12-2.09 ${\mu}g$-atoms/${\iota}$ (averaging 0.71 ${\mu}g$-atoms/${\iota}$) for $NO_2-N$, 3.46-56.79 ${\mu}g$-atoms/${\iota}$ (averaging 21.54 ${\mu}g$-atoms/${\iota}$) for $NO_3$-N, 4.04-57.90 ${\mu}g$-atoms/${\iota}$ (averaging 23.79 ${\mu}g$-atoms/${\iota}$) for total soluble nitrogen, 0.18-5.05 ${\mu}g$-atoms/${\iota}$ (averaging 0.96 ${\mu}g$-atoms/${\iota}$) for $PO_4$-P, and 18.33-133.29 ${\mu}g$-atoms/${\iota}$ (averaging 71.57 ${\mu}g$-atoms/${\iota}$) for $SiO_2$-Si, respectively. These nutrient levels were considerably higher compare with other productive laver beds of Wan do and Pyung-il Do in Korea or Ise Bay in Japan. Concentrations of suspended organic particulates varied 55-648 ${\mu}g/{\iota}$ (averaging 392 ${\mu}g/{\iota}$) with organic carbon, 30-155 ${\mu}g/{\iota}$ (averaging 92 ${\mu}g/{\iota}$) with organic nitrogen, and its carbon-nitrogen ratios were varied within 1.5-8.4 with an average of 4.6.

  • PDF

A Proposal of Sequencing the Combined Processes for Resources Recovery and Nitrogen Removal from Piggery Waste (슬러리형 돈사폐수에서 자원회수와 질소제거를 위한 순차적 결합공정 제안)

  • Hwang, In-Su;Min, Kyung-Sok;Bae, Jin-Yeon
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.28 no.1
    • /
    • pp.61-66
    • /
    • 2006
  • The combined ADEPT(Anaerobic Digestion Elutriated Phased Treatment)-SHARON(Single reactor system for High Ammonium Removal Over nitrite)-ANAMMOX(Anaerobic ammonium oxidation) processes were operated for resources recovery and nitrogen removal from slurry-type piggery waste. The ADEPT process operated at an acidogenic loading rates of 3.95 gSCOD/L-day, the SCOD elutriation rate and acid production rate were 5.3 gSCOD/L-day and 3.3 gVFAs(as COD)/L-day, respectively. VS reduction and SCOD reduction by the hydrolysis were 13% and 0.19 $gSCOD_{prod.}/gVS_{feeding}$, respcetively. Also, the acid production rate was 0.80 $gVFAs/gSCOD_{prod}$. In methanogenic reactor, the gas production rate and methane content were 2.8 L/day($0.3m^3CH_4/kgCOD_{removal}@STP$) and 77%, respectively. With these operating condition, the removals of nitrogen and phosphorus were 94.1% as $NH_4-N$(86.5% as TKN) and 87.3% as T-P respectively.

Physico-Chemical Environment and Productivity of the Phytoplankton Community in the Jido Pond Ecosystem (지도지생태계의 물리화학적환경과 식물성 플랭크톤군집의 생산성)

  • Song Seung-Dal;M. Anwarul Huque
    • Journal of environmental and Sanitary engineering
    • /
    • v.5 no.2
    • /
    • pp.117-122
    • /
    • 1990
  • The Jido Pond system was investigated from April, 1979 through March, 1980, in respect of seasonal changes in physico-chemical factors: i.e., temperature, pH, DO, BOD, COD, $Cl^-, \; Mg^{++}$, alkalinity, detergent, $SiO_2, PO_4\;^{3-}, NH_4\;^+, NO_2\;^-, NO_3\;^-$, total N, OM and OC; phytoplankton community growth; and the ecosystem metabolism. The phytoplankton community was represented by 23 species belonging to Chlorophyta, Bacillariophyta and Cyanophyta; each sharing 11, 9 3 respectively. The Chlorophyceans dominated the phytoplankton community contributing 75% of the total ?미 counts. The ranges of biotic diversity indices were, d, 0.85~2.80; H, 1.10~2.40; c, 0.13~0/40; and 3, 0.56~0.90. The chlorophyll standing crop varied in between 0.043 and 0.385g/$\textrm{cm}^2$ surface area. The ranges of photosynthetic and respiratory rates were 0.36~4.50; and 0.10~1.40 $O_2$ mg/1/hr, respectively. The monthly areal net primary production varied from 23.9 to 305.1C g/$\textrm{m}^2$/month. The Eu of the net production seasonally varied in between 0.31 and 7.80%, and the annual mean was 2.44%. The annual turnover times of phosphorus and nitrogen were 20 and 3 days, respectively.

  • PDF

Application of upflow multi-layer bioreactor (UMBR) for domestic wastewater treatment in HCMC

  • Cao, Duc Hung;Nguyen, Ngoc Han;Nguyen, Phuoc Dan;Bui, Xuan Thanh;Kwon, J.C.;Shin, H.S.;Lee, E.T.
    • Membrane and Water Treatment
    • /
    • v.3 no.2
    • /
    • pp.113-121
    • /
    • 2012
  • Up-flow multi-layer bioreactor (UMBR) is a hybrid system using dual sludge that consists of an up-flow multi-layer bioreactor as anaerobic/anoxic suspended growth microorganisms followed by an aeration tank. The UMBR acts as a primary settling tank, anaerobic/anoxic reactor, thickener which requires low energy due to mixing by up-flow stream. This study focused on using a pilot UMBR plant with capacity of 20-30 $m^3$/day for domestic wastewater in HCMC. HRTs of UMBR and aeration tank were 4.8 h and 7.2 h, respectively. The average MLSS of UMBR ranged from 10,000-13,600 mg/l SS. Internal recycle rate and sludge return were 200-300% and 150-200%, respectively. The results obtained from this study at flow rate of 20 $m^3$/day showed that removal of COD, SS, TKN, N-$NH_4$, T-N, and color were 91%, 87%, 86%, 80%, 91% and 91%, respectively.