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Characterization of saturation of CR-39 detector at high alpha-particle fluence

  • Ghazaly, M. El;Hassan, Nabil M.
    • Nuclear Engineering and Technology
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    • v.50 no.3
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    • pp.432-438
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    • 2018
  • The occurrence of saturation in the CR-39 detector reduces and limits its detection dynamic range; nevertheless, this range could be extended using spectroscopic techniques and by measuring the net bulk rate of the saturated CR-39 detector surface. CR-39 detectors were irradiated by 1.5 MeV high alpha-particle fluence varying from $0.06{\times}10^8$ to $7.36{\times}10^8\;alphas/cm^2$ from Am-241 source; thereafter, they were etched in a 6.25N NaOH solution at a temperature of $70^{\circ}C$ for different durations. Net bulk etch rate measurement of the 1.5 MeV alpha-irradiated CR-39 detector surface revealed that rate increases with increasing etching time and reaches its maximum value at the end of the alpha-particle range. It is also correlated with the alpha-particle fluence. The measurements of UV-Visible (UV-Vis) absorbance at 500 and 600 nm reveal that the absorbance is linearly correlated with the fluence of alpha particles at the etching times of 2 and 4 hour. For extended etching times of 6, 10, and 14.5 hour, the absorbance is saturated for fluence values of $4.05{\times}10^8$, $5.30{\times}10^8$, and $7.36{\times}10^8\;alphas/cm^2$. These new methods pave the way to extend the dynamic range of polymer-based solid state nuclear track detectors (SSNTDs) in measurement of high fluence of heavy ions as well as in radiation dosimetry.

Shell Valve Movement of Pacific Oysters, Crassostrea gigas, in Response to Low Salinity Water (저염수에서 이매패류 참굴(Crassostrea gigas)의 패각운동)

  • Moon, Suyeon;Oh, Seok Jin
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.23 no.6
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    • pp.684-689
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    • 2017
  • We examined the possibility of developing an early monitoring system using the shell valve movement activity of Pacific oyster (Crassostrea gigas) for early detection of low salinity water in coastal areas. At salinity levels of 30 psu and 20 psu, SVMs were detected $7.32{\pm}3.21times/hr$ and $7.11{\pm}3.90times/hr$, respectively, The patterns and times of SVMs were not significantly different between the two experiment phases. However, at 10 psu and 5 psu, shell valves were observed to be permanently closed in all experiments. Under combined condition (Group 1: temperature $15^{\circ}C$ ${\times}$ salinity 15 psu), SVMs were observed from 20 psu to 30 psu over a 2 - 3 hr period, and then remained closed. In Group 2 (temperature $30^{\circ}C$ ${\times}$ salinity 15 psu), SVMs were observed, which indicated that the physiological condition of the oysters reached a critical point. Thus, it may be possible to utilize SVMs as an early warning signal for low salinity water.

The Effect of Change in Moisture Content on Some Physical Properties of Grains (I) -Spericity, Weight, Volume- (含水率變化가 穀物의 物理的 特性에 미치는 影響(I) -球形率, 重量, 體積-)

  • Oh, Moo-Young
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.26 no.2
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    • pp.59-68
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    • 1984
  • The Purpose of this study was to investigate the effect of the change in misture content on some physical properties of grains, and some relations amont the properties. Materials included ere rough rice, brown rice, barley and wheat with the range of moisture content of 6~26 percent, 7~25 percent, 10~24 percent and 6~22 percent, respectively. Kernel dimension, sphericity, kernel weight, and volume were included as the physical properties of the grains. The results obtained are summarized as follows; 1. The ratio of grain length to the thickness was in the range of 3.59~4.16 for rough rice(Indica type), 2.98~3.27 for rough rice(Japonica type), 3.25 for brown rice (I.T.), 2.14~2.38 for brown rice(J.T.), 2.92~3.13 for barley and 2.10~2.21 for wheat, respectively. 2. The sphericity was found to be 42 percent for rough rice(I.T.), 48 percent for rough rice(J.T.), 52 percent for brown rice(I.T.), 62 percent for brown rice(J.T.), 45 percent for barley and 61 percent for wheat, respectively. 3. The kernel weight of grains was linealy increased with the increase of moisture content. At a specified moisture centent of 14 percent, the kernel weight was shown to be in the range of 4.72${\times}10^{-5}$~3.58${\times}10^{-5}$kg for wheat, 3.60${\times}10^{-5}$~3.12${\times}10^{-5}$kg for barley, 2.80${\times}10^{-5}$~2.35${\times}10^{-5}$kg for rough rice, and 2.24${\times}10^{-5}$~1.82${\times}10^{-5}$kg for brown rice, respectively. 4. The kernel volume was linearly increased with increase of moisture content. The rate of increase was significantly low for rough rice in comparison with the remaining grains. The kernel volume, at a specified moisture content of 14 percent, was in the range of 3.51${\times}10^{-8}$~2.76${\times}10^{-8}m^3$ for wheat, 2.84${\times}10^{-8}$~2.43${\times}10^{-8}m^3$ for barley, 2.93${\times}10^{-8}$~1.97${\times}10^{-8}m^3$ for rough rice, and 1.61${\times}10^{-8}$~1.29${\times}10^{-8}m^3$ for brown rice, respectively. 5. The kernel volume of grains was found to be related to the length, width, thickness and kernel weight as a exponential function. The kernel volume was shown to have correlation coefficient to the length factor rough rice and barley which were of low sphericity, while the width factor was predominant for brown rice and wheat which was of high sphericity.

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Oxidation Reaction of Hydrazobenzene by Activated Catalysts of Oxygen Adducted Tetradentate Schiff Base Cobalt(Ⅱ) Complexes in Methanol Solvent. (Ⅱ) (메탄올 용매에서 산소 첨가된 네자리 Schiff Base Cobalt(II) 착물들의 활성촉매에 의한 Hydrazobenzene의 산화반응 (제 2 보))

  • Ki-Kyung Chjo;Yong-Kook Choi;Sang-Bock Kim;Jong-Ki Park;Dong-Hwa Park
    • Journal of the Korean Chemical Society
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    • v.36 no.6
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    • pp.894-905
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    • 1992
  • Dioxygen binding and homogeneous catalytic oxidation of hydrazobenzene were investigated by employing tetradentate Schiff base Cobalt(II) complexes such as Co(II)(SED)$(Py)_2$, Co(II)(SOPD)$(Py)_2$ and Co(II)(SND)$(Py)_2$ in saturated oxygen methanol solvent. The major product of hydrazobenzene ($H_2$AB) oxidation by catalysts of superoxo type [Co(III)(SED)(Py)$O_2$] and [Co(III)(SOPD)(Py)$O_2$] complexes are trans-azobenzene (t-AB) and rate constants k for oxidation reaction was 7.692 ${\times}$ $10^{-2}$ M/sec for [Co(III)(SED)(Py)$O_2$] and 5.076 ${\times}$ $10^{-2}$ M/sec for [Co(III)(SOPD)(Py)$O_2$]. But cis-azobenzene (c-AB) are obtained as a major product with ${\mu}$-peroxo type [Co(III)(SED)(Py)]$_2O_2$ catalyst, and rate constant k is 1.266 ${\times}$ $10^{-2}$ M/sec. The rate constants of oxidation reaction has been studied spectrophotometrically and the rate law established. A mechanism involving a intermediate activated complexes of catalyst, hydrazobenzene and oxygen has been proposed. $H_2$AB + Co(II)(Schiff base)$(Py)_2$ + $O_2$ ${\rightleftharpoons}_{MeOH}^K$ Co(III)(Schiff base)(Py)$O_2$${\cdot}$$H_2$AB + Py $\longrightarrow^k$ Co(II)(Schiff base)$(Py)_2$ + t-AB + $H_2O_2$(Scchiff base : SED and SOPD). $H_2$AB + 2Co(II)(SND)$(Py)_2$ + $O_2$ ${\rightleftharpoons}_{MeOH}^K$ [Co(III)(SND)(Py)]$_2O_2$${\cdot}$H_2$AB + 2Py ${\longrightarrow}^k$ (Co(II)(SND)$(Py)_2$ + c-AB + $H_2O_2$.

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$H_2S$ Adsorption Characteristics and Property Analyses of Activated Carbon Adsorbent Impregnated with Basic Solutions (염기성용액으로 첨착시킨 활성탄의 물성분석 및 $H_2S$ 흡착특성)

  • Lee, Suk-Ki;Yim, Chang-Sun;Park, Yeong-Seong
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.11
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    • pp.1011-1016
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    • 2010
  • The $H_2S$ adsorption characteristics and property analyses of granular activated carbon adsorbent impregnated with basic solution such as NaOH, KOH, and $(CH_2CH_2OH)_2NH$ were investigated. The concentrations of NaOH and KOH reagent ranged over 1 to 5 M, The concentration of $(CH_2CH_2OH)_2NH$ was in the range of 0.1 to 1 M. Adsorption temperature($25{\sim}45^{\circ}C$) and adsorbate ($H_2S$) concentration (18.23 mg/L) were applied. The experimental results showed that the BET surface area of activated carbon impregnated with KOH decreases from $1,050\;m^2/g$ to $750\;m^2/g$, and the acidity of activated carbon impregnated with NaOH decreases from 0.541 meq/g-AC to 0 meq/g-AC, as the concentration of basic solution increases, while the pH of impregnated activated carbon increased from 9.54 to 10.94 for three basic solutions. It was also found that the $H_2S$ adsorption equilibrium capacity of activated carbon impregnated with NaOH, KOH, $(CH_2CH_2OH)_2NH$ increased with increasing temperature and $H_2S$ adsorption equilibrium capacity of the activated carbon impregnated with diethanolamine was much higher than other cases. At adsorption temperature of $45^{\circ}C$, the $H_2S$ adsorption equilibrium capacity of impregnated activated carbon was 2.0~3.3 times lager than that of pure activated carbon.

Analysis of General Ingredient and Amino Acid Contents in Silkworm Feces with Different Extracting Methods and Collecting Time (추출 방법 및 채취 시기를 달리한 잠분추출물의 일반성분 및 아미노산 함량 분석)

  • Sohn, Bong-Hee;Chung, Wan-Tae;Kang, Pil-Don;Ryu, Kang-Sun;Jung, I-Yeon;Kim, Yong-Soon;Kim, Kee-Young;Kim, Mi-Ja;Chung, In-Sick
    • Journal of Sericultural and Entomological Science
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    • v.49 no.2
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    • pp.43-46
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    • 2007
  • Analysis of general ingredients and amino acid content in dried silkworm feces which were extracted with hot water, EtOH, MeOH for developing new income source of rearing farm, seeking high additive value material and industrialization of silkworm feces. In the analysis of general ingredient content by extracting solution, raw protein and ash contents were increased with MeOH, EtOH, hot water. And raw fat showed higher contents by the order of EtOH > MeOH > hot water. The inorganic matter content showed a little difference among collection times of silkworm feces. Hot water was most effective extracting solution for total amino acid, and no significant difference between EtOH and MeOH. According to the time, there were no significant difference in amino acid contents. When extracted with hot water, Glu content was highest content and order of others is Asp > Gly > Ala > Leu > Thr > Ser among 18 amino acids.

Characteristics of Anion Exchange Measured by the Rate of Hemolysis in Human Erythrocyte (사람의 적혈구에서 용혈성을 이용하여 측정한 음이온 교환특성)

  • Woo, Jae-Suk;Kim, Yong-Keun;Hwang, Il-Yong
    • The Korean Journal of Physiology
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    • v.20 no.2
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    • pp.218-224
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    • 1986
  • The characteristics of anion exchange with internal $HCO_3\;^{-}\;(or\;OH^-)$ was studied by determining the time course of hemolysis in isoosmotic ammonium salt solution in human erythrocytes. The effects of inhibitors, pH and temperature on the exchange between internal $HCO_3\;^-\;(or\;OH^-)$ and external $Cl^-$ were observed and the permeabilities of various organic and inorganic anions were also measured. The results were compared with data previously reported from the experiments using radioisotopes. The results are as follows; 1) SITS $H_2DIDS$ and furosemide inhibited the hemolysis of erythrocytes in isoosmotic $NH_4Cl$ solution in a dose·dependent manner, and the concentrations for lengthening twice the time for $half-hemloysis(t_{1/2})\;were\;2.3{\times}10^{-7},\;1.3{\times}10^{-7}\;and\;2.5{\times}10^{-5}M$, respectively. 2) Acetazolamide also shifted the time-dependent hemolytic curve to the right in a dose-dependent manner, and the concentrations for lengthening twice $t_{1/2}\;was\;2.4{\times}10^{-5}M$. 3) The time-dependent hemolysis was delayed by decreasing pH from 7.0 to 6.2, but w·as not affected by the change of pH in the range of 7.0 to 8.2. 4) The time for $half-hemloysis(t_{1/2})$ showed a temperature-dependency and Arrhenius plot exhibited a break point at $20^{\circ}C$. The apparent activation energy calculated from this plot was 18.1 kcal/mol between $2^{\circ}C-20^{\circ}C$ and 11.2 kcal/mol between $20^{\circ}C-37^{\circ}C$, respectively. 5) The apparent permeabilities of various inorganic anions based on $t_{1/2}$ were in the order of $Cl^->NO_{3}\;^->SCN^->SO_4\;^{2-}>SSO_3\;^{2-}>HPO_4\;^{2-}$. which was similar with the previous reports based on the experiment using radioisotopes. The results Obtained from this study are comparable with the previous data reported from the experiments using radioisotopes. This indicates that the hemolysis of erythrocytes in isoosmotic ammonium salt solution can be used as a simple and good method for the study of anion exchange in erythrocyte membrane.

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Influence of Food Allowance on Nutrient Utilization of Oat (Avena sativa) Hay by Goats and Feeding Value of Leftovers from High Levels of Offer in Sheep

  • Dutta, N.;Sharma, K.;Hasan, Q.Z.;Pathak, N.N.
    • Asian-Australasian Journal of Animal Sciences
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    • v.12 no.5
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    • pp.723-727
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    • 1999
  • Two experiments were conducted to determine the effect of feeding levels on intake and nutrient utilization of oat (Avena sativa) hay (OH) by goats and potential feeding value of leftovers from high levels of offer in sheep. In experiment 1, the goats (15) were offered OH at three levels of feeding to give leftovers of about 20% (T-1), 35% (T-2) and 50% (T-3) of DM offered. A marked effect of refusal rate of OH on intake and digestibility of nutrients was evident. Allowing selective consumption at higher levels (T-2 and T-3), the intake of DCP and TDN from OH was found not only to meet the maintenance requirement but provided surplus nutrients for moderate production. In experiment 2, Sheep (3) were offered one of the three dietary treatments viz OH, refusals left uneaten by goats in T-2 and T-3 (OHR) and 3% urea treated oat hay refusals (UTR) in a $3{\times}3$ latin square design. Though the potential feeding value of leftovers (OHR and UTR) was lower than OH, the results confirm the possibility of their effective use. It was concluded that feeding above the conventional ad libitum level could be an alternative to improve the performance of ruminants fed feeds like oat hay. The potential impact of the strategy would, however, depend on the effective reutilization of leftovers for feeding other animals.

The Surface Morphology and Characteristics of Poly (ethylene Terephthalate) Film (Poly(ethylene Terephthalate) 필름의 표면모폴로지와 표면특성)

  • Kang, In-Sook;Mun, Mi-Hwa;Rha, Jong-Joo
    • Journal of the Korean Society of Clothing and Textiles
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    • v.34 no.11
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    • pp.1880-1888
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    • 2010
  • This study was a preliminary investigation of the influence of surface characteristics of substrates on the detergency of particulate soil. A PET film was surface modified with NaOH and DMF for different times. The surface morphology of the film was scanned by AFM and the surface energies were calculated from the measured contact angles between several solutions and film based on a geometric mean and the Lewis acid base method. The surface morphology of the PET film treated with NaOH and DMF became more etched and swelled with an increased treatment time, respectively. The surface roughness and surface area of film treated with NaOH enlarged with increased treatment time. However, the coefficient of friction of film treated with NaOH and coefficient of friction, surface roughness, and surface area of film treated with DMF increased and then decreased with increased treatment time. The contact angle of film treated with DMF decreased with increased treatment time in water and surfactant solution; however, the effect of treatment time on the contact angle was different in both solutions for film treated with NaOH. By the treatment of PET film with NaOH and DMF, the polar group of the surface energy increased and the nonpolar group decreased; however, the change of total surface energy was not significant.

Gas Sensing Characteristics and Preparation of SnO2 Nano Powders (SnO2 나노 분말의 합성 및 가스 감응 특성)

  • Lee, Ji-Young;Yu, Yoon-Sic;Yu, Il
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.7
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    • pp.589-593
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    • 2011
  • [ $SnO_2$ ]nano powders were prepared by solution reduction method using tin chloride($SnCl_2{\cdot}2H_2O$), hydrazine($N_2H_4$) and NaOH. The $SnO_2$ thick films for gas sensors were fabricated by screen printing method on alumina substrates and annealed at $300^{\circ}C$ in air, respectively. XRD patterns of the $SnO_2$ nano powders showed the tetragonal structure with (110) dominant orientation. The particle size of $SnO_2$ nano powders at the ratio of $SnCl_2:N_2H_4$+NaOH= 1:6 was about 60 nm. The sensing characteristics were investigated by measuring the electrical resistance of each sensor in a test box. Sensitivity of $SnO_2$ gas sensor to 5 ppm $CH_4$gas and 5 ppm $CH_3CH_2CH_3$ gas was investigated for various $SnCl_2:N_2H_4$+NaOH proportion. The highest sensitivity to $CH_4$ gas and $CH_3CH_2CH_3$ gas of $SnO_2$ sensors was observed at the $SnCl_2:N_2H_4$+NaOH= 1:8 and $SnCl_2:N_2H_4$+NaOH= 1:6, respectively. Response and recovery times of $SnO_2$ gas sensors prepared by $SnCl_2:N_2H_4$+NaOH= 1:6 was about 40 s and 30 s, respectively.