• Title/Summary/Keyword: "S" modifier

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Direct Determination Method of Antimony in High Purity Copper Metal by Graphite Furnace Atomic Absorption Spectrometry (흑연로 원자 흡수흡광법에 의한 고순도 구리 합금중의 안티몬의 직접 분석 방법)

  • Yoo, K.S;Kyung, J.D;Kwon, J.G;Lee, J.J
    • Journal of the Korean Chemical Society
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    • v.39 no.4
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    • pp.252-256
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    • 1995
  • A study was carried out for the development of direct determination of antimony in high purity copper metal without preseparation. The large excess of copper seemed to be performed as the matrix modifier to enhance the absorbance of antimony in copper metal. Sensitivity enhancement of Sb was obtained at the condition of the ashing temperature of $600^{\circ}C(20s){\sim}700^{\circ}C(10s)$ rather than $1000^{\circ}C(20s){\sim}1100^{\circ}C(10s)$, and the atomization temperature of $2200^{\circ}C.$ The operating pressure of argon gas was readjusted to the optimum condition at 2.0 kg/$cm^2.$ The linearity of the Sb calibration graph could be obtained in the range of 20 ppb up to 200 ppb Sb in existence of 5,000 ppm Cu with the coefficient of variation of about 5%.

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Matrix Modification for Graphite Furnace Atomic Absorption Spectrophotometric Determination of Volatile Elements (Ⅰ). Determination of Trace Lead by Graphite Furnace Atomization (휘발성 원소들의 원자흡수 분광분석을 위한 매트릭스 개선에 관한 연구 (제 1 보). 흑연로 원자화에 의한 흔적량 납의 정량)

  • Choi, Jong Moon;Choi, Ho Sung;Kim, Young Sang
    • Journal of the Korean Chemical Society
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    • v.39 no.3
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    • pp.204-212
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    • 1995
  • The graphite furnace atomic absorption spectrophotometric determination of trace lead in water samples was studied using matrix modifiers. In order to modify the sample matrix, the type and optimum amount of the modifier were investigated with a given concentration of Pb solution. In fact, if the matrix is not modified, lead has low ashing and atomization temperatures as to give a low absorbance with bad reproducibility because of its volatility. Therefore, optimum modifiers should be used to stabilize the atomization. In this work, the ashing and atomization temperatures were raised from 400 and $1800^{\circ}C$, to 1,000 and $2000^{\circ}C$, by the addition of palladium to 50 ng/mL lead solution as a modifier. The concentration of palladium was 5.0 ${\mu}g/mL$ in the modified solution. Furthermore, if 1.5 ${\mu}g/mL$ of aluminum was mixed with the palladium modifier as an auxiliary modifier, the ashing temperature could be increased $150^{\circ}C$ additionally. With such a treatment, the sensitivity was improved more than 5 times of the solution unmodified and the reproducible results of less than 5% RSD were obtained in the samples of university's waste water and pipe-washing tap water. It could be concluded that this procedure was quantitative in the determination of trace lead from the recoveries of more than 88% obtained in the samples in which a given amount of lead was spiked.

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Properties of Polymer Cement Mortar Based on Styrene-Butyl Acrylate according to Emulsifier and Monomer Ratios (유화제 및 단량체비에 따른 스티렌-부틸 아크릴레이트계 폴리머 시멘트 모르타르의 특성)

  • Jo, Youngkug;Hyung, Wongil
    • Polymer(Korea)
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    • v.37 no.2
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    • pp.148-155
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    • 2013
  • The purpose of this study is to clarify the effect of the emulsifier ratio on the properties of the polymer cement mortars based on styrene-butyl acrylate (S/BA) latexes, and to obtain necessary basic data to develop appropriate latexes for cement modifiers. The polymer dispersions for cement modifiers was synthesized using styrene and butyl acrylate. Polymer cement mortars based on S/BA latexes were prepared with various monomer and emulsifier ratios, and their water-cement ratio, air content, flexural and compressive strengths, water absorption and chloride ion penetration were tested. From the test results, the maximum flexural and compressive strengths of polymer cement mortars based on S/BA latexes were obtained at a bound styrene content of 60% and an emulsifier ratio of 6%. Also, the water absorption and chloride ion penetration depth are greatly affected by the polymer-cement ratio rather than the bound styrene and emulsifier content. Accordingly, it is judged that S/BA latexes can be used place of the conventional polymer dispersions of cement modifier.

Signaling Interface of Advanced Glycation Endproducts Receptor and Ubiquitin-Conjugating Enzyme Ubc9 Complex in Atherosclerosis and Cancer Cells

  • Kim, June Hyun
    • Interdisciplinary Bio Central
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    • v.4 no.4
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    • pp.13.1-13.6
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    • 2012
  • The advanced glycation endproducts receptor (AGER) is a multiligand signal transduction receptor. One of its ligands, S100b molecules activates vascular smooth muscle cells and endothelial cells via its receptor, thus triggering activation of signaling cascades and generation of cytokines and proinflammatory molecules. Ubiquitin-conjugating enzyme Ubc9 is an E2 conjugating enzyme that transfers the activated small ubiquitin-related modifier to protein substrates, and thus it plays a critical role in SUR-Mylation-mediated cellular pathways. Previous studies have shown that both AGE-R and Ubc9 play roles in diverse cellular signaling pathways. However, until recently, little attention has been paid to interactions between AGE-R and Ubc9. In this study, sequence database searches allowed us to identify a potential interaction motif between AGE-R and Ubc9. The subsequent biochemical and molecular biological analysis suggested that there may be specificity in AGE-R and Ubc9 complex signaling in atherosclerosis and cancer cells in a cell-type specific manner. Although the determinant for specificity in AGE-R and Ubc9 complex signaling in cancer cells and atherosclerosis is yet to be determined, this study provides the basis to develop a specific therapeutic application of AGE-R, SURM (small ubiquitin-related modifier)-1, and Ubc9 complex activation pathways in atherosclerosis, diabetes, cancer and inflammatory diseases.

The Study on Prepare Water Proof Agent by Acryl Copolymer and Oleic Acid Mixed Emulison (아세트화 아크릴 공중합체-올레인산 혼합 에멀젼계 방수제 제조연구)

  • Kim, Young-Geun;Hwang, Yong-Hyun
    • Journal of the Korean Applied Science and Technology
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    • v.13 no.3
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    • pp.83-94
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    • 1996
  • EMA-co-DAMA were synthesized from 2-diethylaminoethyl metacrylate and ethylhexyl metacrylate in acrylmonomer. To facilitate water emulsification, acrylic copolymer was cationized by acetic acid to produce acetated acrylic copolymer. The structures of the synthesized copolymer and acetated copolymers were confirmed by IR, NMR, and molecular weight was measure by GPC, and C.H.N elemental analysis. Acetated acrylic copolymers were perfectly emulsified in water and showed increased emulsion stability. Polymer dispersion for cement modifier[(PDCM-PED) water proof agent of cement for concrete in building construction] was prepared by blending of the guaternized acrylic copolymer syndisized above, sodium silicate, sodium gluconate and oleic acid emulsion. The result with prepared polymer dispersion of cement modifier was examined, and it was found that excellent waterprooffing effect ; Water permeability ratio is 0.50 under the water pressure of $100g/cm^2$ and 0.60 under $3kg/cm^2$, and water absorption ratio is $0.42{\sim}0.50$ and $1.0{\sim}1.02$ compressive strength ratio at mixed of water/PDCM-PED is 50 times.

CFD Simulation of NACA 2412 airfoil with new cavity shapes

  • Merryisha, Samuel;Rajendran, Parvathy;Khan, Sher Afghan
    • Advances in aircraft and spacecraft science
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    • v.9 no.2
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    • pp.131-148
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    • 2022
  • The paper presents the surface-modified NACA 2412 airfoil performance with variable cavity characteristics such as size, shape and orientation, by numerically investigated with the pre-validation study. The study attempts to improve the airfoil aerodynamic performance at 30 m/s with a variable angle of attack (AOA) ranging from 0° to 20° under Reynolds number (Re) 4.4×105. Through passive surface control techniques, a boundary layer control strategy has been enhanced to improve flow performance. An intense background survey has been carried out over the modifier orientation, shape, and numbers to differentiate the sub-critical and post-critical flow regimes. The wall-bounded flows along with its governing equations are investigated using Reynolds Average Navier Strokes (RANS) solver coupled with one-equational transport Spalart Allmaras model. It was observed that the aerodynamic efficiency of cavity airfoil had been improved by enhancing maximum lift to drag ratio ((l/d) max) with delayed flow separation by keeping the flow attached beyond 0.25C even at a higher angle of attack. Detailed investigation on the cavity distribution pattern reveals that cavity depth and width are essential in degrading the early flow separation characteristics. In this study, overall general performance comparison, all the cavity airfoil models have delayed stalling compared to the original airfoil.

The Bioinformatics and Molecular Biology Approaches for Vascular Cell Signaling by Advanced Glycation Endproducts Receptor and Small Ubiquitin-Related Modifier

  • Kim, June Hyun
    • Interdisciplinary Bio Central
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    • v.4 no.4
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    • pp.12.1-12.6
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    • 2012
  • The advanced glycation endproducts receptor (AGE-R) is a signal transduction receptor for multiligand such as S100b and AGEs. S100b has been demonstrated to activate various cells with important links to atherosclerosis initiation and progression including endothelial cells, and smooth muscle cells via AGE-R, triggering activation of multiple signaling cascades through its cytoplasmic domain. Many studies have suggested AGE-R might even participate in the cardiovascular complications involved in the pathogenesis of type I diabetes. Recently, Small Ubiquitin-Related Modifier 1 (SURM-1 also known as SUMO-1) has been recognized as a protein that plays an important role in cellular post-translational modifications in a variety of cellular processes, such as transport, transcriptional, apoptosis and stability. Computer Database search with SUMOplot Analysis program identified the five potential SURMylation sites in human AGE-R: K43, K44, K123, and K273 reside within the extracellular domain of AGE-R, and lastly K374 resides with the cytosolic domain of AGE-R. The presence of the consensus yKXE motif in the AGE-R strongly suggests that AGE-R may be regulated by SURMylation process. To test this, we decided to determine if AGE-R is SURMylated in living vascular cell system. S100b-stimulated murine aortic vascular smooth muscle cells were used for western blot analysis with relevant antibodies. Taken together, bioinformatics database search and molecular biological approaches suggested AGE-R is SURMylated in living cardiovascular cell system. Whilst SURMylation and AGE-R undoubtedly plays an important role in the cardiovascular biology, it remains unclear as to the exact nature of this contribution under both physiological and pathological conditions.

A Method Detecting the Phrase and Clause in Korean (한국어에서 구절의 검출 방법)

  • Lee, J.H.;Choi, J.S.;Lee, D.H.;Lee, J.K.
    • Proceedings of the KIEE Conference
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    • 1987.07b
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    • pp.1097-1099
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    • 1987
  • This paper describes a method which detects the phrase and clause in Korean sentences. By analysing modificatory relation of modifier and modified word in Korean, two rules are defined. (1) The rules of phrase and clause. (2) The rules of separation points. As the result of this method, the conceptual units are easily elicited from the Korean sentence.

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Fiber Optic Engine for Full Color Mobile Display

  • Arabi, H.;An, S.;Oh, K.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.400-401
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    • 2009
  • In this paper we report a micro projector including of RGB sources, a $3{\times}1$ Fiber Optic Color Synthesizer (FOCS), and a two dimensional micro mechanical scanning mirror. We further report a modifier micro collimator which can enhance the resolution of the screened image.

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Analysis of Lead in Blood using SR(self-reversal) and $D_2$ Arc Background Correction Methods (SR 바탕보정법과 $D_2$ 바탕보정법에 의한 혈액 중 Pb 분석)

  • Lee, Seokki;Kim, Poongzag
    • Analytical Science and Technology
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    • v.7 no.4
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    • pp.427-434
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    • 1994
  • For the analysis of the relatively volatile lead in blood by GFAAS(graphite furnace atomic absorption spectrophotometer), one can not raise the ashing temperature beyond certain degree due to the elevation of the baseline. Previous investigations showed that background is stabilized when the ashing temperature is raised to $700^{\circ}C$ using a matrix modifier. In this study, same result was obtained at the ashing temperature of around $550^{\circ}C$ even when the matrix modifier is not used and only Triton X-100 is used as a diluent, on an instrument which is equipped with both temperature and current controller(Shimadzu, AA-6501S) and thus the temperature control is fast and accurate. Background correction methods of $D_2$ arc and SR(self reversal) were reviewed. The results show that the absorbance is higher for the $D_2$ arc method, but the background correction is higher for the SR method.

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