Browse > Article

Comparison of Multi-element Extraction Methods to Determine Available Phosphate and Exchangeable Cations of Korean Soils  

Kim, Myung-Sook (National Academy of Agricultural Science)
Yang, Jae Eui (Division of Biological Environment, Kangwon National University)
Kim, Yoo-hak (National Academy of Agricultural Science)
Yoon, Jung-Hui (Daejeon Agricultural Technology Center)
Zhang, Yong-Seon (National Academy of Agricultural Science)
Kwak, Han-Gang (Rural Development Administration)
Ha, Sang-Keon (National Academy of Agricultural Science)
Hyun, Byung-Keun (National Academy of Agricultural Science)
Publication Information
Korean Journal of Soil Science and Fertilizer / v.42, no.3, 2009 , pp. 192-200 More about this Journal
Abstract
Soil testing is one of the best management practices for sustainable agriculture. Recently, as increasing soil testing needs, simplification of soil analytical procedure has been required. To determine recommendable multi-element extractant, the soil testing results of available phosphate and exchangeable cations between the conventional methods (Lancaster and 1M $NH_4OAc) and multi-element extraction methods such as Mehlich III, Modified Morgan and Kelowna methods were compared. There were highly significant correlation between the conventional methods and multi-element extraction methods (Mehlich III, Modified Morgan and Kelowna) for available phosphate and exchangeable K, Ca, Mg and Na. The coefficients of determination ($R^2) between available phosphate extracted by Lancaster method and multielement extraction methods were in the order of Mehlich III ($0.979^{***}$) > Kelowna ($0.977^{***}$) > Modified(Mod.). Morgan ($0.553^{***}$). For exchangeable cations, there were highly significant correlations between 1M $NH_4OAc method and Mehlich III, Mod. Morgan and Kelowna. However, exchangeable K, Ca and Mg by Mehlich III method were more highly correlated with conventional method than other methods. Therefore, Mehlich III extraction method could be recommended as a single extractant for simultaneous measurement using ICP in the analysis of avaliable phosphate and exchangeable cations.
Keywords
Multi-element extraction; ICP; Available phosphate; Exchangeable cations; Soil;
Citations & Related Records
연도 인용수 순위
  • Reference
1 Elrashidi, M. A., M. D. Mays, and C. W. Lee. 2003. Assessment of Mehlich 3 and Ammonium Bicarbonate-DTPA Extraction for Simultaneous Measurement of Fifteen Elements in Soil. Commun. Soil Sci. Plant Anal. 34(19&20):2817-2838   DOI   ScienceOn
2 Jung, W. K. and Y. H. Kim. 2006. Soil organic carbon determination for calcareous soils. Korean J. Soil Sci. Fert. 39(6):396-401
3 Ketterings, Q. M. and M. Flock. 2005. Comparison of Bray-1 and Mehich-3 tests in high phosphorus soils. Soil Science 170(3):212-219   DOI   ScienceOn
4 Macaulay Institute for Soil Research and Scottish Agricultural Colleges Group. 1984. Advisory soil Analysis and Interpretation. Bulletin 1. Aberdeen, Scotland
5 Mallarino, A. P. 2002. Field calibration for corn for the Mehlich-3 soil phosphorus test with colorimetric and inductively coupled plasma emission spectroscopy determination methods. Soil Sci. Soc. Am. J. 68:1928-1934
6 Mehich, A. 1978. Influence for fluoride, sulfate and acidity on extractable phosphorus, calcium, magnesium and potassium. Commun. In Soil Sci. Plant Anal. 9(6):455-476   DOI
7 Nathan, M. V., A. Mallarino, R. Elliason, and R. Miller. 2002. ICP vs. Colorimetric determination of Mehlich Ⅲ extractable phosphorus. Commun. Soil Sci. Plant Anal. 33:2432-2433
8 Pittman, J. J., H. Zhang, and J. L. Schroder. 2005. Difference of phosphorus inMehlich 3 extracts determined by colorimetirc and spectroscopic methods. Commun. In Soil Sci. Plant Anal. 36:1641-1659   DOI   ScienceOn
9 Van Lierop, W. 1988. Determination of available phosphorus in acid and calcareous soils with the Kelowna multi-element extractant. Soil Science 146(4):284-291   DOI
10 Van Lierop, W., and N. A. Gough. 1989. Extraction of potassium and sodium from acid and calcareous soils with the Kelowna multiple element extractant. Soil Science 69:235-242
11 Mallarino, A. P., D. J. Wittry and P. A. Barbagelata. 2002. Iowa Soil-Test Field Calibration Research update: Potassium and the Mehlich-3 ICP Phosphorus Test. Department of Agronomy, Iowa State University, Ames, Iowa
12 Mallarino, A. P. and A. M. Atia. 2005. Correlation of a Resin Membrane soil phosphorus test with corn yield and routine soil tests. Soil Sci. Soc. Am. J. 69:266-272   DOI   ScienceOn
13 Mehlich, A. 1953. Determination of P, Ca, Mg, K, Na and NH4. North Carolina Soil Testing Division(Mimeo), N. C. Dept. Agr., Raleigh
14 Park, Y. H., Y. G. Jung, and C. W. Hong. 1980. Simplification of soil tests. RDA annual reports. Suwon, Republic of Korea
15 Michaelson, G. J., and C. L. Ping. 1986. Extraction of phosphorus from the major agricultural soils of Alaska. Commun. Soil Sci. Plant Anal. 17(3):275-297   DOI   ScienceOn
16 Emgblom, S. O. 1999. Determination of inorganic phosphate in a soil extract using a cobalt electrode . Plant Soil 206:173-179   DOI   ScienceOn
17 Ketterings, O. M., K. J. Cymmek, W.S. Reid, and R.F. Wildman. 2002. Conversion of Modified Morgan and Mehlich-Ⅲ soil tests to Morgan soil test values. Soil Science. 167(12):830-837   DOI   ScienceOn
18 Kim, M. S. 2008. Evaluation of Available Phosphorus Soil Tests in different Soils. Bull. of Agro-Environment Research 2007, pp 416-436. National Institute of Agricultural Science and Technology. Suwon. Republic of Korea
19 Park, B. G. and J. H. Yoon. 1992. Study on the simplified extraction methods for the analysis of available nutrients in the soil. Res. Rept. RDA(S&F) 34(2):43-47
20 National Institute of Agricultural Science and Technology. 2000. Analytical methods of Soil and Plant. NIAST, Suwon, Republic of Korea
21 Sharpley. A. N., J. L. Weld., D. B. Beegle, P. J. A. Kleinman, W. J. Gburek, P. A. Moore, Jr., and G. Mullins. 2003. Development of phosphorus indices for nutrient management planning strategies in the United States. J. Soil Water Conserv. 58:137-151
22 Soltanphour, P. N., and A. P. Schwab. 1977. A New Soil Test for simultaneous Extraction of Macro- and Micro Nutrients in alkaline soils. Commun. Soil Sci. Plant Anal. 8(3):195-207   DOI
23 Bray, R. H., and L. T. Kurtz. 1945. Determination of total organic and available forms of phosphorus in soil. Soil Science 59:39-45   DOI
24 Wolf, A. and D. Beegle. 1995. Recommended soil tests for macronutrients: phosphorus, potassium, calcium and magnesium. pp 30∼38. In Recommended soil testing procedures for the Northeastern United States. 2nd ed. Northeastern regional publication No. 493. Available at .edu/extension/agnr/soiltesting.htm
25 Gartley. K. L., J. T. Sims, C. T. Olsen, and P. Chu. 2002. Comparison of soil test extractants used in Mid-Atlantic Uinted States. Commun. Soil Sci. Plant Anal. 33(5&6):873-895   DOI   ScienceOn
26 McIntosh, J. L. 1969. Bray and Morgan soil test extractants modified for testing acid soils from different parent materials. Agron. J. 61:259-265   DOI
27 Olsen, S. R., and L. E. Sommers. 1982. Phosphorus soluble in sodium bicarbonate, pp 421-422. In : A. L. Page(ed.) American Society of Agronomy. Madison, WI
28 Soltanphour, P. N. 1991. Determination of Nutrient Availability and Elemental Toxicity by AB-DTPA soil Test and ICPS. Advances in Soil Science. 16:165-187
29 Wolf, B. 1982. An improved universal extracting solution and its use for diagnosing soil fertility. Commun. Soil Sci. Plant Anal. 13(12):1003-1005   DOI   ScienceOn
30 Munter, R. C. 1990. Advances in soil testing and plant analysis analytical technology. Commun. Soil Sci. Plant Anal. 21:1831-1841   DOI
31 Wang, J. J., D. L. Harrell, R. E. Henderson, and P. F. Bell. 2004. Comparison of soil-test extractants for phosphorus, potassium, calcium, magnesium, sodium, zinc, copper, manganese, and iron in Louisiana soils. Commun. In Soil Sci. Plant Anal. 35(1&2):145-160   DOI   ScienceOn