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http://dx.doi.org/10.7316/KHNES.2018.29.5.530

Effect on the Heat of Reaction to Temperature and Absorption Capacity in the Reaction of Cyclic Amines with Carbon Dioxide  

CHOI, JEONG HO (Greenhouse Gas Laboratory, Climate Change Research Division, Korea Institute of Energy Research)
JANG, JONG TACK (Greenhouse Gas Laboratory, Climate Change Research Division, Korea Institute of Energy Research)
YUN, SOUNG HEE (Greenhouse Gas Laboratory, Climate Change Research Division, Korea Institute of Energy Research)
JO, WON HEE (Greenhouse Gas Laboratory, Climate Change Research Division, Korea Institute of Energy Research)
JUNG, JIN YOUNG (Greenhouse Gas Laboratory, Climate Change Research Division, Korea Institute of Energy Research)
YOON, YEO IL (Greenhouse Gas Laboratory, Climate Change Research Division, Korea Institute of Energy Research)
Publication Information
Transactions of the Korean hydrogen and new energy society / v.29, no.5, 2018 , pp. 530-537 More about this Journal
Abstract
The effect of temperature and absorption capacity on heat of reaction, which is one of the characteristic studies of $CO_2$ absorption, were investigated in a differential reaction calorimeter (DRC) by using piperazine (PZ) and 2-methylpiperazine (2-MPZ). For all absorbents, $CO_2$ loading capacity decreased with increasing the temperature, while the heat of reaction increased, it figured out that these had a linear correlation between $CO_2$ loading capacity and/or heat of reaction and the temperature. The heat of reaction of all absorbents increased with increasing $CO_2$ loading capacity, especially 2-MPZ rapidly increased at $70^{\circ}C$. The reason for increase in the heat of reaction was occurred the regeneration of $CO_2$, which is a reverse-reaction, simultaneously with the absorption.
Keywords
Heat of reaction; Piperazine; Carbon dioxide; Climate change; $CO_2$ loading;
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  • Reference
1 C. Alie, L. Backham, E. Croiset, and P. L. Douglas, "Simulation of $CO_2$ capture using MEA scrubbing: a flowsheet decomposition method", Energy Conversion and Management, Vol. 46, 2005, pp. 475-487.   DOI
2 K. Robinson, A. McCluskey, and M. I. Attalla, "An ATR-FTIR study on the effect of molecular structural variations on the $CO_2$ absorption characteristics of heterocyclic amines, Part II", Chem. Phys. Chem., Vol. 13, 2012, pp. 2331-2341.   DOI
3 K. Robinson, A. McCluskey, and M. I. Attalla, "The effect molecular structural variations has on the $CO_2$ absorption characteristics of heterocyclic amines", American Chemical Society, 2012, Chapter 1, pp. 1-27.
4 K. K. Li, A. Cousins, H. Yu, P. Feron, M. Tade, W. Luo, and J. Chen, "Systematic study of aqueous monoethanolamine-based $CO_2$ capture process: model development and process improvement", Energy Science & Engineering, Vol. 4, No. 1, 2016, pp. 23-39.   DOI
5 J. H. Choi, S. H. Yun, Y. E. Kim, Y. I. Yoon, and S. C. Nam, "The Effect of Functional Group Position of the Piperidine Derivatives on the $CO_2$ Absorption Characteristics in the ($H_2O$-Piperidine-$CO_2$) System", Korean Chem. Eng. Res., Vol. 53, No. 1. 2015, pp. 57-63.   DOI
6 I. Kim and H. F. Svendsen, "Heat of Absorption of Carbon Dioxide ($CO_2$) in Monoethanolamine (MEA) and 2-(Aminoethyl)ethanolamine (AEEA) Solutions", Ind. Eng. Chem. Res., Vol. 46, No. 17, 2007, pp. 5803-5809.   DOI
7 Contribution of working group I,II and III, "Climate Change 2014 Synthesis Report", Intergovernmmental Panel on Climate Change, Switzerland, 2014, pp. 1-151.
8 P. Friedlingstein, P. M. Andrew, J. Rogelj, G. P. Peters, J. G. Canadell, R. Knutti, G. Luderer, M. R. Raupach, M. Schaeffer, D. P. van Vuuren, and C. Le Quere, "Persistent growth of $CO_2$ emissions and implications for reaching climate targets", Nature Geoscience, Vol. 7, 2014, pp. 709-715.   DOI
9 United Nations, "Paris agreement", United Nations, Paris, 2015, pp. 1-27.
10 Ministry of Environment, "2030 Greenhouse Gas Reduction Roadmap", Korea, 2018, pp. 1-24.
11 R. M. Cuellar-Franca and A. Azapagic, "Carbon capture, storage and utilisation technologies: A critical analysis and comparison of their life environmental impacts", Journal of $CO_2$ Utilization, Vol. 9, 2015, pp. 82-102.   DOI
12 T, Naucler and P. A. Enkvlst, "Pathways to a low-carbon economy", Mckinsey & Company, 2009, pp. 1-190.
13 J. G. Shim, Y. H. Jhon, J. H. Kim, J. H. Lee, I. Y. Lee, K. R. Jang, and J. Kim, "Calculated accessibilities and nucleophilicities of linear and cyclic amines for carbon dioxide absorption reactions", Bulletin Korean Chemical Society, Vol. 32, 2011, pp. 2813-2816.   DOI
14 A. Muhammad, M. I .A. Mutalib, T. Murugesan, and A. Shafeeq, "Thermophysical properties of aqueous piperazine and aqueous (N-Methyldiethanolamine+Piperazine) solutions at temperatures (298.15 to 338.15) K", Journal of Chemical & Engineering Data, Vol. 54, 2009, pp. 2317-2321.   DOI
15 A. Veawab, P. Tontiwachwuthikul, A. Aroonwilas, and A. Chakma, "Performance and cost analysis for $CO_2$ capture from flue gas streams: absorption and regeneration aspects", Greenhouse Gas Control Technol., Vol. 1, 2003, pp. 127-132.