Browse > Article

Fabrication of Sn-Sb Based Powder by Carbothermal Reduction of Spherical Ultrafine Metal Oxides  

Hong, Seong-Hyeon (New Functional Materials Research Division, Korea Institute of Machinery and Materials)
Bae, Jong-Soo (New Functional Materials Research Division, Korea Institute of Machinery and Materials)
Chin, Young-Mi (Advanced Materials Research Division, Korea Institute of Machinery and Materials)
Kwon, Hae-Woong (Department of Materials Science and Engineering, Pukyong National University)
Publication Information
Transactions of the Korean hydrogen and new energy society / v.17, no.3, 2006 , pp. 324-330 More about this Journal
Abstract
In this study, carbothermal reduction method was employed to synthesis Sn-Sb alloy powders from chief metal oxides with ultrafine sizes. The Sn-Sb powders consisting of ultrafine particles were formed at $800{\sim}900^{\circ}C$ by reduction of oxides. Those powders have high initial discharge capacities ($570{\sim}637\;mAh/g$) and discharge capacities of those powders maintain initial capacity after 20 cycle due to existence of ultrafine particles in powders and alloying effect of Sn-Sb.
Keywords
lithium ion battery; SnSb powder; reduction; anode powder; cycle test;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
연도 인용수 순위
1 Chunsheng Wang, A. John App1eby, and Frank E. Little, 'Electrochemical study on nano-Sn, L4.4Sn and $AISi_{0.1}$ powders used as secondary lithium battery anodes', Journal of Power Sources, Vol. 93, No. 1-2, 2001, pp. 174-185   DOI   ScienceOn
2 J.O. Besenhard, J. Yang, and M. Winter, 'Will advanced lithium-alloy anodes have a chance in lithium-ion batteries?', Journal of Power Sources, Vol. 68, No. 1, 1997, pp. 87-90   DOI   ScienceOn
3 J. Yang, Y. Takeda, N. Imanishi, J. Y. Xie , and O. Yamamoto, 'Intermetallic SnSbx compounds for lithium insertion hosts', Solid State lonics, Vol. 133, No. 3-4, 2000, pp. 189-194   DOI   ScienceOn
4 N. Pereira , L. C. Klein, and G. G. Amatucci, 'Particle size and multiphase effects on cycling stability using tin-based materials', Solid State lonics, Vol. 167, No. 1-2, 2004, pp. 29-40   DOI   ScienceOn
5 Nikolay Dimov, Satoshi Kugino, and Masaki Yoshio, 'Carbon-coated silicon as anode material for lithium ion batteries: advantages and limitations', Electrochimica Acta, Vol. 48, No. 11, pp. 1579-1587   DOI   ScienceOn
6 M. Endo, C. Kiln, K. Nishimura, T. Fujino, and K. Miyashita, 'Recent development of carbon materials for Li ion batteries, Carbon, Vol. 38, No. 2, 2000, pp. 183-197   DOI   ScienceOn
7 Hailiei Zhal, Chaoli Yin, Dickon H.L, Ng, and Weihua Qiu, 'Electrochemical properties of carbothermal synthesized SnSb anode materials for Li-ion batteries', Proceedings of The 5th Asian Conference on Electrochmistry (ACEC 2005), Shanghai (China), 2005, pp. 0-4-23
8 Inngard Rom, Mario Wachtler, Ilse Papst, Mario Schmied, Jurgen O. Besenhard, Ferdinand Hofer, and Martin Winter, 'Electron microscopical characterization of Sn/SnSb composite electrodes for lithium-ion batteries', Solid State lonics, Vol. 143, No. 3-4, 2001, pp. 329-336   DOI   ScienceOn
9 J. Yang, M. Winter, and J.O. Besenhard, 'Small particle size multiphase Li-alloy anodes for lithium-ion batteries', Solid State lonics, Vol. 90, No. 1-4, 1996, pp. 281-287   DOI   ScienceOn
10 D. G. Kim, H. Kiln, H. -J. Sohn, and T. Kang, 'Nanosized Sn - Cu - B alloy anode prepared by chemical reduction for secondary lithium batteries', Journal of Power Sources, Vol. 104, No. 2, 2002, pp. 221-225   DOI   ScienceOn
11 안중호, '나노결정립분말을 이용한 리튬2차전지용의 새로운 전지재료', 한국분말야금학회지, Vol. 9, No. 5, 2002, pp. 370-374
12 Hailei Zhao, D.H.L. Ng, Zhongqin Lu , and Nangang Ma, 'Carbothermal synthesis of $Sn_{x}Sb$ anode material for secondary lithium-ion battery', Journal of Alloys and Compounds, Vol. 395, No. 1-2, 2005, pp. 192-200   DOI   ScienceOn
13 Z. S. Wen, J. Yang, B. F. Wang, K. Wang, and Y. Liu, 'High capacity silicon/carbon composite anode materials for lithium ion batteries', Electrochemistry Communications, Vol. 5, No. 2, 2003, pp. 165-168   DOI   ScienceOn