Browse > Article

Hydrogen Production by Catalytic Reforming of $CO_2$ by $CH_4$ over Ni Based Catalysts and It's Applications  

Moon, Dong-Ju (Hydrogen Energy Research Center, Korea Institute of Science & Technology)
Kang, Jung-Shik (Hydrogen Energy Research Center, Korea Institute of Science & Technology)
Ryu, Jong-Woo (Hydrogen Energy Research Center, Korea Institute of Science & Technology)
Kim, Dae-Hyun (Hydrogen Energy Research Center, Korea Institute of Science & Technology)
Yoo, Kye-Sang (Hydrogen Energy Research Center, Korea Institute of Science & Technology)
Lee, Hyun-Joo (Hydrogen Energy Research Center, Korea Institute of Science & Technology)
Kim, Hong-Gon (Hydrogen Energy Research Center, Korea Institute of Science & Technology)
Lee, Sang-Deuk (Hydrogen Energy Research Center, Korea Institute of Science & Technology)
Ahn, Byoung-Sung (Hydrogen Energy Research Center, Korea Institute of Science & Technology)
Lee, Byung-Gwon (Hydrogen Energy Research Center, Korea Institute of Science & Technology)
Publication Information
Transactions of the Korean hydrogen and new energy society / v.17, no.2, 2006 , pp. 166-173 More about this Journal
Abstract
Catalytic reforming of $CO_2$ by $CH_4$ over Ni-YSZ based catalysts was investigated to produce syngas as raw material of high valued chemicals and develop high performance catalyst electrode for an internal reforming of $CO_2$ in SOFC system. Ni-YSZ based catalysts were prepared using physical mixing and maleic acid methods to improve catalytic activity and inhibition of carbon deposition. The catalysts before and after the reaction were characterized by $N_2$ physisorption, TPR(temperature programed reduction), XRD and impedance analyzer. The conversions for $CO_2$ and $CH_4$ over Ni-MgO catalyst showed 90% but much amount of carbon deposition was detected on catalyst surface. On the other hand, the conversions for $CO_2$ and $CH_4$ over NiO-YSZ-$CeO_2$ catalyst showed 100% and 85% respectively, and carbon deposition on catalyst surface was inhibited under the tested condition. It was concluded that NiO-YSZ-$CeO_2$ catalyst is a promising candidate for the catalytic reforming of $CO_2$ and the internal reforming in SOFC system.
Keywords
Ni-YSZ based catalyst$CO_2$; Syngas$H_2$ production$CO_2$ reforming; SOFC; Internal reforming;
Citations & Related Records
연도 인용수 순위
  • Reference
1 D. J. Moon, J. W. Ryu., 'Electrocatalytic reforming of carbon dioxide by methane in SOFC system', Catal. Today, Vol. 87, 2003, p. 255   DOI
2 Q. G. Yan, W.Z. Weng, H.L. Wan., H. Toghiani, 'Activation of methane to syngas over a $Ni/TiO_{2}$ catalyst', Appl. Catal. A: General 239, 2003, p. 43   DOI
3 S. Wang and G. Q. Lu, 'Catalytic Activities and Coking Characteristics of Oxides-Supported Ni Catalysts for $CH_{4}$ Reforming with Carbon Dioxide', Energy & Fuels, Vol. 12, 1998, p. 248   DOI   ScienceOn
4 D. J. Moon, J. W. Ryu, K. S. Yoo and B. G. Lee, 'Hydrogen production by autothermal reforming reaction of gasoline over Ni-based catalysts and its applications', Trans of the Korean Hydrogen and New Energy Society, Vol. 15, No. 4, 2004, p. 274
5 S. B. Tang, F. L. Qiu, S. J. Lu, 'Effect of supports on the carbon deposition of nickel catalysts for methane reforming with $CO_{2}$', Catal. Today, Vol. 24, 1995, p.253   DOI   ScienceOn
6 D. J. Moon, J. W. Ryu, D. M Kang, B. K Lee, B. S. Ahn, 'C02 reforming by CH4 over Ni-YSZ modified catalysts', Stud. in Surf. Sci. & Catal., vol. 153, 2004, p. 195
7 M. Foumier, J. Hamelin, K. Agbossou, T. K. Bose, 'Fuel cell operation with oxygen enrichment', Fuel Cells, vol. 2, No. 2, 2003, p. 117   DOI   ScienceOn
8 D. J. Moon, J. W. Ryu, T. Y. Kim, D. M Kang, J. M. Park, S. D. Lee and B. G. Lee, '$CO_{2}$의 전기화학적 전환, 회수 및 활용을 위한 SOFC 시스템', Korean Patent 2003-0074934, 2003
9 S. Freni, S. Cavallaro, N. Mondello, L. Spadaro, F. Frusteri, 'Production of hydrogen for MC fuel cell by steam reforming of ethanol over MgO supported Ni and Co catalysts', Catal. Comm. Vol. 4, 2003, p. 259   DOI   ScienceOn
10 W. Cho, Y. Baek, Y. C. Kim, M. Anpo, 'Plasma catalytic reaction of natural gas to C2 product over $Pd-NiO/Al_{2}O_{3}$ and $Pt-Sn/Al_{2}O_{3}$ catalysts', Res. Chem. Interrned., vol. 28, No. 4, 2002, p. 343   DOI   ScienceOn
11 V. C .H. Kroll, H. M Swaan, S. Lacombe, C. Mirodatos, 'Catalytic hydrodechlorination of 1, 1-Dichlorotetrafluoroethane by $Pd/Al_{2}O_{3}$', J. Catal. vol. 164, No. 2, 1997, p. 387   DOI   ScienceOn
12 W. Cho, Y. Baele, S. K. Moon, Y. C. Kim, 'Oxidative coupling of methane with microwave and RF plasma catalytic reaction over transitional metals loaded on ZSM-5', Catal. Today, vol. 74, 2002, p. 207   DOI   ScienceOn
13 C. J. Michael, and M. A. Vannice, '$CO_{2}$ Reforming of $CH_{4}$ over Supported Ru Catalysts', J. of Catal., Vol. 183, 1999, p. 69   DOI   ScienceOn
14 P. Vemoux et aI., 'Alternative anode material for gradual methane reforming in solid oxide fuel cells', Solid State lonics, Vol. 135, 2000, p. 425   DOI   ScienceOn
15 A. M. O'Connor, J. R. H. Ross, 'The effect of Oz addition on the carbon dioxide reforming of methane over $Pt/ZrO{2}$ catalysts', Catal.Today, vol. 46, No. 2-3, 1998, p. 203   DOI   ScienceOn
16 D. J. Moon, J. W. Ryu, S. D. Lee, 'Carbon dioxide reduction technology with SOFC system', Stud. in Surf Sci. & Catal., vol. 153, 2004, p. 149   DOI
17 H. Y. Wang, C. T. Au, 'Carbon dioxide reforming of methane to syngas over $SiO_{2}-supported$ rhodium catalysts', App. Catal. A: General 155, 1997, p. 239   DOI   ScienceOn
18 D. J. Moon, J. W. Ryu, T.Y. Kim, B. G. Lee and S. D. Lee, 'Electrode catalyst for internal reforming of carbon dioxide and hydrocarbon and the electrocatalytic SOFC system for producing syngas and electricity', US Patent No. 10830225, 2004