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http://dx.doi.org/10.4191/kcers.2019.56.4.10

Dielectric, Ferroelectric, Energy Storage, and Pyroelectric Properties of Mn-Doped (Pb0.93La0.07)(Zr0.82Ti0.18)O3 Anti-Ferroelectric Ceramics  

Kumar, Ajeet (School of Materials Science and Engineering, Yeungnam University)
Yoon, Jang Yuel (School of Materials Science and Engineering, Yeungnam University)
Thakre, Atul (School of Materials Science and Engineering, Yeungnam University)
Peddigari, Mahesh (Functional Ceramics Group, Korea Institute of Material Science)
Jeong, Dae-Yong (Department of Materials Science and Engineering, Inha University)
Kong, Young-Min (School of Materials Science and Engineering, University of Ulsan)
Ryu, Jungho (School of Materials Science and Engineering, Yeungnam University)
Publication Information
Journal of the Korean Ceramic Society / v.56, no.4, 2019 , pp. 412-420 More about this Journal
Abstract
In this study, the dielectric and polarization properties of manganese (Mn% = 0.0, 0.1, 0.2, 0.5) doped (Pb0.93La0.07)(Zr0.82Ti0.18)O3 (PLZT 7/82/18) anti-ferroelectric ceramics were studied for energy storage capacitor and pyroelectric applications. A systematic investigation demonstrated that the electric properties of PLZT 7/82/18 ceramics are affected significantly by the Mn-doping content. A maximum dielectric constant of ~ 2,128 at 1 kHz was found for 0.1% Mn-doped PLZT ceramics with a low dielectric loss of 0.018. The bipolar polarization versus electric field (P-E) hysteresis loops were traced for all compositions showing a typical anti-ferroelectric nature. The breakdown field was found to decrease with Mn-doping. The energy storage density and efficiency were found to be 460 J/㎤ and ~ 63%, respectively, for 0.2% Mn-doped PLZT ceramics. The pyroelectric coefficient of PLZT ceramics shows an increase based on the amount of Mn-doping.
Keywords
PLZT; Ferroelectric properties; Anti-ferroelectric; Energy storage; Pyroelectricity;
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Times Cited By KSCI : 8  (Citation Analysis)
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