Browse > Article
http://dx.doi.org/10.4191/kcers.2019.56.4.03

Compressive Strength Properties of Geopolymers from Pond Ash and Possibility of Utilization as Synthetic Basalt  

Kim, Byoungkwan (Resources Recycling, University of Science & Technology)
Lee, Bokyeong (Intelligent Construction Automation Center, Kyungpook National University)
Chon, Chul-Min (Geological Environment Division, Korea Institute of Geoscience and Mineral Resources)
Lee, Sujeong (Resources Recycling, University of Science & Technology)
Publication Information
Abstract
Pond ash is a mixture of mostly coarser fly ash and bottom ash. The recycling rate of pond ash is low because pond ash is mixed with seawater and deposited in ponds. The pond ash is also subjected to natural weathering over a period of time. In this study, we investigated whether pond ash can be used as a raw material of geopolymers, without any purification process or through a minimal purification process. In addition, we investigated whether synthetic basalt made by adding foaming agent to geopolymer or casting it into a mold can show the surface of the natural basalt as it is. The highest 7-day compressive strength in geopolymers from pond ash without purification process was 26 MPa. The highest 7-day compressive strength in geopolymers from pond ash with impurities removed through dry sieve analysis was found to improve to 80 MPa. On the other hand, synthetic basalt made with geopolymer was shown to be more advantageous aesthetically when produced by casting it in a silicone mold rather than by adding a foaming agent. Non-purified pond ash can be made into geopolymers having low strength. Pond ash purified by sieving can, without use of an aggregate, be made into geopolymer having high-strength. Also, it is possible to produce synthetic basalt with the same appearance as natural basalt and sufficient strength for commercialization. This process will contribute to the mass consumption and recycling of pond ash.
Keywords
Geopolymer; Pond ash; Compressive strength; Synthetic basalt;
Citations & Related Records
Times Cited By KSCI : 8  (Citation Analysis)
연도 인용수 순위
1 S. Lee, S. Cho, Y. S. Lee, E. M. An, and S. B. Cho, "Application of Unburned Carbon Produced from Seochun Power Plant," J. Korean Inst. Resour. Recycl., 23 [1] 40-7 (2014).   DOI
2 Y. Kim, K. Kim, and G. Y. Jeong, "Study of Detailed Geochemistry of Hazardous Elements in Weathered Coal Ashes," Fuel, 193 343-50 (2017).   DOI
3 D. H. Kim, W. S. Ki, and S. H. Kim, "The Utilization of Pond Ash as Embankment and Backfill Material," J. Engineering Geology, 20 [3] 297-310 (2010).
4 J. Temuujin, A. Minjigmaa, B. Davaabal, T. Zolzaya, U. Bayarzul, T. Jadambaa, and C. H. Ruscher "Preparation of Geopolymer-Type Mortar and "Light-Weight Concrete" from Coppoer Flotation Waste and Coal Combustion by Products," pp. 89-101 in Developments in Strategic Ceramic Materials: A Collection of Papers Presented at the 39th International Conference on Advanced Ceramics and Composites, John Wiley & Sons, USA 2016.
5 J. Temuujin, A. Minjigmaa, U. Bayarzul, D. S. Kim, S.-H. Lee, H. J. Lee, C. H. Ruescher, and K. J. D. MacKenzie, "Properties of Geopolymer Binders Prepared from Milled Pond Ash," Mater. Construcc., 67 [328] e134 (2017).
6 M. Panigrahi, S. Mohanty, R. R. Dash, and R. I. Ganguly, "Development of Novel Constructional Material from Industrial Solid Waste as Geopolymer," IOP Conf. Ser.: Mater. Sci. Eng., 410 [1] 012012 (2018).   DOI
7 S Lee, H. T. Jou, C. M. Chon, N. H. Kang, and S. B. Cho, "Developing and Assessing Geopolymers from Seochun Pond Ash with a Range of Compositional Ratios," J. Korean Ceram. Soc., 50 [2] 134-41 (2013).   DOI
8 B. Kim, Y.-E. Heo, C. M. Chon, and S. Lee, "Influence of Na/Al Ratio and Curing Temperature of Geopolymers on Efflorescence Reduction," J. Korean Inst. Resour. Recycl., 27 [6] 59-67 (2018).   DOI
9 Y. H. Kim, "Manufacture of Lightweight Aggregates Using Bottom Ash," J. Rec. Const. Resources, 11 [2] 30-4 (2016).
10 S. Lee, A. Van Riessen, and C. M. Chon, "Benefits of Sealed-Curing on Compressive Strength of Fly Ash-based Geopolymers," Materials, 9 [7] 598 (2016).   DOI
11 S. Lee, E. M. An, and Y. H. Cho, "Effect of Foaming Agent Content on the Apparent Density and Compressive Strength of Lightweight Geopolymers," JRCR, 4 [4] 363-70 (2016).
12 Y. N. Lee, and I. S. Jung, "Boundary Stone Made from Artificial Basalt," Korea Patent, 20-2001-0031178, 2011.
13 S. H. Shin and M. K. Jo, "Artifical Stone Made from Waste Stone or Lightweight Aggregate of Baslt," Korea Patent, 10-2012-0059758, 2012.
14 I. Kulaots, R. H. Hurt, and E. M. Suuberg, "Size Distribution of Unburned Carbon in Coal Fly Ash and its Implications," Fuel, 83 [2] 223-30 (2004).   DOI
15 M. C. Fuerstenau and K. N. Han, Principles of Mineral Processing; p. 573, Society for Mining, Metallurgy, and Exploration Inc, USA, 2003.
16 C. M. Chon, S. Lee, and S. W. Lee, "Quantitative X-ray Diffraction Analysis of Synthetic Mineral Mixtures Including Amorphous Silica using the PONKCS Method," J. Miner. Soc. Korea, 26 [1] 27-34 (2013).   DOI
17 R. P. Williams and A. Van Riessen, "Determination of the Reactive Component Fly Ashes for Geopolymer Production Using XRF and XRD," Fuel, 89 [12] 3682-92 (2010).
18 N. H. Kang, C. M. Chon, H. T. Jou, and S. Lee, "Effect of Particle Size and Unburned Carbon Content of Fly Ash from Hadong Power Plant on Compressive Strength of Geopolymers," Korean J. Mater. Res., 23 [9] 510-16 (2013).   DOI
19 S. Lee, M. D. Seo, Y. J. Kim, H. H. Park, T. N. Kim, Y. Hwang, and S. B. Cho, "Unburned Carbon Removal Effect on Compressive Strength Development in a Honeycomb Briquette Ash-based Geopolymer," Int. J. Miner. Process., 97 [1-4] 20-25 (2010).   DOI
20 J. Davidovits, M. Izquierdo, X. Querol, D. Antennuci, H. Nugteren, V. Butselaar-Orthlieb, C. Fernandez-Pereira, and Y. Luna, The European Research Project GEOASH: Geopolymer Cement Based On European Coal Fly Ashes; Geopolymer Institute Library, Technical Paper, 22, 2014.
21 C. Klein and A. R. Philpotts, Earth Materials: Introduction to Mineralogy and Petrology; pp. 66-72, Cambridge University Press, Cambridge, 2013.
22 A. Van Riessen and N. Chen-Tan, "Beneficiation of Collie Fly Ash for Synthesis of Geopolymer: Part 1-Beneficiation," Fuel, 106 569-75 (2013).   DOI
23 S. Lee, S. Cho, Y. S. Lee, E. M. An, and S. B. Cho, "Application of Unburned Carbon Produced from Seochun Power Plant," J. Korean Inst. Resour. Recycl., 23 [1] 40-7 (2014).   DOI
24 D. N. C. Phan, The Relationship between Fly Ash Chemistry and the Thermal Formation of Polychlorinated Pollutants during Waste Incineration, pp. 60-1, in Ph.D. Thesis, Umea universitet, Umea, 2013.
25 H. Schmidt and H. Scholze, In Aerogels; The Sol-Gel Process for Non-Metallic Inorganic Materials; pp. 49-56, Springer, Berlin, 1986.
26 P. R. Vora and U. V. Dave, "Parametric Studies on Compressive Strength of Geopolymer Concrete," Procedia Eng., 51 210-19 (2013).   DOI
27 S. Park and M. Pour-Ghaz, "What is the Role of Water in the Geopolymerization of Metakaolin?," Constr. Build. Mater., 182 360-70 (2018).   DOI
28 Z. Zuhua, Y. Xiao, Z. Huajun, and C. Yue, "Role of Water in the Synthesis of Calcined Kaolin-based Geopolymer," Appl. Clay Sci., 43 [2] 218-23 (2009).   DOI
29 T. W. Kong, S. H. Lee, C. W. Kwon, and H. B. Lee, "Advanced Concrete Technology Trends," Ceramist, 14 [6] 45-53 (2011).
30 S. W. Kim, S. T. Kang, and S. M. Han, "Characteristics and Application of Ultra High Performance Cementitious Composite," Magazine of the Korea Concrete Institute, 18 [1] 16-21 (2006).
31 T.-W. Jeon, J.-E. Park, D.-G. Hwang, S.-Y. Hong, S.-K. Shin, G.-J. Oh, Y.-Y. Kang, N.-I. Um, Y.-W. Jeong, and S.-K. Jeong, "The Study on Recycling Availability and Use Expansion of Coal Ash," National Institute of Environmental Research, 2014.
32 J. H. Maeng, T. Y. Kim, and D. H. Seo, "Minimizing Environmental Impact in accordance with the Thermal Power Plant Ash Management(I)," Korea Environment Institute, 2014.