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http://dx.doi.org/10.4191/kcers.2017.54.5.08

Fabrication of Calcium Phosphate Glass Using Eggshell and its Crystallization Behavior  

Kang, Tea-Sung (Department of Advanced Materials Science and Engineering, Mokpo National University)
Lee, Sang-Jin (Department of Advanced Materials Science and Engineering, Mokpo National University)
Publication Information
Journal of the Korean Ceramic Society / v.54, no.5, 2017 , pp. 395-399 More about this Journal
Abstract
The thermal properties and crystallization behavior of calcium phosphate glass fabricated using eggshell were examined. Nature eggshell has several impurities in the main component of $CaCO_3$. To manufacture calcium phosphate glass, washed eggshell was dissolved in aqua-regia while adding a solution of isopropyl alcohol, D. I. water and phosphoric acid. The calcined precursor was melted at $1000^{\circ}C$, and the glass ($T_g$ : $540^{\circ}C$) was crystallized at $620{\sim}640^{\circ}C$, which temperature range is relatively low compared to the crystallization temperature of other general types of calcium phosphate glass. The calcium phosphate glass using eggshell was successfully crystallized without any additional nucleating agents due to the multiple effects of impurities such as $Fe_2O_3$, $Al_2O_3$, SrO and $SiO_2$ in the eggshell. The main crystalline phase was ${\beta}-Ca(PO_3)_2$ and a biocompatible material, hydroxyapatite, was also observed. The crystallization process was completed under the condition of a holding time of only 1 h at the low temperature.
Keywords
Calcium phosphate glass; Glass ceramic; Crystallization; X-ray diffraction; Eggshell;
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Times Cited By KSCI : 2  (Citation Analysis)
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