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http://dx.doi.org/10.4191/kcers.2013.50.6.510

Synthesis of (Co,Mg)Al2O4 and (Ni,Mg)Al2O4 Blue Ceramic Nano Pigment by Polymerized Complex Method  

Son, Bo-Ram (Icheon Branch, Korea Institute of Ceramic Engineering & Technology (KICET))
Yoon, Dea-Ho (Department of Advanced Materials Engineering, Sungkyunkwan University)
Kim, Jin-Ho (Icheon Branch, Korea Institute of Ceramic Engineering & Technology (KICET))
Han, Kyu-Sung (Icheon Branch, Korea Institute of Ceramic Engineering & Technology (KICET))
Cho, Woo-Suk (Icheon Branch, Korea Institute of Ceramic Engineering & Technology (KICET))
Hwang, Kwang-Taek (Icheon Branch, Korea Institute of Ceramic Engineering & Technology (KICET))
Publication Information
Journal of the Korean Ceramic Society / v.50, no.6, 2013 , pp. 510-517 More about this Journal
Abstract
In this study, the properties of blue inorganic nano-pigments with a spinel structure were systematically investigated. We report the preparation of a blue ceramic nano-pigment and the Co and Ni substitutional effects on the blue color. $MgAl_2O_4$ was selected as the crystalline host network for the synthesis of cobalt and nickel-based blue ceramic nano-pigments. Various compositions of $Co_xMg_{1-x}Al_2O_4$ and $Ni_xMg_{1-x}Al_2O_4$ ($0{\leq}x{\leq}1$) powders were prepared using apolymerized complex method. The obtained powder was preheated at $400^{\circ}C$ for 5 h and then calcined at $1000^{\circ}C$ for 5 h. XRD patterns of the (Co,Mg)$Al_2O_4$ and (Ni,Mg)$Al_2O_4$ samples showed a single phase of the spinel structure in all compositions. TEM results indicated nano-sized pigments for (Co,Mg)$Al_2O_4$ and (Ni,Mg)$Al_2O_4$ with a particle size ranging from 20 to 50 nm. The characteristics of the color tones of (Co,Mg)$Al_2O_4$ and (Ni,Mg)$Al_2O_4$ were analyzed by CIE $L^*a^*b^*$ measurements. In addition, the thermal stability and the binding characteristics of (Co,Mg)$Al_2O_4$, (Ni,Mg)$Al_2O_4$ are discussed in terms of the TG-DSC and FT-IR results, respectively.
Keywords
Blue ceramic nano-pigment; $Co_xMg_{1-x}Al_2O_4$; $Ni_xMg_{1-x}Al_2O_4$; Spinel; Polymerized complex method;
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Times Cited By KSCI : 1  (Citation Analysis)
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