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http://dx.doi.org/10.4191/kcers.2013.50.2.116

The Effect of Nucleating Agent on Zn2SiO4 Crystal Glaze  

Lee, Hyun-Soo (Department of Materials Science & Engineering, Myongji University)
Publication Information
Journal of the Korean Ceramic Society / v.50, no.2, 2013 , pp. 116-121 More about this Journal
Abstract
Zinc crystal glaze has its limits in practical use of commercial glaze due to the controlling crystal. In order to overcome this limit, and to heighten the practical usage, this study is aimed to develop artificially controlling willemite ($Zn_2SiO_4$) zinc crystalline glaze. For this purpose, it has experimented with the effect of anatase form and rutile form using $TiO_2$ known as nucleating agent. In zinc glaze, adding $TiO_2$ resulted with anatase form becoming more effective at nucleating formation and growth of willemite than the rutile form. Furthermore, it turned out that using the $TiO_2$ - anatase form, with synthetic seeds (zinc silicate), the numbers and positions of crystals can be controlled artificially.
Keywords
Zinc crystal glaze; Zinc silicate seed; Zinc crystal nuclei growth; Willemite; $TiO_2$;
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