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http://dx.doi.org/10.4191/kcers.2012.49.5.461

The Photocatalytic Decompositions of 2-Chlorophenol on the Sn-impregnated Titania Nanoparticles and Nanotube  

Kim, Hyun Soo (Department of Chemistry, Yeungnam University)
Lee, Gayoung (Department of Chemistry, Yeungnam University)
Park, Sun-Min (Korean Institutes of Ceramic Engineering & Technology (KICET))
Kang, Misook (Department of Chemistry, Yeungnam University)
Publication Information
Abstract
This study focuses on the difference of photocatalytic activity depending on crystal structure type of nanoparticles ($TiO_2$) and nanotubes (TNT). The photodecomposition of 2-chlorophenol on the synthesized $TiO_2$, Sn-impregnated $TiO_2$, TNT, and Snimpregnated TNT were evaluated. The characteristics of the synthesized photocatalyts, TNT, Sn/TNT, $TiO_2$, and Sn/$TiO_2$ were analyzed by X-ray diffraction (XRD), transmission electron microscopy (TEM), and UV-Visible spectroscopy (UV-Vis), and cyclic voltammeter (CV). The water-suspended 2-chlorophenol photodegradation over $TiO_2$ (anatase structure) catalyst was better than that over pure TNT. Particularly, the water-suspended 2-chlorophenol of 10 ppm was perfectly decomposed within 4 h over Sn/$TiO_2$ photocatalyst.
Keywords
Hydrothermal method; $TiO_2$; Titania nanotube; Impregnation; 2-Chlorophenol photodegradation;
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Times Cited By KSCI : 2  (Citation Analysis)
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1 S. Ken, O. Yuya, U. Hiroaki, H. Eiji, Z. Haoshen, and I. Hiroaki, "Aqueous Solution Synthesis of SnO Nanostractures with Tuned Optical Absorption and Photoelectrochemical Properties through Morphological Evolution," J. Roy. Soc. Chem., 2 2424-30 (2010).
2 K. P. Yu, W. Y. Yu, M. C. Kuo, Y. C. Liou, and S. H. Chien, "Pt/titania-nanotube: A Potential Catalyst for $CO_2$ Adsorption and Hydrogenation," Appl. Catal. B-Environ., 84 112- 18 (2008).   DOI
3 B. S. Kwak, H. Choi, J. Woo, J. Lee, J. An, S. G. Ryu, and Misook Kang, "Photo-electrochemical Hydrogen Production Over P- and B- Incorporated $TiO_2$ Nanometer Sized Photo-Catalysts," Clean Tech., 17 [1] 78-82 (2011).   과학기술학회마을
4 R. Vinu and G. Madras, "Photocatalytic Activity of Ag-substituted and Impregnated Nano-$TiO_2$," Appl. Catal. A - Gen., 366 130-40 (2009).   DOI
5 R. Enederson, I. P. Diego, H.Z. dos S. Joao, B.C. P. Sibele, and G. P. Fabio, "Bentonites Impregnated with $TiO_2$ for Photodegradation of Methylene Blue," Appl. Clay. Sci., 48 602- 06 (2010).   DOI
6 M. A. Barakat, H. Schaeffera, G. Hayesa, and S. Ismat-Shah, "Photocatalytic Degradation of 2-Chlorophenol by Codoped $TiO_2$ Nanoparticles," Appl. Catal. B-Environ., 57 23- 30 (2005).   DOI
7 D. N. Bui, S. Z. Kang, X. Li, and Jin Mu, "Effect of Si Doping on the Photocatalytic Activity and Photoelectrochemical Property of $TiO_2$ Nanoparticles," Catal. Commun., 13 14-7 (2011).   DOI
8 I. C. Flores, J. N. de Freitas, C. Longo, M. A. de Paoli, H. Winnischofer, and A. F. Nogueira, "Dye-sensitized Solar Cells Based on $TiO_2$ Nanotubes and a Solid-state Electrolyte," J. Photoch. Photobio. A., 189 153-60 (2007).   DOI
9 M. P. Moya, M. Graells, L. J. del Valle, E. Centelles, and H. D. Mansilla, "Fenton and Photo-fenton Degradation of 2- Chlorophenol: Multivariate Analysis and Toxicity Monitoring," Catal. Today, 124 163-71 (2007).   DOI
10 Ch. Boughelouma and A. Messalhib, "Photocatalytic Degradation of Benzene Derivatives on $TiO_2$ Catalyst," Physics. Procedia., 2 1055-58 (2009).   DOI
11 Y. H. Chena, L. L. Chen, and N. C. Shang, "Photocatalytic Degradation of Dimethyl Phthalate in an Aqueous Solution with Pt-doped $TiO_2$-coated Magnetic PMMA Microspheres", J. Hazard. Mater., 172 20-29 (2009).   DOI
12 G. B. Ortiz de la Plata, O. M. Alfano, and A. E. Cassano, "Decomposition of 2-chlorophenol Employing Goethite as Fenton Catalyst II: Reaction Kinetics of the Heterogeneous Fenton and Photo-fenton Mechanisms," Appl. Catal. BEnviron., 95 14-25 (2010).   DOI
13 J. M. Monteagudo, A. Dura'n, and C. Lo'pez-Almodo'var, "Homogeneus Ferrioxalate-assisted Solar Photo-fenton Degradation of Orange II Aqueous Solutions," Appl. Catal. B-Environ., 83 46-55 (2008).   DOI
14 S. H. Kwona and D. Cho, "A Comparative, Kinetic Study on Cork and Activated Carbon Biofilters for VOC Degradation," J. Ind. Eng. Chem., 15 129-35 (2009).   과학기술학회마을   DOI
15 Y. C. Chiang, P. C. Chiang, and C. P. Huang, "Effects of Pore Structure and Temperature on VOC Adsorption on Activated Carbon," Carbon, 39 523-34 (2001).   DOI   ScienceOn
16 S. Santos, K. Jones, R. Abdul, J. Boswell, and J. Pacac, "Treatment of Wet Process Hardboard Plant VOC Emissions by a Pilot Scale Biological System," Biochem. Eng. J., 37 261-70 (2007).   DOI
17 Y. H. Huang, Y. J. Huang, H. C. Tsai, and H. T. Chen, "Degradation of Phenol using Low Concentration of Ferric Ions by the Photo-fenton Process," J. Taiwan. Inst. Chem. E., 41 699-704 (2010).   DOI
18 B. Guieysse, C. Hort, V. Platel, R. Munoz, M. Ondarts, and S. Revah, "Biological Treatment of Indoor Air for VOC Removal: Potential and Challenges," Biotechnol. Adv., 26 398-410 (2008).   DOI