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http://dx.doi.org/10.4191/kcers.2012.49.2.191

Effect of Melting Atmospheres on the Structure and Properties of P2O5-SnO2 Glass Systems  

An, Yong-Tae (Optical-Electro Materials Laboratory, Korea Institute of Ceramics Engineering and Technology)
Choi, Byung-Hyun (Optical-Electro Materials Laboratory, Korea Institute of Ceramics Engineering and Technology)
Ji, Mi-Jung (Optical-Electro Materials Laboratory, Korea Institute of Ceramics Engineering and Technology)
Kwon, Yong-Jin (Optical-Electro Materials Laboratory, Korea Institute of Ceramics Engineering and Technology)
Bae, Hyun (ShinCeramic CO. Ltd.)
Hwang, Hae-Jin (School of Material Science and Engineering, Inha University)
Publication Information
Journal of the Korean Ceramic Society / v.49, no.2, 2012 , pp. 191-196 More about this Journal
Abstract
In this study, tin phosphate glass system($SnO_2-(1-x)P_2O_5-xB_2O_3$) that occur during the melting of the metal oxide inhibition of the oxidation reaction, and to reduce oxides of high melting temperature in the following three methods were melting. The first is the general way in the atmosphere, and the second by injecting $N_2$ gas under a neutral atmosphere, and finally in the air were melted by the addition of a reducing agent Melt in the atmosphere when the oxidation of the metal oxide is inhibited by low temperatures were melting. In addition, the deposition of crystals within glassy or inhibit devitrification phenomenon is also improved over 80% transmittance. This phenomenon, when the melting of glass, many of $Sn^{4+}$ ions are reduced to the $Sn^{2+}$ was forming oxides SnO, because it acts as a modifier oxide.
Keywords
$SnO_2$-$P_2O_5$; Low glass transition temperature; Melting atmosphere; Sucrose;
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
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1 B. H. Jung, "Pb-free Frit Composition Development for Exploitation of Eco-friendly Materials in PDP", The Korean Information Display Paper, 4 [5] 7-11 (2003).
2 R. Morena, "Phosphate Glasses as Alternatives to Pb-based Sealing Frit," J. Non-cry. Solids, 263-264 382-87 (2000).   DOI
3 B. H. Choi, M. J. Ji, Y. T. An, Y. S. Ko, and Y. H. Lee, "Effects of Substituting $B_2O_3\;for\;P_2O_5$ on the Structure and Properties of $P_2O_5-SnO_2$ Glass System," J. Kor. Ceram. Soc., 45 [8] 459-63 (2008).   DOI
4 B. H. Choi, "Technical Development Trend for PDP Device Material," The Korean Information Display, 8 [1] 10-1 (2007).
5 A. Hayashi, T. Konishi, K. Tadanaga, T. Minami, and M. Tatsumisago, "Preparation and Characterization of $SnO-P_2O_5$ Glasses as Anode Materials for Lithium Secondary Batteries," J. Non-Cryst. Solids, 345&346 478-83 (2004).   DOI
6 A. Hayashi, M. Nakai, M. Tatsumisago, T. Minami, Y. Himei, Y. Miura, and M. Katada, "Structural Investigation of $SnO-B_2O_3$ Glasses by Solid-state NMR and X-ray Photoelectron Spectroscopy," J. Non-Cryst. Solids, 306 227-37 (2002).   DOI
7 C. Gejke and E. Zanghellini, "Microscopic Structure of Tinborate Phosphate Glasses," J. Power Sources, 119-121 576-80 (2003).   DOI
8 K. Morinaga and S. Fujino, "Preparation and Properties of $SnO-SnCl_2-P_2O_5$ Glass," J. Non-Cry. Solids, 282 118-24 (2001).   DOI
9 J. Y. Ding and P. Y. Shih, "The Properties and Structure of Sn-Ca-P-O-F Glasses," Mat. Chem. and Phy. 82 61-7 (2003).   DOI
10 C. M. Lee and J. Jeong, "Oxidation Process from SnO to $SnO_2$," J. Mat's Sci. Letters, 16 1551-54 (1997).   DOI
11 J. Y. Lee and Y. Xiao, "Amorphous $Sn_2P_2O_7,\;Sn_2B_2O_5\;and\;Sn_2BPO_6$ Anodes for Lithium Ion Batteries," Solid State Ionics, 133 25-35 (2000).   DOI
12 M. Tatsumisago, Y. Kowada, and T. Minami, "Structure of Rapidly Quenched Lithium Phosphate Glasses," Phys. Chem. Glasses, 29 63-66 (1998).
13 R. K. Brow, D. R. Tallant, S. T. Myers, and C. C. Phifer, "The Short-range Structure of Zinc Polyphosphate Glass," J. Non-Cryst. Solids, 191 45-55 (1995).   DOI
14 D. H. Kim, C. W. Hwang, N. J. Kim, S. H. Im, D. G. Gwoo, T. H. Kim, J. M. Cha, and B. K. Ryu, "Effects of Substituting $B_2O_3\;for\;P_2O_5$ on the Structure and Properties of $SnO-P_2O_5$ Glass Systems," J. Kor. Ceram. Soc., 48 [1] 63-8 (2011).   DOI