Browse > Article
http://dx.doi.org/10.4191/kcers.2011.48.5.467

Effects of Ta Substitution on Dielectric and Piezoelectric Properties of Pb-free (Na0.53K0.47)(Nb1-xTax)O3 Ceramics  

Lee, Jung-Hoon (School of Nano & Advanced Materials Engineering, Changwon National University)
Ryu, Gyung-Hyun (School of Nano & Advanced Materials Engineering, Changwon National University)
Sung, Yeon-Soo (School of Nano & Advanced Materials Engineering, Changwon National University)
Cho, Jong-Ho (School of Nano & Advanced Materials Engineering, Changwon National University)
Song, Tae-Kwon (School of Nano & Advanced Materials Engineering, Changwon National University)
Kim, Myong-Ho (School of Nano & Advanced Materials Engineering, Changwon National University)
Publication Information
Abstract
Pb(Zr,Ti)$O_3$ (PZT) based ceramics with superior piezoelectric properties have been extensively used in various domestic and industrial appliances. However, PZT ceramics causing environmental contamination and health problems need to be eventually replaced by any of Pb-free materials. $(Na_{0.53}K_{0.47})(Nb_{1-x}Ta_x)O_3$ (NKNT), one of Pb-free piezoelectric ceramics, has long been known but its properties are not fully understood and developed. In this study, dielectric and piezoelectric properties of Pb-free NKNT ceramics were studied with Ta substitution for B-site at x = 0~0.6. It was found that polymorphic phase transition (PPT) between orthorhombic and tetragonal phases was notably influenced by Ta substitution. The highest piezoelectric coefficient ($d_{33}$) of 284 pC/N was occurred at x = 0.45.
Keywords
PPT; Pb-free; NKNT;
Citations & Related Records

Times Cited By SCOPUS : 0
연도 인용수 순위
  • Reference
1 M. Matsubara, K. Kikura, and S. Hirano, "Piezoelectric Properties of $(Na_{0.5}Na_{0.5})(Nb_{1−x}Ta_x)O_3-K_{5.4}CuTa_{10}O_{29}$ Ceramics," J. Appl. Phys., 97 [6] 114105 (2005).   DOI
2 R. E. Jaeger and L. Egerton, "Hot Pressing of Potassium-sodium Niobates," J. Am. Ceram. Soc., 45 [5] 209-13 (1962).   DOI
3 Y. Guo, K. Kakimoto, and H. Ohsato, "Phase Transitional Behavior and Piezoelectric Properties of $(Na_{0.5}_{0.5})NbO_3-LiNbO_3$ Ceramics," Appl. Phys. Lett., 85 [10] 4121-23 (2004).   DOI
4 V. J. Tennery and K. W. Hang, "Thermal and X-Ray Diffraction Studies of the $NaNbO_3-KNbO_3$ System," J. Appl. Phys., 29 [9] 4740-53 (1968).
5 M. Matsubara, T. Yamaguchi, K. Kikuta, and S. Hirano, "Enhanced Ferroelectric Properties of $LiNbO_3$ Substituted Na_{0.5}K_{0.5}NbO_3$ Lead-free Thin Films Grown by Chemical Solution Deposition," J. Appl. Phys., 97 [10] 114105-111 (2005).   DOI
6 B. Jaffe, W. R. Cook, and H. Faffe : "Piezoelectric Ceramics," Academic Press, 1971.
7 Y. J. Dai, X. W. Zhang, and P. Chen, "Morphotropic Phase Boundary and Electrical Properties of $K_{1−x}Na_xNbO_3$ leadfree ceramics," Appl. Phys. Lett., 94 [1] 042905-907 (2009).   DOI
8 B. Jaffe, R. S. Roth, and S. Marzullo, "Piezoelectric Properties of Lead Zirconate-lead Titanate Solid-solution Ceramics," J. Appl. Phys., 25 809-10 (1954).   DOI
9 Y. S. Sung, J. M. Kim, J. H. Jeong, T. K. Song, H. H. Chong, T. G. Park, D. Do, S. S. Kim, and M. H. Kim, "Effects of Na Nonstoichiometry in $(Bi_{0.5}Na_{0.5+x})TiO_3$ Ceramics," Appl. Phys. Lett., 96 [1] 022901-903 (2010)   DOI
10 Y. G. Lv, C. L. Wang, J. L. Zhang, L. Wu, M. L Zhao, and J. P. Xu, "Tantalum Influence on Physical Properties of $(Na_{0.5}K_{0.5})(Nb_{1−x}Ta_x)O_3$ Ceramics," Mater. Res. Bull., 44 284-87 (2008).
11 Y. Watanabe, K. Sumida, S. Yamada, S. Sago, S. Hirano, and K. Kikuta, "Effect of Mn-doping on the Piezoelectric Properties of $(K_{0.5}Na_{0.5})(Nb_{0.67}Ta_{0.33})O_3$ Lead-free Ceramics," J. Appl. Phys., 47 [10] 3556-58 (2008).   DOI
12 S. Triebwasser, "Study of Ferroelectric Transitions of Solidsolution Single Crystals of $KNbO_3-KTaO_3$," Phys. Rev., 114 [4] 63-70 (1959).   DOI
13 A. Thomas, T. Skidmore, P. Comyn, and S. J. Milne, "Temperature Stability of $({[Na_{0.5}K_{0.5}NbO_3]}_{0.93}-{[LiTaO_3]}_0.07)$ Lead-free Piezoelectric Ceramics," Appl. Phys Lett., 94 [1] 222902-904 (2009).   DOI
14 E. K. Akdogan, K. Kerman, M. Abazari, and A. Safari, "Origin of High Piezoelectric Activity in Ferroelectric $(K_{0.44}Na_{0.52}Li_{0.04})-(Nb_{0.84}Ta_{0.1}Sb_{0.06})O_3$ ceramics," Appl. Phys. Lett., 92 [3] 112908-910 (2008).   DOI
15 Y. Chang, Z. Yang, Y. Hou, Z. Liu, and Z. Wang, "Effects of Li Content on the Phase Structure and Electrical Properties of Lead-free $(NK_{0.46-x/2}Na_{0.54-x/2}Li_x)(Nb_{0.76}Ta_{0.20}Sb_{0.04})O_3$ Ceramics," Appl Phys. Lett., 90 [6] 232905-907 (2007).   DOI
16 J. L. Zhang, X. J. Zong, L. Wu, Y. Gao, P. Zheng, and S. F. Shao, "Polymorphic Phase Transition and Excellent Piezoelectric Performance of $(K_{0.55}Na_{0.45})_{0.965}Li_{0.035}Nb_{0.80}Ta_{0.20}O_3$," Appl. Phys. Lett., 95 [7] 022909-911 (2009).   DOI
17 Y. Zupei, Y. Chang, and L. Wei, "Phase Transitional Behavior and Electrical Properties of Lead-free $(K_{0.44}Na_{0.52}Li_{0.04})(Nb_{0.96−x}Ta_xSb_{0.04})O_3$ Piezoelectric Ceramics," Appl. Phys. Lett., 90 [1] 042911-913 (2007).   DOI
18 Y. Saito and H. Takao, "High Performance Lead-free Piezo-Electric Ceramics in the $(N,K)NbO_3-LiTaO_3$ Solid Solution System," Ferroelectrics., 338 [1] 17-32 (2006).   DOI
19 Y. Saito, H. Takao, T. Tani, T. Nonoyama, K Takatori, T. Homma, T. Nagaya, and M. Nakamura,"Lead-free Piezoelectric," Nature, 432 84-7 (2004).   DOI
20 G. H. Haertling, "Properties of Hot-pressed Ferroelectric Alkali Niobate Ceramics," J. Am. Ceram. Soc., 50 [6] 329-30 (1967).   DOI
21 Y. Guo, K. Kakimoto, and H. Ohsato, "$(Na_{0.5}_{0.5})NbO_3-LiTaO_3$ Lead-free Piezoelectric Ceramics," Materials. Lett., 59 [2] 241-44 (2005).   DOI