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http://dx.doi.org/10.4191/KCERS.2010.47.6.618

Purification of Metallurgical Grade Silicon by Plasma Torch and E-beam Treatment  

Eum, Jung-Hyun (Icheon Branch, KICET)
Nahm, Sahn (Division of Material Science and Engineering, Korea University)
Hwang, Kwang-Taek (Icheon Branch, KICET)
Kim, Kyung-Ja (Icheon Branch, KICET)
Choi, Kyoon (Icheon Branch, KICET)
Publication Information
Abstract
Cost-effective purification methods of silicon were carried out in order to replace the conventional Siemens method for solar grade silicon. Firstly, acid leaching which is a hydrometallurgical process was preceded with grinded silicon powders of metallurgical grade (~99% purity) to remove metallic impurities. Then, plasma treatments were performed with the leached silicon powders of 99.94% purity by argon plasma at 30 kW power under atmospheric pressure. Plasma treatment was specifically efficient for removing Zr, Y, and P but not for Al and B. Another purification step by EB treatment was also studied for the 99.92% silicon lump which resulted in the fast removal of boron and aluminum. That means the two methods are effective alternative tools for removing the doping elements like boron and phosphor.
Keywords
Solar grade silicon; Metallurgical grade silicon; Purification; Plasma treatment; Electron-beam treatment;
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
Times Cited By SCOPUS : 1
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1 Y. Delannoy, C. Alemany, K.-I. Li, P. Proulx, and C. Trassy, “Plasma-refining Process to Provide Solar-grade Silicon,” Mater. Sol. Energy Mater. Sol. Cells, 72 69-75 (2002).   DOI   ScienceOn
2 S. Martinuzzi, I. Periachaud, C. Trassy, and J. Degoulange, “n-Type Multicrystalline Silicon Wafers Prepared from Plasma Torch Refined Upgraded Metallurgical Feedstock”, Prog. Photovolt : Res. Appl., 17 297-305 (2009).   DOI
3 E. Centurioni, D. Iencinella, C. Bronzoni, and F. Bonafe, “A Simplified Process and Equipment for Upgraded Metallurgical Silicon”, Proceedings of the 24th European Photovoltaic Solar Energy Conference, pp.21-25 Sep., Hamburg, Germany, 2009.
4 J. H. Eum, H. S. Jang, H. T. Kim, and K. Choi, “Silicon Purification Through Acid Leaching and Unidirectional Solidification,” J. Kor. Crystal Growth Cryst. Technol., 6 232-36 (2009).
5 C. P. Khattak, D. B. Joyce, and F. Schmid, “A Simple Process to Remove Boron from Metallurgical Grade Silicon,” Sol. Energy Mater. Sol. Cells, 74 77-89 (2002).   DOI
6 J.C.S. Pires, J. Otubo, A.F.B. Braga, and P.R. Mei, “The Purification of Metallurgical Grade Silicon by Electron Beam Melting”, J. Mater. Proc. Tech., 169 16-20 (2005).   DOI
7 H. Y. Kim, “Preparation of Polysilicon for Solar Cells,” Kor. Chem. Eng. Res., 46 37-49 (2008).   과학기술학회마을
8 S. Pizzini, M. Acciarri, and S. Binetti, “From Electronic Grade to Solar Grade Silicon : Change and Challenges in Photovoltaics,” Phys. Stat. Sol., 202 2928-42 (2005).   DOI
9 K. Peter, R. Kopecek, A. Soiland, and E. Enebakk, “Future Potential for SoG-Si Feedstock from Metallurgical Process Route,” In: Proceedings of the 23rd European Photovoltaic Solar Energy Conference, 1-5 Sep, Valencia, Spain, 2008.