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http://dx.doi.org/10.4191/KCERS.2009.46.5.478

Thermal Shock and Hot Corrosion Resistance of Si3N4 Fabricated by Nitrided Pressureless Sintering  

Kwak, Kil-Ho (School of Mechanical and Automotive Engineering, Kookmin University)
Kim, Chul (School of Mechanical and Automotive Engineering, Kookmin University)
Han, In-Sub (Convergence Materials Research Center, Korea Institute of Energy Research)
Lee, Kee-Sung (School of Mechanical and Automotive Engineering, Kookmin University)
Publication Information
Abstract
Thermal shock and hot corrosion resistance of silicon nitride ceramics are investigated in this study. Silicon nitrides are fabricated by nitride pressureless sintering (NPS) process, which process is the continuous process of nitridation reaction of Si metal combined with subsequent pressureless sintering. The results of thermal shock test show it sustains 400MPa of initial strength during test in the designated condition of ${\Delta}T=700{\sim}25^{\circ}C$ up to maximum 4,800 cycles. Hot corrosion tests also reveal that the strength degradation of NPS silicon nitride did not occur at $700^{\circ}C$ with an exposure in Ar, $H_2$, Na and K for 1,275 h.
Keywords
Nitrided Pressureless Sintering(NPS); Silicon nitride; Thermal shock resistance; Corrosion resistance;
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Times Cited By KSCI : 2  (Citation Analysis)
Times Cited By SCOPUS : 1
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1 S. K. Lee, K. S. Lee, and B. R. Lawn, “Effect of Starting Powder on Damage Resistance of Silicon Nitrides,” J. Am. Ceram. Soc., 81 [8] 2061-70 (1998)   DOI   ScienceOn
2 W. Y. Park, D. S. Park, H. D. Kim, and B. D. Han, “Sintering and Mechanical Properties of Silicon Nitride Prepared with a Low-cost Silicon Nitride Powder(in Korean),” J. Kor. Ceram. Soc., 38 [11] 987-92 (2001)   과학기술학회마을
3 K. H. Guahk, I. S. Han, and K. S. Lee, “Strength Degradation from Hertzian Contact Damages in Nitrided Pressureless Sintered Silicon Nitride Ceramics,” Inter. J. Mod. Phys. B., 22 [9/11] 1819-26 (2008)   DOI   ScienceOn
4 B. R. Lawn, “Indentation of Ceramics with Spheres : A Century After Hertz,” J. Am. Ceram. Soc., 81 [8] 1977-94 (1998)   DOI   ScienceOn
5 H. Huang, K. J. Winchester, A. Suvorova, B. R. Lawn, Y. Liu, X. Z. Hu, J. M. Dell, and L. Faraone, “Effect of Deposition Conditions on Mechanical Properties of Low-Temperature PECVD Silicon Nitride Films,” Mater. Sci. & Eng., A435-546 453-59 (2006)   DOI   ScienceOn
6 B. T. Lee and H. D. Kim, “Microstructure and Fracture Characteristic of Reaction-Sintered $Si_3N_4$ -TiN Composite(in Korean),” J. Kor. Ceram. Soc., 33 [6] 686-92 (1996)   과학기술학회마을
7 S. H. Cheon, I. S. Han, Y. H. Chung, D. W. Seo, S. Lee, K. S. Hong, and S. K. Woo, “Preparation and Properties of Silicon Nitride Ceramics by Nitrided Pressureless Sintering (NPS) Process(in Korean),” J. Kor. Ceram. Soc., 41 [12] 893-99 (2004)   과학기술학회마을   DOI   ScienceOn
8 M. Mitomo and S. Uenosono, “Microstructural Development During Gas Pressure Sintering of a-Silicon Nitride,” J. Am. Ceram. Soc., 75 [1] 103-8 (1992)   DOI
9 F. F. Lange, “Fracture Toughness of $Si_3N_4$ as a Function of the Initial a-Phase Content,” J. Am. Ceram. Soc., 62 [7-8] 428-30 (1979)   DOI
10 G. Wötting and G. Ziegler, “Influence of Powder Properties and Processing Condictions on Microstructure and Mechanical Properteis of Sintered $Si_3N_4$,” Ceram. Int., 10 [1] 18-22 (1984)   DOI   ScienceOn
11 S. K. Lee, J. D. Morreti, M. J. Readey, and B. R. Lawn, “Thermal Shock Resistance of Silicon Nitrides,” J. Am. Ceram. Soc., 85 [1] 279-81 (2002)   DOI   ScienceOn
12 I. S. Han, S. H. Cheon, Y. H. Jung, D. W. Seo, S. Lee, K. S. Hong, and S. K. Woo, “Oxidation Behavior of $Si_3N_4$ by the Nitrided Pressureless Sintering(in Korean),” J. Kor. Ceram. Soc., 42 [1] 62-8 (2005)   과학기술학회마을   DOI   ScienceOn
13 I. S. Han, D. W. Seo, S. Y. Kim, K. S. Hong, G. H. Guahk, and K. S. Lee “Properties of Silicon Nitride for Aluminum Melts Prepared by Nitrided Pressureless Sintering,” J. Eur. Ceram. Soc., 28 1057-63 (2008)   DOI   ScienceOn
14 S. K. Woo, I. S. Han, G. G. Ri, S. C. Park, K. Cho, and B, K. Jang, “Hot Crrositon Behavior of Silicon Nitride-Bonded Silicon Carbide,” J. Ceram. Soc. Japan, 109 [1] 23-8 (2001)   DOI   ScienceOn
15 K. S. Lee, I. S. Han, D. W. Seo, and S. K. Woo, “Strength Degradation of Silicon Carbide Hot Gas Filter in the Simulated PFBC Condition,” Key Eng. Mater. 287 495-505 (2005)   DOI
16 B. R. Lawn, S. K. Lee, I. M. Peterson, and S. Wuttiphan, “Model of Strength Degradation from Hertzian Contact Damage in Tough Ceramics,” J. Am. Ceram. Soc., 81 [6] 1509-20 (1998)   DOI   ScienceOn