Browse > Article
http://dx.doi.org/10.4191/KCERS.2009.46.4.397

The Influence of Firing Conditions on the Color Properties of Pr-ZrSiO4 Pigments Synthesized Using Rice Husk Ash  

Pyon, Kyu-Ri (Department of Material Science & Engineering, Myongji University)
Lee, Byung-Ha (Department of Material Science & Engineering, Myongji University)
Publication Information
Abstract
Using rice husk ash as silica, the influence of the firing temperature and holding time on the color intensity of Pr-$ZrSiO_4$ pigments were investigated. The Pr-yellow pigments were calcined at 500, 700, 800, 900, 950, 1000, $1100^{\circ}C$ in a ceramic method. The synthesized pigments were characterized by DT-TG thermal analysis, X-ray diffraction, UV-Vis spectroscopy, and SEMEDAX analysis. The relationship between the zircon phase-formation growth and Pr-yellow color development was evaluated and the optimum firing conditions were determined. The color of the pigment samples was characterized on the grounds of the Commission Internationale de l'Eclairage (CIE) standard procedure (CIE $L^*a^*b^*$ measurement) after an application on the bisque ceramic tile.
Keywords
Rice husk ash; Pr-$ZrSiO_4$ pigment; Firing condition; Color properties;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
Times Cited By SCOPUS : 6
연도 인용수 순위
1 K. Hill and R. Lehman, 'Effects of Selected Processing Variables on Color Formation in Praseodymium-Doped Zircon Pigments,' J. Am. Ceram. Soc., 83 [9] 2177-82 (2000)   DOI   ScienceOn
2 R. A. Eppler, 'Mechanism of Formation of Zircon Stains,' J. Am. Ceram. Soc., 53 [8] 457-62 (1970)   DOI
3 M. Ocana, A. Caballero, A. R. Gonzalez-Elipe, and P. Tartaj, C. J. Serna, 'Valence and Localization in Pr-doped zircon,' J. Solid State Chem., 139 [2] 412-15 (1998)   DOI   ScienceOn
4 E. A. Basha, R. Hashim, and H. B. Mahmud, 'Stabilization of Residual Soil with Rice Husk Ash and Cement,' Construction & Building Materials, 19 [6] 448-53 (2005)   DOI   ScienceOn
5 F. Bondioli, F. Andreola, L. Barbieri, T. Manfredini, and A. M. Ferrari, 'Effect of Rice Husk Ash (RHA) in the Synthesis of (Pr,Zr)$SiO_4$ Ceramic Pigment,' J. Euro. Ceram. Soc., 27 [12] 3483-88 (2007)   DOI   ScienceOn
6 M. Shoyama, H. Nasu, and K. Kamiya, 'Preparation of Rare Earth-Zircon Pigments by the Sol-Gel Method,' J. Ceram. Soc. Jpn., 106 [3] 279-84 (1998)   DOI
7 M. Shoyama, K. Hashimoto, T. Hashimoto, H. Nasu, and K. Kamiya, 'Iron-Zircon Pigments Prepared by the Sol-Gel Method,' J. Ceram. Soc. Jpn., 107 [6] 534-40 (1999)   DOI
8 E. Kato and H. Takashima, 'Study of Zircon Pigments-Vanadium Blue,' Rep. Gov. Ind. Res. Inst, Nagoya, 4 [2] 147-50 (1956)
9 C. A. Seabright, Yellow Pigments for Ceramic Ware, US Patent 2,992,123 (1961)
10 G. D. Nero, G. Cappelletti, S. Ardizzone, P. Fermo, and S. Gilardoni, 'Yellow Pr-Zircon Pigments The Role of Praseodymium and of the Mineralizer,' J. Euro. Ceram. Soc., 24 [14] 3603-11 (2004)   DOI   ScienceOn
11 K. R. Pyon and B. H. Lee, 'Effect of Iron Content and Annealing Temperature on the Color Characteristics of Fe-$ZrSiO_4$ Coral Pink Pigments Synthesized by Sol-gel Method,' J. Ceram. Soc. Jpn., 117 [3] 258-63 (2009)   DOI   ScienceOn
12 M. Llusar, J. B. Vicent, J. Badenes, M. A. Tena, and G. Monros, 'Environmental Optimisation of Blue Vanadium Zircon Ceramic Pigment,' J. Euro. Ceram. Soc., 19 [15] 2647-57 (1999)   DOI   ScienceOn
13 V. P. Della, I. Kuhn, and D. Hotza, 'Rice Husk Ash as an Alternate Source for Active Silica Production,' Mater. Lett., 57 [4] 818-21 (2002)   DOI   ScienceOn
14 Y. Q. Zhao and S. F. Qingge, 'The Effect of Highly Reactive Rice Husk Ash on the Strength and Durability of Concrete,' J. Wuhan. Univ. Tech., 25 [2] 15-19 (2003)
15 K. Ganesan, K. Rajagopal, and K. Thangavel, 'Rice Husk Ash Blended Cement: Assessment of Optimal Level of Replacement for Strength and Permeability Properties of Concrete,' Construction and Building Materials, 22 [8] 1675-83 (2008)   DOI   ScienceOn
16 A. Biswas, 'Preparation and Characterisation of Monolithic Pr-doped Silica,' Mater. Sci. and Eng., 49 [3] 191-96 (1997)   DOI   ScienceOn
17 M. Trojan, Synthesis of Yellow Pigments, Dyes and Pigments, 9 [4] 261-73 (1988)   DOI   ScienceOn
18 M. Ocana, A. Caballero, A. R. Gonzalez-Elipe, P. Tartaj, C. J. Serna, and R. I. Merino, 'The Effects of the NaF Flux on the Oxidation State and Localisation of Praseodymium in Pr-doped Zircon Pigments,' J. Euro. Ceram. Soc., 19 [5] 641-48 (1999)   DOI   ScienceOn
19 J. A. Badenes, J. B. Vicent, M. Llusar, M. A. Tena, and G. Monros, 'The Nature of Pr-$ZrSiO_4$ Yellow Ceramic Pigment,' J. Mater. Sci., 37 [7] 1413-20 (2002)   DOI   ScienceOn
20 S. J. Park, M. H. Kim, and Y. K. Choi, 'Wet Fine Grinding of Rice Husk Ash using a Stirred Ball Mill,' J. Biosystem Eng., 31 [1] 33-38 (2006)   과학기술학회마을   DOI   ScienceOn
21 R. F. Abreu and J. Schneider, 'Structure and Hydration Kinetics of Silica Particles in Rice Husk Ash Studied by $^{29}Si$ High-Resolution Nuclear Magnetic Resonance,' J. Am. Ceram. Soc., 88 [6] 1514-20 (2005)   DOI   ScienceOn
22 C. S. Prasad, K. N. Maiti, and R. Venugopal, 'Effect of Rice Husk Ash in Whiteware Compositions,' Ceram. Inter., 27 [6] 629-35 (2001)   DOI   ScienceOn
23 Y. Kanno, 'Thermodynamic and Crystallographic Discussion of the Formation and Dissociation of Zircon,' J. Mater. Sci., 24 [7] 2415-20 (1989)   DOI
24 Y. C. Shin, D. Y. Shin, S. M. Han, and I. T. Nam, 'Synthesis of $ZrSiO_4$ Powders by the Sol-Gel Process,' J. Kor. Ceram. Soc., 32 [7] 853-57 (1995)   과학기술학회마을
25 T. Mori, H. Hoshino, Y. Ishikawa, H. Yamamura, H. Kobayashi, and T. Mitamura, 'Preparation of $ZrSiO_4$ Powder Using Sol-Gel Process (Part 4) Preparation from $ZrOCl_2$ and Colloidal $SiO_2$,' J. Ceram. Soc. Jpn., 99 [3] 227-32 (1991)   DOI