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http://dx.doi.org/10.4191/KCERS.2008.45.8.459

Effects of Substituting B2O3 for P2O5 on the Structure and Properties of P2O5-SnO2 Glass Systems  

Choi, Byung-Hyun (Electric Materials Laboratory, Korea Institute of Ceramics Engineering and Technology)
Ji, Mi-Jung (Electric Materials Laboratory, Korea Institute of Ceramics Engineering and Technology)
An, Yong-Tae (Electric Materials Laboratory, Korea Institute of Ceramics Engineering and Technology)
Ko, Young-Soo (Electric Materials Laboratory, Korea Institute of Ceramics Engineering and Technology)
Lee, Young-Hun (Samsung SDI)
Publication Information
Journal of the Korean Ceramic Society / v.45, no.8, 2008 , pp. 459-463 More about this Journal
Abstract
$P_2O_5-SnO_2$ system $0.5SnO_2-xP_2O_5-(0.5-x)B_2O_3$(x=0.1, 0.2, 0.3, 0.4, 0.5) glasses have been prepared for Pb-free low temperature glass frit. A investigation about the effect of $B_2O_3$ substitution on properties of $P_2O_5$ glasses, including glass structure properties, thermal properties, and mechanical properties was presented. Substance that is responsible for in moisture absorption existing circumstances supposes by phosphate, and excess moisture tolerance that state funeral's structure is improved breaking does not affect in state funeral bond that only most single bond remains, and can know that does not suffer big impact in boric oxide anomaly present state. This phenomenon estimates that connect with structure change. It is thought according to link this result the phosphoric acid happened structural change. $B_2O_3$ displacement quantity 0.3 mole put out $BO_4$ structures, but above 0.3 mole it changed with the case $BO_3$ structure which it displaces.
Keywords
$SnO_2-P_2O_5$ glass system; Pb-free; FT-IR; $B_2O_3$ substitution;
Citations & Related Records

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