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http://dx.doi.org/10.4191/KCERS.2008.45.8.453

Synthesis of Cr-doped Y2O3-Al2O3 Red Pigments and their Application  

Shin, Kyung-Hyun (Department of Materials Science & Engineering, Myongji University)
Lee, Byung-Ha (Department of Materials Science & Engineering, Myongji University)
Publication Information
Abstract
New inorganic red pigments based on Cr-doped $Y_2O_3$ and $Al_2O_3$ were synthesized by solid state method and characterization of their pigments were characterized by using XRD, FT-IR, SEM and UV-Vis spectrophotometer. The single perovskite phase revealed at $1450^{\circ}C{\sim}1550^{\circ}C$ for 6 h due to using mineralizers. The color of pigment powders resulted out various red-shades depending on the compositions of used materials and temperatures. Glazed tiles painted with pigment powders showed red color in oxidation and reduction firing. The best red colour was obtained when the $Cr_2O_3$ was used 0.04 mole at $1450^{\circ}C$ for 6 h.
Keywords
Red pigments; Solid state method; Perovskite; Reduction firing;
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1 R. Galindo, M. Llusar, M. A. Tena, G. Monrs, and J. A. Badenes, "New Pink Ceramic Pigment Based on Chromium(IV)-Doped Lutetium Gallium Garnet," J. Eur. Ceram. Soc., 27 199-205 (2007)   DOI   ScienceOn
2 M. Martos, M. Martnez, E. Cordoncillo, and P. Escribano, "Towards More Ecological Ceramic Pigments : Study of the Influence of Glass Composition on the Colour Stability of a Pink Chromium-doped Ceramic Pigment," J. Eur. Ceram. Soc., 27 4561-67 (2007)   DOI   ScienceOn
3 F. Bondioli, T. Manfredini, and C. Siligardi, "New Glassceramic Inclusion Pigment," J. Am. Ceram. Soc., 88 [4] 1070-71 (2005)   DOI   ScienceOn
4 Elena Lpez-Navarrete, Victor M. Orena, Francisco J. Lzaro, Juan B. Carda, and Manuel Ocaa, "Preparation Through Aerosols of Cr-doped $Y_2Sn_2O_7$(pyrochlore) Red-shade Pigments and Determination of the Cr Oxidation State," J. Am. Ceram. Soc., 87 [11] 2108-13 (2004)   DOI   ScienceOn
5 S. Furukawa, T. Masui, and N. Imanaka, "New Environment-friendly Yellow Pigments Based on $CeO_2-ZrO_2$ Solid Solutions," J. Alloys and Compounds, 451 640-43 (2008)   DOI   ScienceOn
6 M. Shirpour, M. A. Faghihi Sani, and A. Mirhabibi, "Synthesis and Study of a New Class of Red Pigments Based on Perovskite $YAlO_{3}$ Structure," Ceramics International, 33 [8] 1427-33 (2007)   DOI   ScienceOn
7 R. S. Pavlov, Juan B. Carda Castell, V. Blasco Marza, and J. M. Hohemberger, "New Red-shade Ceramic Pigments Based on $Y_{2}Sn_{2-x}Cr_{x}O_{7-{\infty}}$ Pyrochlore Solid Solutions," J. Am. Ceram. Soc., 85 [5] 1197-202 (2002)   DOI   ScienceOn
8 M. Jansen and H. P. Letschert, "Inorganic Yellow-red Pigments without Toxic Metals," Nature, 404 [4] 980-82 (2000)   DOI   ScienceOn
9 F. Matteucci, C. Lepri Neto, M. Dondi, G. Cruciani, G. Baldi, and A. O. Boschi, "Colour Development of Red Perovskite Pigment Y(Al,Cr)O3 in Various Ceramic Applications," Advances in Applied Ceramics, 105 [2] 99-106 (2006)   DOI   ScienceOn
10 Y. Marinova, J. M. Hohemberger, E. Cordoncillo, P. Escribano, and J. B. Carda, "Study of Solid Solutions, with Perovskite Structure, for Applivation in the Field of the Ceramic Pigments," J. Eur. Ceram. Soc., 23 213-20 (2003)   DOI   ScienceOn
11 L. Sandhya Kumari, P. Prabhakar Rao, and M. Lakshmipathy Reddy, "Environment-friendly Red Pigments from $CeO_{2}-Fe_{2}O_{3}-Pr_6O_{11}$ Solid Solutions," J. Alloys and Compounds, 461 509-15 (2008)   DOI   ScienceOn
12 A. Garca, M. Llusar, J. Calbo, M. A. Tena, and G. Monrs, "Low-toxicity Red Ceramic Pigments for Porcelainised Stoneware from Lanthanide-cerianite Solid Solutions," Green Chemistry, 13 238-42 (2001)
13 Jitendra Kumar Kar, Ron Stevens, and Christoper R. Bowen, "Processing and Characterisation of Various Mixed Oxide and Perovskite-based Pigments for High Temperature Ceramic Colouring Application," J. Alloys and Compounds, 461 77-84 (2008)   DOI   ScienceOn
14 E. S. Cherepanov, O. S. Grum-Grzhimailo, N. S. Belostotskaya, and M. S. Bibilashvili, "New Group of Ceramic Pigments," Translated from Steklo I Keramika, No. 8, pp. 26, August, 1986
15 R. A. Eppler and D. R. Eppler, "Which Colors Can and Cannot Be Produced in Ceramic Glazes," Ceram. Eng. Sci. Proc., 15 [1] 281-88 (1994)
16 Neil T. McDevitt and William L. Baun, "Infrared Absorption Study of Metal Oxides in the Low Frequency Region (700-200 $cm^{-1}$)," Spectrochemica, Acta, 20 799-808 (1964)   DOI   ScienceOn