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http://dx.doi.org/10.4191/KCERS.2008.45.6.363

Effects of High Energy Ball Milling on the Piezoelectric Properties of Lead-free (K0.44Na0.52)(Nb0.86Ta0.10)-0.04LiSbO3 Ceramics  

Kim, Young-Hyeok (Ulsan Fine Chemical Industry Center)
Heo, Dae-Young (Ulsan Fine Chemical Industry Center)
Tai, Weon-Pil (Ulsan Fine Chemical Industry Center)
Lee, Jae-Shin (School of Materials Science and Engineering, University of Ulsan)
Publication Information
Abstract
Lead-free $(K_{0.44}Na_{0.52})(Nb_{0.86}Ta_{0.10})-0.04LiSbO_3$ piezoelectric ceramics have been synthesized by conventional sintering process and then investigated on the sintering and piezoelectric properties by high energy ball milling (HEBM) treatment. The powders milled for different time are characterized by XRD, FE-SEM. The powders are pressed into a pellet and sintered. It is found that the piezoelectric properties of sintered specimens are strongly dependent on the milling time. The piezoelectric properties are enhanced by high energy ball milling treatment. The planer electromechanical coupling factor ($k_p$) and piezoelectric constant ($d_{33}$) of a specimen sintered at $1050^{\circ}C$ are 0.44 and 267 pC/N, respectively.
Keywords
Lead-free; High energy ball milling$(K_{0.44}Na_{0.52})(Nb_{0.86}Ta_{0.10})-0.04LiSbO_3$;
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1 B. Jaffe, W. R. Cook, and H. Jaffe, "Piezoelectric Ceramics," pp. 271-79, Academic press, New York, 1971
2 H. Du, S. Qu, J. Che, Z. Liu, X. Wei, and Z. Pei, "The Effect of Composition on Microstructure and Properties of PNW-PMS-PZT Ceramics for High-powder Pizoelectic Tansformer," Mater. Sci. Eng. A, 393 36-41 (2005)   DOI   ScienceOn
3 Z. P. Yang, Y. F. Chang, and H. Li, "Piezoelectric and Dielectric Properties of PZT-PZN-PMS Ceramics Prepared by Molten Salt Synthesis Method," Mater. Res. Bull., 40 2110-19 (2005)   DOI   ScienceOn
4 R. E. Jaeger and L. Egerton, "Hot Pressing of Potassium-Sodium Niobates," J. Am. Ceram. Soc., 45 209-13 (1962)   DOI
5 Y. Guo, K. I. Kakimoto, and Hi. Ohsato, "Phase Transitional Behavior and Piezoelectric Propeties $(Na_{0.5}K_{0.5})NbO_3$ Ceramics," Applied Physics Letters, 85 [18] 4121 (2004)   DOI   ScienceOn
6 E. Hollstein, M. Davis, D. Damjanovic, and Nava Setter, "Piezoelectric Properties of Li- and Ta-modified $(K_{0.5}Na_{0.5})NbO_3$ Ceramics," Applied Physics Letters, 87 [18] 182905 (2005)   DOI   ScienceOn
7 Y. Guo, K I. Kakimoto, and H. Ohsato, "$(Na_{0.5}K_{0.5})NbO_3-LiTaO_3$ Lead-free Piezoelectric Ceramics," Materials Letters, 59 241-44 (2005)   DOI   ScienceOn
8 Z. Yang, Y. Chang, B. Liu, and L. Wei, "Effects of Composition on Phase Structure and Electrical Properties of $(K_{0.5}Na_{0.5})NbO_3-LiSbO_3$ Ceramics," Mat. Scien. and Eng. A, 432 292-98 (2006)   DOI   ScienceOn
9 Yasu. Saito, His. Tako, Tosh. Tani, Tat. Nonoyama, Kaz. Takatori, Tosh. Nagaya, and Mas. Nakamura, "Lead-free Piezoceramics," Nature, 432 84-7 (2004)   DOI   ScienceOn
10 M. Kosec, B. Malic, W. Wolny, A. S. James, A. Alemany, and L. Pardo, "Effect of a Chemically Aggressive Environment on the Electromechanical Behavior of Modified Lead Titanate Ceramics," J. Korean Phys. Soc., 32 S1163 (1998)
11 G. H. HAERTLING, "Properties of Hot-Pressed Ferroelectric Alkali Niobate Ceramics," J. Am. Ceram. Soc., 30 32930 (1967)
12 X. Wang, K. Kwork, X. Tang, H. Chan, and C. Choy, "Electro-mechanical Properties and Dielectric Behavior of $(Bi_{1/2}Na_{1/2})_{(1-1.5x)Bi_xTiO_3 $ Lead-free Piezoelectric Ceramics," Solid State Commu., 129 319-23 (2004)   DOI   ScienceOn
13 J. F. Li and Ke Wang, "Ferroelectric and Piezoelectric Properties of Fine-Grained $(Na_{0.5}K_{0.5})NbO_3$ Lead-Free Piezoelectric Ceramics Prepared by Spark Plasma Sintering," J. Am. Ceram. Soc., 89 [2] 706-09 (2006)   DOI   ScienceOn
14 M. I. Mendelson, "Average Grain Size in Polycrystalline Ceramics," J. Am. Ceram. Soc., 52 [8] 443-46 (1969)   DOI
15 S. M. Bhim and O. K. Kim, "Grain Size Dependence of Dielectric Properties of (Ba, Sr)$TiO_3$ Ceramics," Jour. of Natural Scie., 17 53-7 (1998)
16 R. Zuo and J. Rodel, "Sintering and Electrical Properties of Lead-Free $Na_{0.5}K_{0.5}NbO_3$ Piezoelectric Ceramics," J. Am. Ceram. Soc., 89 [6] 2010-15 (2006)   DOI   ScienceOn
17 L. B Kong, J. Ma, W. Zhu, and O. K. Tan, "Prepareation and Characterization of Lead Zirconate Ceramics from High Energy Ball Milled Powder," Mat. Letters, 49 91-101 (2001)   DOI   ScienceOn
18 J. S. Lee, M. S. Choi, N. V. Hung, Y. S. Kim, I. W. Kim, E. C. Park, S. J. Jeong, and J. S. Song, "Effects of High Energy Ball-milling on the Sintering Behavior and Piezoelectric Properties of PZT-based Ceramics," Cera. Inter., 33 1283-86 (2007)   DOI   ScienceOn