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http://dx.doi.org/10.4191/KCERS.2008.45.5.256

Synthesis of ZnO-Al2O3-Cr2O3 Pigments and Coloring in Glazes  

Choi, Soo-Nyong (Department of Materials Science & Engineering, Myongji University)
Lee, Yong-Seok (Department of Materials Science & Engineering, Myongji University)
Lee, Byung-Ha (Department of Materials Science & Engineering, Myongji University)
Publication Information
Journal of the Korean Ceramic Society / v.45, no.5, 2008 , pp. 256-262 More about this Journal
Abstract
$ZnAl_{1-x}\;Cr_xO_4$ solid solutions were synthesized as pink pigments with and without mineralizer. The pigments were examined to optimize color development conditions of temperature and $Cr_2O_3$ contents. The characteristics of synthesized pigments were analyzed by XRD, XPS, FT-IR and UV-vis spectrophotometer. While samples without mineralizer fired at $1300^{\circ}C$, showed $ZnAl_2O_4$ and $ZnCr_2O_4$ spinel in XRD analysis. While samples with mineralizer resulted in $ZnAl_2O_4$. As a results, the pigments show pink color and most effective pink color was obtained at X=0.15 and $1250^{\circ}C$ when mineralizer was used. The chromatic coordinates are $L^*$ 58.61 $a^*$ 24.48, and $b^*$ 9.60.
Keywords
Pink pigments; Mineralizer $ZnAl_2O_4$;
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1 U. G. Lim, 'A Study on the Internationalization of Traditional Technology in korea-pottery,' Kor. Sci. Eng. Foun., 160-61 (1994)
2 Y. P. Park, 'Introduction to Technical Pottery,' pp. 1252-55, Korea Ceramic Industry Council, Seoul, 2003
3 M. Kato, H. Unuma, and M. Takahashi, 'Color Modification of Chromium-Tin Pink Pigment by Substitution of Ti for Sn,' J. Ceram. Assoc. Jap. 108 5 478-81 (2000)   DOI   ScienceOn
4 M. Martos, M. Martinez, E. Cordoncillo, and P. Escribano 'Towards more Ecological Ceramic Pigments: Study of the Influence of Glass Composition on the Colour Stability of Pink Chromium- doped Ceramic Pigment,' J. Eur. Ceram. Soc., 27 4561-67 (2007)   DOI   ScienceOn
5 T. Hiroo, 'Fondness for Pottery,' p. 39, Human & History, TOKYO, 2000
6 G. Monros, H. Pinto, J. Badenes, M. Llusar, and M. A.Tena, 'Chromium(IV) Stabilisation in New Ceramic Matrices by Coprecipitation Method: Application as Ceramic Pigments,' Z. Anorg. Allg. Chem., 631 11 2131-35 (2005)   DOI   ScienceOn
7 M.S.EL-Shahawi, 'Chromium(III) Complexes of Naturally Occurring Ligand,' Spectrochimica Acta, 51A 2 161-70 (1995)
8 M. Grinberg, D. L. Russell, K. Holliday, K. Wisniewski, and Cz. Koepke, 'Continuous Function Decay Analysis of a Multi Site Impurity Activated Solid,' Optics Communications, 156 409-41 (1998)   DOI   ScienceOn
9 G. Lorenzi, G. Baldi, F. Di Benedetto, V. Fasoa, and Luca A. P. Maurizio Romanelli, 'HF2EPR Investigation of a Crbearing Gahnite Pigment,' J. Euro. Ceram. Soc., 26 125-29 (2006)   DOI   ScienceOn
10 Cz. Koepke, K. Wisniewski, M. Grinberg, and G. H. Beall 'Excited State Absorption in the Gahnite Glass Ceramics and its Parent Glass doped with Chromium,' Spectro. Acta Part A, 54 1725-34 (1998)   DOI   ScienceOn
11 A. Ohtsuka, 'Formation and Color of the Spinel Solid Solutions in CoO-ZnO-$Al_2O_3-Cr_2O_3-Fe_2O_3$ System,' J. Ceram. Assoc. Japan, 81 2 49-63 (1973)   DOI
12 D. Chidambaram, Gary P. Halada, and Clive R. Clayton, 'Development of a Technique to Prevent Radiation Damage of Chromate Conversion Coatings during X-ray Photoelectron Spectroscopic Analysis,' Applied Surface Science, 181 283-95 (2001)   DOI   ScienceOn
13 A. Ohtsuka and K. Kazama, 'Formation and Color of the Spinel Solid Solutions in CoO-ZnO-$Al_2O_3-Cr_2O_3-TiO_2$ System,' J. Ceram. Assoc. Japan, 84 10 457-69 (1976)   DOI
14 M. Kato, M. Takahashi, H. Unuma, and S. Suzuki, 'Synthesis of Reddish Pink Pigment by Addition of $Mg^2+$ into (Al,$Cr)_2O_3$ Corundum,' J. Ceram. Soc. Japan, 107 2 181-83 (1999)   DOI   ScienceOn
15 E. Unveren, E. Kemnitz, S. Hutton, A. Lippitz, and W. E. S. Unger, 'Analysis of Highly Resolved X-ray Photoelectron Cr 2p Spectra Obtained with a $Cr_2O_3$ Powder Sample Prepared with Adhesive Tape,' Surf. Interface Anal., 36 92-5 (2004)   DOI   ScienceOn
16 T. Hiroo, 'Science of Pottery Glazes,' TOKYO, 1996
17 R. A. Nyquist and R. O. Kagel, 'Infrared Spectra of Inorganic Compounds,' pp. 216-219, 488-489, Academic Press, INC. New York, 1971
18 G. Costa, M. J. Ribeiro, J. A. Labrincha, M. Dondi, F. Matteucci, and G. Cruciani, 'Malayaite Ceramic Pigments Prepared with Galvanic Sludge,' Dyes and Pigments, 78 2 157-64 (2008)   DOI   ScienceOn