Browse > Article
http://dx.doi.org/10.4191/KCERS.2008.45.3.150

Properties and Photocatalytic Activity of Pitch-binded ACF/TiO2Composites  

Oh, Won-Chun (Department of Advanced Materials & Science Engineering, Hanseo University)
Jung, Ah-Reum (Department of Advanced Materials & Science Engineering, Hanseo University)
Publication Information
Abstract
Pitch-binded activated carbon fiber(ACF)/$TiO_2$ composite photocatalysts were prepared by Carbon Tetra Chloride (CTC) solvent mixing method with different mixing ratios of anatase to ACF. The result of the textural surface properties demonstrated that there is a slight increase in the Brunauer, Emmett and Teller (BET) surface area of composites with an increase of the amount of ACF. The surfaces structure morphologies of the composites were observed using an Scanning Electron Microscope (SEM). In the XRD patterns for all ACF/$TiO_2$ composites, the diffraction peaks showed the formation of anatase crystallites. The EDX spectra showed the presence of C, O and Si with strong Ti peaks. Most of these samples were richer in carbon and major Ti metal than any other elements. From the photo-decomposition results, the excellent activity of the ACF/$TiO_2$ composites between c/$c_0$ for methylene blue and UV irradiation time could be attributed to both the effects of the photocatalysis of the supported $TiO_2$ and adsorptivity of activated carbon fiber and another carbon derived from pitch.
Keywords
Activated carbon fiber; Anatase; BET surface area; SEM; XRD; EDX; Photocatalysis;
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
Times Cited By SCOPUS : 3
연도 인용수 순위
1 F. Schuth, S. W. K. Sing, and J. Weitamp, "Handbook of Porous Solids," Vol.4, pp.1766-1960, Wiley-VCH, NewYork, 2002.
2 W. C. Oh, J. S. Park, H. J. Lee, and M. H. Yum, "Electrochemical Removal Efficiency of Pollutants on ACF Electrodes," Carbon Science, 5 [4] 191-96 (2004).
3 W. C. Oh, C. S. Park, J. S. Bae, and Y. S. Ko, "Removal Efficiency of the Pollutants from Piggery Wastes with Activated Carbon Treated with Metal and their Pilot Scale Design," Carbon Science, 7 [3] 180-87 (2006).
4 W. C. Oh, J. S. Bae, and M. L. Chen, "Characterization of $AC/TiO_2$ Composite Prepared with Pitch Binder and their Photocatalytic Activity," Bull. Korean Chem. Soc., 27 [9] 1323-28 (2006).   DOI   ScienceOn
5 W. C. Oh, J. S. Bae, M. L. Chen, and Y. S. Ko, "Characterization of Composite Prepared with Different Mixing Ratios of $TiO_2$ to Activated Carbon and their Photocatalytic Activity," Analytical Science & Technology, 19 [5] 376-82 (2006).
6 M. Graetzel and A. J. Frank, "Interfacial Electron-Transfer Reactions in Colloidal Semiconductor Dispersions Kinetic Analysis," J. Phys. Chem., 86 2964-67 (1982).   DOI
7 T. Tsumura, N. Kojitani, I. Izumi, N. Iwashita, M. Toyoda, and M. Inagaki, "Carbon Coating of Anatase-Type $TiO_2$ and Photoactivity," J. Mater. Chem., 12 1391-96 (2002).   DOI   ScienceOn
8 M. Inagaki, F. Kojin, B. Tryba, and M. Toyoda, "Carbon- Coated Anatase: the Role of the Carbon Layer for Photcatalytic Performance," Carbon, 43 1652-59 (2005).   DOI   ScienceOn
9 X. Zhang, M. Zhou, and L. Lei, "$TiO_2$ Photocatalyst Deposition by MOVCD on Activated Carbon," Carbon, 44 325-33 (2006).   DOI   ScienceOn
10 W. C. Oh, J. S. Bae, and M. L. Chen, "Photocatalytic Effect for the Pitch-Coated $TiO_2$," Analytical Science & Technology, 19 [4] 301-08 (2006).
11 W. C. Oh, C. S. Park, C. Y. Park, A. R. Jung, and M. L. Chen, "Characterization of Pitch-Coated $TiO_2$ and their Photocatalytic Performance," p. 94, Conference Proceeding of Korea Carbon Society, 2006.
12 J. Matos, J. Laine, and J. M. Herrmann, "Association of Activated Carbons of Different Origins with Titania in the Photocatalytic Purification of Water," Carbon, 37 1870-72 (1999).   DOI   ScienceOn
13 W. C. Oh and Y. R. Na, "Photocatalytic Oxidation for Organic Dye using Phenol Resin-based Carbon-titania Composites," J. Kor. Ceram. Soc., 45 [1] 36-42 (2008).   과학기술학회마을   DOI   ScienceOn
14 M. Schneider, M. Widberger, D. G. Duff, T. Mallant, M. Maciejewsks, A. Baiker, in : G. Poncelet et.al (Eds) "Scientific Bases for the Preparation of Heterogeneous Catalyst, Preparation of Catalyst, VI," pp. 5-11, Elsevier, Amsterdam, 1995.
15 R. P. Schwarzenbach, P. M. Gschwend, and D. M. Imboden, "Environmental Organic Chemistry," 2nd Ed., pp. 34-9, John Wily and Sons, NewYork, 2002.