Browse > Article
http://dx.doi.org/10.4191/KCERS.2007.44.1.703

Comparison of the Power Generating Characteristics of KIST- and FZ-Julich SOFCs  

Jung, Hwa-Young (Center for Energy Materials Research, KIST)
Lee, Sang-Cheol (Center for Energy Materials Research, KIST)
Tietz, Frank (Institute for Materials and Processes in Energy Systems, Forschungszentrum Julich)
Kim, Hae-Ryoung (Center for Energy Materials Research, KIST)
Lee, Hae-Weon (Center for Energy Materials Research, KIST)
Lee, Jong-Ho (Center for Energy Materials Research, KIST)
Publication Information
Abstract
We evaluate and compare the power generating characteristics of the anode supported SOFCs which have been fabricated from KIST and FZ-Julich in Germany. The performance and electrochemical property of each unit cell was characterized at the temperature range of $650-850^{\circ}C$ under same operating conditions and its microstructural property was thoroughly investigated via SEM after the performance test. According to the investigation, KIST- and FZJ SOFC showed different power generating characteristics in their temperature dependances due to their different design of electrode microstructure, especially the cathode microstructure. FZJ SOFC showed better performance at high temperature while showed lower performance at lower temperature. From the investigation about the correlation between microstructure and electrochemical property, we found that the superior performance of FZJ SOFC at high temperature was mainly due to its lower cathodic polarization resistance whereas better performance of KIST SOFC at lower temperature was mostly attributed to the lower ohmic resistance.
Keywords
Anode supported SOFC; Unit cell; Performance;
Citations & Related Records
Times Cited By KSCI : 5  (Citation Analysis)
Times Cited By SCOPUS : 0
연도 인용수 순위
1 F. Tietz, Q. Fu, V. A. C. Haanappel, A. Mai, N. H. Menzler, and S. Uhlenbruck, 'Materials Development for Advanced Planar Solid Oxide Fuel Cells,' Int. J. Appl. Ceram. Technol., 4 [5] 436-45 (2007)   DOI   ScienceOn
2 V. A. C. Haanappel, J. Mertens, and A. Mai, 'Performance Improvement of $(La,\;Sr)MnO_3\;and\;(La,\;Sr)x(Co,\;Fe)O_3$-Type Anode-Supported SOFCs,' J. Fuel Cell SCi. and Technol., 3 263-70 (2006)   DOI
3 R. Wilkenhoner, W. Mallener, H. P. Buchkrenmer, Th. Hauber, and U. Stimming, in: B. Thorstensen (Ed), pp. 279-288, Proceeding of the Second European Solid Oxide Fuel Cell Forum, Oslo, Norway, May 6-10, 1996
4 B. Wei, Z. Lu, S. Li, Y. Liu, K. Liu, and W. Su, 'Thermal and Electrical Properties of New Cathode Material $Ba_{0.5}Sr_{0.5}Co_{0.8}Fe_{0.2}O_{3-{\delta}}$ for Solid Oxide Fuel Cells,' Electrochem. and Solid-State Lett., 8 [8] A428-31 (2005)   DOI   ScienceOn
5 T. Tsai, E. Perry, and S. Barnett, 'Low-Temperature Solid Oxide Fuel Cells Utilizing Thin Bilayer Electrolyte,' J. Electrochem. Soc., 144 [5] L130-L32 (1997)   DOI
6 J. D. Kim, G.D. Kim, J. W. Moon, and C. E. Kim, 'Preparation of (La, Sr)$MnO_3$ Powder by Glycine-Nitrate Preocess Using Oxide as Starting Materials(in Korean),' J. Kor. Ceram. Soc., 34 [10] 1003-08 (1997)   과학기술학회마을
7 F. Sissine, 'Fuel Cells for Electric Power Production: Future Potential, Fedral Role and Policy Options,' pp.1-18 in Fuel Cells: Trends in Research and Applications, Ed. by A.J. Appleby, Hemisphere Pub. Co., 1987
8 H. Y. Jung, T. W. Roh, J. Kim, H.-W. Lee, H. Ko, K. C. Lee, and J.-H. Lee, 'Power Generating Characteristics of Anode-Supported SOFC Fabricated by Uni-Axial Pressing and Screen Printing(in Korean),' J. Kor. Ceram. Soc., 41 [6] 456-63 (2004)   과학기술학회마을   DOI   ScienceOn
9 H. Y. Jung, K.-S. Hong, H.-G. Jung, H. Kim, H.-R. Kim, J.-W. Son, J. Kim, H.-W. Lee, and J.-H. Lee, 'SOFCs with Sc-Doped Zirconia Electrolyte and Co-Containing Perovskite Cathodes,' J. Electrochem. Soc., 154 [5] B480-85, (2007)   DOI   ScienceOn
10 J. D. Kim, G. D. Kim, and J. A. Park, 'The Effect of Particle Size and Ratio of LSM-YSZ Powders on SOFC cathode properties(in Korean),' J. Kor. Ceram. Soc., 37 [3] 227-32 (2000)   과학기술학회마을
11 J.-H. Lee, G. D. Kim, Y. B. Sohn, H.-W. Lee, S. W. Kim, H. S. Song, and G. H. Kim, 'Power Generating Characteristics and Long Term Stability of the Anode Supporting Type SOFC(in Korean),' J. Kor. Ceram. Soc., 37 [9] 847-55 (2000)   과학기술학회마을
12 H. Moon, H.-W. Lee, J.-H. Lee, and K.-H. Yoon, 'Correlation between the Microstructure and the Electrical Conductivity of SOFC anode, Ni-YSZ: I. Microstructure Analysis(in Korean),' J. Kor. Ceram. Soc., 37 [5] 479-90 (2000)   과학기술학회마을
13 Nguyen. Q. Minh, 'Ceramic Fuel Cells,' J. Am. Ceram. Soc., 76 [3] 563-88 (1993)   DOI
14 H. Moon, H.-W. Lee, J.-H. Lee, and K.-H. Yoon, 'Correlation between the Microstructure and the Electrical Conductivity of SOFC anode, Ni-YSZ: II. Temporal Variation(in Korean),' J. Kor. Ceram. Soc., 37 [12] 1140-45 (2000)   과학기술학회마을
15 J.-W. Moon, G. D. Kim, K.-T. Lee, and H.-L. Lee, 'Effect of YSZ Particle Size and Sintering Temperature on the Microstructure and Impedance Property of Ni-YSZ Anode for Solid Oxide Fuel Cell(in Korean),' J. Kor. Ceram. Soc., 38 [5] 466-73 (2001)   과학기술학회마을
16 J. W. Heo, D. S. Lee, J.-H. Lee, J. D. Kim, J. Kim, H.-W. Lee, and J. H. Moon, 'Effect of the Pore Structure on the Anodic Property of SOFC(in Korean),' J. Kor. Ceram. Soc., 39 [1] 86-91 (2002)   과학기술학회마을   DOI   ScienceOn
17 V. A. C. Haanappel, J. Mertens, D. Rutenbeck, C. Tropartz, W. Herzhof, D. Sebold, and F. Tietz, 'Optimization of Processing and Microstructural Parameters of LSM Cathodes to Improve the Electrochemical Performance of Anode-supported SOFCs,' J. Power Sources, 141 216-26 (2005)   DOI   ScienceOn
18 Nguyen. Q. Minh and T. Takahashi, 'Science and Technology of Ceramic Fuel Cells,' pp. 1-14, Elsevier Science, Amsterdam, 1995