Browse > Article
http://dx.doi.org/10.4191/KCERS.2006.43.9.552

Low Temperature Processing of Porous Silicon Carbide Ceramics by Carbothermal Reduction  

Eom, Jung-Hye (Department of Materials Science and Engineering, the University of Seoul)
Jang, Doo-Hee (Department of Materials Science and Engineering, the University of Seoul)
Kim, Young-Wook (Department of Materials Science and Engineering, the University of Seoul)
Song, In-Hyuck (Ceramic Materials Group, Korea Institute of Machinery and Materials)
Kim, Hai-Doo (Ceramic Materials Group, Korea Institute of Machinery and Materials)
Publication Information
Abstract
A low temperature processing route for fabricating porous SiC ceramics by carbothermal reduction has been demonstrated. Effects of expandable microsphere content, sintering temperature, filler content, and carbon source on microstructure, porosity, compressive strength, cell size, and cell density were investigated in the processing of porous silicon carbide ceramics using expandable microspheres as a pore former. A higher microsphere content led to a higher porosity and a higher cell density. A higher sintering temperature resulted in a decreased porosity because of an enhanced densification. The addition of inert filler increased the porosity, but decreased the cell density. The compressive strength of the porous ceramics decreased with increasing the porosity. Typical compressive strength of porous SiC ceramics with ${\sim}70%$ porosity was ${\sim}13 MPa$.
Keywords
Porous ceramics; Silicon carbide; Carbothermal reduction; Processing; Porosity;
Citations & Related Records
Times Cited By KSCI : 3  (Citation Analysis)
연도 인용수 순위
1 X. Bao, M. R. Nangrejo, and M. J. Edirisinghe, 'Synthesis of Silicon Carbide Foams from Polymeric Precursors and their Blends,' J. Mater. Sci., 34 2495-505 (1999)   DOI   ScienceOn
2 S. H. Kim, Y.-W. Kim, J. Y. Yun, and H. D. Kim, 'Fabrication of Porous SiC Ceramics by Partial Sintering and their Properties(in Korean),' J. Kor. Ceram. Soc., 41 [7] 541-47 (2004)   DOI   ScienceOn
3 S. S. Hwang, S. W. Park, J. H. Han, K. S. Han, and C. M. Kim, 'Mechanical Properties of Porous Reaction Bonded Silicon Carbide(in Korean),' J. Kor. Ceram. Soc., 39 [10] 948-54 (2002)   DOI   ScienceOn
4 N. Keller, C. Pham-Huu, S. Roy, M. J. Ledoux, C. Estournes, and J. Guille, 'Influence of the Preparation Conditions on the Synthesis of High Surface Area SiC for Use as a Heterogeneous Catalyst Support,' J. Mater. Sci., 34 3189-202 (1999)   DOI   ScienceOn
5 W. Wu, T. Fujiu, and G. L. Messing, 'Synthesis of Cellular Inorganic Materials by Foaming Sol-Gels,' J. Non-Cryst. Solids, 121 407-12 (1990)   DOI   ScienceOn
6 F. F. Lange and K. T. Miller, 'Open Cell, Low-Density Ceramics Fabricated from Reticulated Polymer Substrates,' Adv. Ceram. Mater., 2 [4] 827-31 (1987)   DOI
7 Y.-W. Kim, S. H. Kim, H. D. Kim, and C. B. Park, 'Processing of Closed-Cell Silicon Oxycarbide Foams from a Preceramics Polymer,' J. Mater. Sci., 39 5647-52 (2004)   DOI   ScienceOn
8 Y.-W. Kim, S. H. Kim, C. B. Park, and H. D. Kim, 'Processing and Mechanical Properties of Microcellular Ceramics,' Key Eng. Mater., 317-318 899-904 (2006)   DOI
9 Y.-W. Kim, S. H. Kim, I. H. Song, H. D. Kim, and C. B. Park, 'Fabrication of Open-Cell, Microcellular Silicon Carbide Ceramics by Carbothermal Reduction,' J. Am. Ceram. Soc., 88 [10] 2949-51 (2005)   DOI   ScienceOn
10 A. Herzog, R. Klingner, U. Vogt, and T. Graule, 'Wood- Derived Porous SiC Ceramics by Sol Infiltration and Carbothermal Reduction,' J. Am. Ceram. Soc., 87 [5] 784-93 (2004)   DOI   ScienceOn
11 Y. S. Chun and Y.-W. Kim, 'Processing of Silica-Bonded Silicon Carbide Ceramics,' J. Kor. Ceram. Soc., 43 [6] 327- 32 (2006)   과학기술학회마을   DOI   ScienceOn
12 Y.-W. Kim, S. H. Kim, C. Wang, and C. B. Park, 'Fabrication of Microcellular Ceramics Using Gaseous Carbon Dioxide,' J. Am. Ceram. Soc., 86 [12] 2231-33 (2003)   DOI   ScienceOn
13 M. Komac, 'The Investigation of High-Temperature Strength of SiC Based Refractories,' Ceram. Int., 7 [3] 103-05 (1981)   DOI   ScienceOn
14 G. T. Burns, R. B. Taylor, Y. Xu, A. Zangvil, and G. A. Zank, 'High-Temperature Chemistry of the Conversion of Siloxanes to Silicon Carbide,' Chem. Mater., 4 1313-23 (1992)   DOI
15 S. H. Kim, Y.-W. Kim, and C. B. Park, 'Effect of Inert Filler Addition on Pore Size and Porosity of Closed-Cell Silicon Oxycarbide Foams,' J. Mater. Sci., 39 3513-15 (2004)   DOI   ScienceOn
16 D. H. Jang, Y.-W. Kim, I. H. Song, H. D. Kim, and C. B. Park, 'Processing of Highly Porous, Open-Cell, Microcellular Silicon Carbide Ceramics by Expansion Method Using Expandable Microspheres,' J. Ceram. Soc. Jpn., 114 [6] 549-53 (2006)   DOI
17 Y.-W. Kim, Y. J. Jin, Y. S. Chun, I. H. Song, and H. D. Kim, 'A Simple Pressing Route to Closed-Cell Microcellular Ceramics,' Scripta Mater., 53 921-25 (2005)   DOI   ScienceOn
18 Y.-W. Kim and C. B. Park, 'Processing of Microcellular Preceramics Using Carbon Dioxide,' Comp. Sci. & Tech., 63 [14] 2371-77 (2003)   DOI   ScienceOn
19 Y.-W. Kim, H. D. Kim, and C. B. Park, 'Processing of Microcellular Mullite,' J. Am. Ceram. Soc., 88 [12] 3311-15 (2005)   DOI   ScienceOn